• Journal of Soil and Groundwater Environment
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• v.6 no.2
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• pp.39-47
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• 2001

According to a series of batch-scale washing tests, SDS+$POE_5$ and $POE_5$+$POE_14$ were determined for the applicable mixed surfactants. Because SDS+$POE_5$ showed slightly negative effects on the microbes in the toxicity tests, $POE_5$+$POE_14$((1:1) 1%) was chosen for this study. In the in-situ flushing experiments, the removal rate of endosulfan was 67% for the injection rate of 1.5L/min/$\textrm{km}^2$. And when methanol and ethanol were added as cosolvent, 75% and 81% removal efficiencies were achieved, respectively. In the tests of bioremediation after the application of in-situ flushing, the removal rates of contaminated soils having 13mg/kg dry soil and 3mg/kg dry soil as initial concentrations were 86% and 81%, respectively. There were no significant degradation after 24 hours. The major rate-limiting factor for the biodegradation of endosulfan might be the mass transfer from soil phase to liquid phase after 24 hours. With the addition of surfactant, 89% removal was achieved after 120 hours. Because the surfactant improved the mass transfer rate, the biodegradation of endosulfan was enhanced. When surfactant and cosolvent were added together, the adaptation period of microorganisms to the surfactant became longer and the removal rates were 84% and 83% for methanol and ethanol, respectively.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.87-91
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• 2002

Lab scale batch and column tests were performed to investigate the treatability of petroleum contaminated soil using the in-situ soil flushing method. The pyrex column (4.5$\times$25 cm) was used to investigate optimal washing agent, surfactant concentration, mixing ratio, and inlet velocity. The miked surfactant of $POE_{14}$ and SDS were determined as ideal systems for the batch tests. From the results of preliminary tests, mixed surfactant was found to be more harmful for microorganisms. So $POE_{5}$ and $POE_{14}$ were chosen as the surfactant system for the batch study. The washing efficiency for the diesel contaminated soil was increased until 1 %, and decreased after l %. When applied as selected mixed surfactant, the ideal mixed ratio was recognized as 1:1. Therefore we selected miked surfactant $POE_{5}$ and $POE_{14}$, surfactant concentration 1%, and mixed ratio 1:1 for the remediation of diesel contaminated soil. In column tests, the total removal efficiency was improved as the flux of washing agent was increased. At the same pore volume, small flux showed better removal efficiency.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.183-185
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• 2004

In this study, the combined electrokinetic and ultrasonic remediation technique, ultrasonically enhanced electrokinetic technique, was studied for the removal of heavy metal and organic substance in contaminated soils. The electrokinetic technique has been applied to remove mainly the heavy metal and the ultrasonic technique has been to remove mainly organic substance in contaminated soil. The laboratory soil flushing tests combined electrokinetic and ultrasonic technique were conducted using specially designed and fabricated devices to determine the effect of these both techniques. A series of laboratory experiments involving the simple, electrokinetic, ultrasonic, and electrokinetic & ultrasonic flushing test were carried out. A soil admixed with sand and kaolin was used as a test specimen, and Pb and ethylene glycol were used as contaminants of heavy metal and organic substance. An increase in out flow, permeability and contaminant removal rate was observed in electrokinetic and ultrasonic flushing tests. Some practical implications of these results are discussed in terms of technical feasibility of in situ implementation of electrokinetic ultrasonic remediation technique.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.1
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• pp.67-73
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• 2014

In this study, the residual heavy metals in the mine tailings, primarily treated by soil washing, were stabilized using phosphate salts. The concentrations of residual contaminants in the washed mine tailings were As (1,861 mg/kg), Cd (20 mg/kg), Cu (56 mg/kg), Pb (2,149 mg/kg), and Zn (633 mg/kg). They were stabilized with $CaHPO_4$, $Ca(H_2PO_4)_2{\cdot}H_2O$, and hydroxyapatite at 0.1 wt%, 1 wt%, and 10 wt% for 1, 3, 5, 7, and 14 days. It was found that 1 wt% $Ca(H_2PO_4)_2{\cdot}H_2O$ was optimum in our experiments, but the stabilization duration did not affect the efficiency. After stabilization with 1 wt% $Ca(H_2PO_4)_2{\cdot}H_2O$ for 1 day, the concentrations of arsenic and heavy metals, As (0.328 mg/L), Cd (0.250 mg/L), Cu (0.143 mg/L), Pb (0.359 mg/L), and Zn (2.622 mg/L), in TCLP leachate were below the RCRA-TCLP limits, which meant the contaminants in the treated mine tailings were stably immobilized.

• Journal of Korean Society on Water Environment
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• v.22 no.5
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• pp.824-830
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• 2006

Several tests were conducted to optimize the design parameters of ln-situ soil flushing processes for diesel contaminated soil. According to the batch extraction test for three anionic surfactants evaluation, Calgonit limiting bubble occurrence was selected for its higher oil cleaning efficiency. After optimum surfactant selection, there were many sets of column flushing test. Over 70% of BTEX was removed in this surfactant dose with 400% of soil volume. In the case of no surfactant addition flushing in column, so called "blank flushing test", BTEX removal rate was 64%. But when we reused the effluent for the cleaning solution, the removal rate was decreased to 46.9%. This result showed reabsorption of oil occurred on the soil. With the addition of Calgonit solution to the diesel contaminated column, BTEX was removed up to 98.9% during the first flushing and 99.4% for the second recirculation flushing. In microcosm tests, diesel contaminated soils were cleaned by both surfactant flushing and biological activities. In anoxic condition, nitrate was used as an electron acceptor while the surfactant and the oil were used an electron donor. BTEX removal efficiency could be achieved up to 80% by biological degradation.

• The Korean Journal of Mycology
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• v.16 no.4
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• pp.220-225
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• 1988

This study was carried out to investigate the effect on the system of crop rotation of sesame(Sesamum indicum L). The results of infected plant percentage and yield of sesame wilting disease, fluctuation of density of Fusarium oxysporum and Actinomycetes, and their pathogenicity test on Fusarium spp isolated from sesame cultural soil were investigated. Density of F. oxysporum was the highest in a sesame continuous cropping soil but that of Actinomycetes was the lowest in that soil. And that of F. oxysporum and Actinomycetes according to investigation date was the highest at June. 30 and July. 30, respectively. Their pathogenicity of F. oxysporum and F. solani isolated from sesame cultural soil to sesame, peanut and green gram were recognized to all isolates except one isolate among F. oxysporum 8 isolates and one isolate to sesame, 2 isolates to peanut and all isolates to green gram among F. solani 4 isolates. F. oxysporum density and infected plant of wilting disease were increased as a result of replanted cultivation of sesame, and yield of that was prominantly reduced. Relation between density of F. oxysporum in cultural soil and infected plant percentage showed positive correlation and yield index highly negative. There was little difference between sesame-upland rice and sesame-peanut in the system of crop rotation.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.7
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• pp.549-556
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• 2009

In situ chemical oxidations (ISCO) are technologies for destruction of many contaminants in soil and groundwater, and persulfate has been recently studied as an alternative ISCO oxidant. Trichloroethylene (TCE) and tetrachloroethylene (PCE) were chosen for target organic compounds. The objective of this study is to demonstrate the influence of initial pH (3, 6, 9, 12), oxidant concentrations (0.01, 0.05, 0.1, 0.3, 0.5 M), and contaminants concentrations (10, 30, 50, 70, 100 mg/L) on TCE/PCE degradation by persulfate oxidation. The maximum TCE/PCE degradation occurred at pH 3, and the removal efficiencies with this pH condition were 93.2 and 89.3%, respectively. The minimum TCE/PCE degradation occurred at pH 12, and the removal efficiencies were 55.0 and 31.2%, respectively. This indicated that degradation of TCE/PCE decreased with increasing the initial pH of solution. Degradation of TCE/PCE increased with increasing the concentration of persulfate and with decreasing the concentration of contaminants (TCE/PCE). The optimum conditions for TCE/PCE degradation were pH 3, 0.5 M of persulfate solution, and 10 mg/L of contaminant concentration. At these conditions, the first-order rate constants ($k_{obs}$) for TCE and PCE were 1.04 and 1.31 $h^{-1}$, respectively.