• Title/Summary/Keyword: 테트라

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Synthesis and Biological Activity Test of the Sex Pheromone of the Summer Fruit Tortrix Moth (애모무늬잎말이나방의 성 페로몬 합성과 생물활성 시험)

  • Suk-Ku Kang;Sang Soon Ahn;Jung Han Kim;Jeong-Oon Lee
    • Journal of the Korean Chemical Society
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    • v.32 no.1
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    • pp.65-70
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    • 1988
  • Synthesis and biological activity test are described for the (Z)-9-tetradecen-1-yl acetate(1) and (Z)-11-tetradecen-1-yl acetate(1) and (Z)-11-tetradecen-1-yl acetate(2), the sex pheromone of the summer fruit tortrix moth, Adoxophyes orana. 8-Bromoctan-l-ol THP ether was prepared from 8-bromoctan-l-ol. The lithium anion of 1-hexyne was alkylated with 8-bromoctan-l-ol THP ether gave 9-tetradecyn-l-ol THP ether. Catalytic hydrogenation over Pd/BaSO4 followed by deprotection afforded (Z)-9-tetradecen-l-ol. Acetylation gave (Z)-9-tetradecen-1-yl acetate(1). l0-Bromodecan-l-ol THP ether was obtained from l0-bromodecan-l-ol. In liquid ammonia with THF and HMPA as cosolvents, sodium acetylide could be alkylated with 10-bromodecan-l-ol THP ether to give 11-dodecyn-l-ol THP ether. 11-Dodecyn-l-ol THP ether was then treated with n-BuLi in THF to give the lithium acetylide, which was alkylated with bromoethane to afford 11-tetradecyn-l-ol THP ether. Catalytic hydrogenation, deprotection, and acetylative gave (Z)-11-tetradecen-1-yl acetate(2). The synthetic pheromone thus obtained was attractive to the males of the summer fruit tortrix in the field.

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Thermal Performance Evaluation of Composite Phase Change Material Developed Through Sol-Gel Process (졸겔공법을 이용한 복합상변화물질의 열성능 평가)

  • Jin, Xinghan;Haider, Muhammad Zeeshan;Park, Min-Woo;Hu, Jong-Wan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.5
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    • pp.555-566
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    • 2023
  • In this study, a composite phase change material (CPCM) produced using the SOL-GEL technique was developed as a thermal energy storage medium for low-temperature applications. Tetradecane and activated carbon (AC) were used as the core and supporting materials, respectively. The tetradecane phase change material (PCM) was impregnated into the porous structure of AC using the vacuum impregnation method, and a thin layer of silica gel was coated on the prepared composite using the SOL-GEL process, where tetraethyl orthosilicate (TEOS) was used as the silica source. The thermal performance of the CPCM was analysed using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). DSC results showed that the pure tetradecane PCM had melting and freezing temperatures of 6.4℃ and 1.3℃ and corresponding enthalpies 226 J/g and 223.8 J/g, respectively. The CPCM exhibited enthalpy of 32.98 J/g and 27.7 J/g during the melting and freezing processes at 7.1℃ and 2.4℃, respectively. TGA test results revealed that the AC is thermally stable up to 500℃, which is much higher than the decomposition temperature of the pure tetradecane, which is around 120℃. Moreover, in the case of AC-PCM and CPCM thermal degradation started at 80℃ and 100℃, respectively. The chemical stability of the CPCM was studied using Fourier-transform infrared (FT-IR) spectroscopy, and the results confirmed that the developed composite is chemically stable. Finally, the surface morphology of the AC and CPCM was analysed using scanning electron microscopy (SEM), which confirmed the presence of a thin layer of silica gel on the AC surface after the SOL-GEL process.

Photoaddition Reactions of trans-1,2-Bispyrazylethylene to Tetramethylethylene (테트라메틸에틸렌에 대한 트란스-1,2-비스피라질에틸렌의 광첨가반응)

  • Sang Chul Shim;Jin Ho Cho
    • Journal of the Korean Chemical Society
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    • v.23 no.5
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    • pp.325-328
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    • 1979
  • trans-1,2-Bispyrazylethylene (BPE) undergoes photoaddition reaction to tetramthylethylene (TME) which appears to involve radical intermediates under conditions where the corresponding hydrocarbons are unreactive. This photoaddition reaction involves abstraction of an allylic hydrogen atom of TME by $^1(n,\;{\pi}^*)$ states of BPE having radical character. The major photoadduct is isolated by column chromatography and fractional vacuum sublimation and characterized to be 2,3-dimetyl-5,6-bispyrazyl-2-hexene.

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Gateway Platform for Connecting D-TRS in Electric Power IT (전력 IT용 D-TRS 접속을 위한 게이트웨이 플랫폼)

  • Song, Byung-Kwen;Jeong, Tae-Eui
    • Journal of the Korean Society for Railway
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    • v.12 no.1
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    • pp.45-54
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    • 2009
  • TETRA(Terrestrial Trunked Radio) is the standard of D-TRS(Digital Trunked Radio System) developed by the ETSI(European Telecommunications Standards Institute). Currently, TETRA has been selected as Electric Power IT Wireless Backbone Network. Traditional distribution automation system has used the wireless network of Mobile Service Provider using CDMA(Code-Division Multiple Access) and WCDMA(Wideband CDMA) modem. Therefore, the development of gateway platform is indispensable according to the change to TETRA network. In this paper, we propose an embedded Linux-based Gateway platform for transmitting Industrial Electric Power IT protocol using TETRA network.