• Title/Summary/Keyword: 탈염방법

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Characteristic of Coastal Soil Improvement by MICP Technology Using Sea Water (해수를 사용한 MICP 기술의 연안 지반 개량시 발생하는 특성 분석)

  • Sojeong Kim;Jinung Do
    • Journal of the Korean Geosynthetics Society
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    • v.22 no.2
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    • pp.13-21
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    • 2023
  • Mean sea level has recently been rising due to global warming causing coastal erosion. As Korea is peninsula, the land loss due to coastal erosion is critical. An approach in this study is cementing the coastal area using bacteria, which is called microbially induced carbonate precipitation (MICP). This study tried to see how fresh water and sea water work with MICP as a solvent. Ureolytic activity during the MICP reaction was measured with deionized and sea water. A soil column was prepared to evaluate the strength of MICP-treated sand. Sands were treated by MICP with surface percolation method. As the treatmen t style was different with other conventional methods, several methods were proposed to properly evaluate the MICP-treated sand surface. A micro-scale evaluation was performed to assess the mineral structure treated by different solvents. As results, sea water rendered the ureolytic reaction slower. A needle penetrometer worked well to evaluate the MICP-treated sand surface. This study confirmed the utilization of sea water is feasible as the solvent of MICP.

Study on Characteristics and Features of Re-corrosion on Archaeological Iron Nails after Conservation Treatments (철제관정의 보존처리 후 재부식 양상 및 특성 연구)

  • Lee, Hyeyoun;Park, Hyungho;Kim, Sujung;Yu, Jaeeun
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.343-351
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    • 2012
  • Excavated archaeological iron objects are prevented from being corroded going through desalination which slow down being corroded. However archaeological iron objects are liable to be corroded due to the high ionization tendency even though they are stored in environment restricted from corrosion factors. Iron objects could be deteriorated more than just excavated. Therefore this study investigated about the characteristic of re-corrosion and the effect on objects. In study, archaeological iron nails in storage for 4 years after conservation treatments were tested. Optical microscopy and X-ray photography for appearance, XRD, SEM-EDS, Raman spectroscopy for chemical composition, IC for chloride ions concentration inside iron nails were used. As results, iron nails carried out conservation treatments measured a high concentration of chloride ions after the long storage period. The form of objects were not in good condition such as broken or destroyed when the high chloride ions concentration was detected. In addition, the yellow and red powdery corrosion product were detected on the boundary between corrosion products and substrates and they were identified as akaganeite which is symptom of active corrosion.

Detection of Salmonella spp. in Seafood via Desalinized DNA Extraction Method and Pre-culture (전배양과 탈염과정을 포함하는 DNA 추출법을 이용한 분자생물학적 방법으로 수산물 중 오염된 Salmonella spp.의 검출)

  • Ye-Jun Song;Kyung-Jin Cho;Eun-Ik Son;Du-Min Jo;Young-Mog Kim;Seul-Ki Park
    • Journal of Food Hygiene and Safety
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    • v.38 no.3
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    • pp.123-130
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    • 2023
  • Salmonella spp. are prevalent foodborne pathogens that are infective at relatively low concentrations, thus posing a serious health threat, especially to young children and the elderly. In several countries, the management and regulation of Salmonella spp. in food, including seafood, adhere to a negative detection standard. The risk of infection is particularly high when seafood is consumed raw, which underscores the importance of timely detection of pathogenic microorganisms, such as Salmonella. Accordingly, this study aimed to develop a combined pre-treatment and detection method that includes pre-culture and DNA extraction in order to detect five species of Salmonella at concentrations below 10 CFU/mL in seafood. The effectiveness of the proposed method was assessed in terms of the composition of the enrichment (pre-culture) medium, minimum incubation time, and minimum cell concentration for pathogen detection. Furthermore, a practical DNA extraction method capable of effectively handling high salt conditions was tested and found to be successful. Through polymerase chain reaction, Salmonella spp. Were detected and positively identified in shellfish samples at cell concentrations below 10 CFU/g. Thus, the proposed method, combining sample pre-treatment and cell culture with DNA extraction, was shown to be an effective strategy for detecting low cellular concentrations of harmful bacteria. The proposed methodology is suitable as an economical and practical in situ pre-treatment for effective detection of Salmonella spp. in seafood.

Report on the Conservation Treatment for the Artifacts Exhibited in the newly-opened Kimhae National Museum (국립김해박물관(國立金海博物館) 개관(開館) 전시유물 보존처리 보고(報告))

  • Kwon, Hyuk-nam;Ahn, Byong-chan
    • Conservation Science in Museum
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    • v.1
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    • pp.15-26
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    • 1999
  • More than 200 objects selected for the newly-opened Kimhae National Museum were treated for conservation. The objects which represent ancient Kaya culture, were mainly composed of metallic such as gilt bronze, silver, copper alloy and iron. The corrosion products on gilt bronze and copper alloy objects were preserved or removed according to their stability. Minimum treatment was done for preserving the original state of the objects. For silver objects and iron objects with silver-plate decorations, silver surfaces were revealed after treatment of corrosion products and treatments to prevent corrosion of silver and iron were done emphatically. For iron objects, which were stabilized, the original shape of objects was restored and acrylic coating was applied to prevent further corrosion. For the objects which were being corroded, 2-step de-chloride treatments were undertaken. The first step was immersing the objects in a solution of 0.3M sodium hydroxide and the second was the pressure de-chloride treatment using borax-distilled water. The main purpose of those treatments was to get rid of the causes of corrosion. Besides, conservation treatments for potteries, making of special mounting board for exhibition and amendment of various modeling were done too.

A study on the properties of polysilanes synthesized by ultrasonic methods (초음파 화학적 방법으로 합성된 폴리실란의 물성에 관한 연구)

  • Yang, Eun-Ok;Lee, Joong-Keun;Lee, Sung-Hwan;Song, Young Sang;Lee, Gyu-Hwan
    • Analytical Science and Technology
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    • v.19 no.6
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    • pp.504-511
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    • 2006
  • Polysilanes with organic substituents such as methyl and phenyl were synthesized by Wurtz dechlorination-condensation reactions using ultrasonic from organochlorosilanes. The yields were compared with the results of thermal dechlorination-condensation reactions. Properties such as thermogravimetric analysis and photoreactivity were investigated for the possibility of applications.

Reductive Degradation Kinetics and Pathways of Chlorophenolic Organic Pollutants by Nickel-Coated Zero Valent Iron (니켈로 코팅된 영가금속을 이용한 염소계 페놀화합물의 반응경로 및 반응율 평가)

  • Shin, Seung-Chul;Kim, Young-Hun;Ko, Seok-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.487-493
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    • 2006
  • Reductive dechlorination of chlorophenols by nickel coated iron was investigated to understand the feasibility of using Ni/Fe for the in situ remediation of contaminated groundwater. Zero Valent Iron(ZVI) was amended with Ni(II) ions to form bimetal(Ni/Fe). Dechlorination of five chlorophenol compounds and formation of intermediates were examined using Ni/Fe. Rate constant for each reaction pathway was quantified by the numerical integration of a series of differential rate equation. Experimental results showed that the sequence of hydrodechlorination rate constant was in the order of 2-CP>4-CP>2,4-DCP>2,4,6-TCP>2,6-DCP. The hydrodechlorination pathways for the conversion of each chlorophenol compound involves a full dechlorination to phenol via both concerted and stepwise mechanisms. Reaction pathways and corresponding kinetic rate constants were suggested based on the experiments and numerical simulations.

Determination of byproducts after treatment in PCBs-containing transformer oils (PCBs 함유 절연유의 처리 후 부산물 배출특성 연구)

  • Shin, Sun Kyoung;Park, Jin Soo;Kang, Young Yeul;Hwang, Seung Ryul;Kim, Young Sik
    • Analytical Science and Technology
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    • v.21 no.3
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    • pp.201-211
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    • 2008
  • The treatment efficiency of PCBs containing wastes has been investigated. The samples treated by electron beam and de-chlorination method were analyzed to verify the byproducts before treatment and after treatment. In the treated samples by electron beam irradiation, PCBs were not detected by comparing the peak matching using the Korean official waste test method. On the other hand, PCBs congeners were detected by analyzing individual isotope method using HRGC/HRMS. Most of PCB congeners in waste were decomposed to 3-chlorobiphenyls, lower chlorinated congener produced during the treatment of electron beam. In the chemical dechlorination treatment, it was found that the concentrations of PCBs in treated samples were lower than those of regulation criteria in Waste & POPs management law and the after treatment concentration were satisfied to the regulation criteria. Also, dioxins were not observed after the physio-chemical treatment processes of PCBs containing wastes.

새송이버섯의 절임전처리 조건에 따른 품질 변화 특성

  • 황성희;이예경;윤광섭;김순동
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.117.1-117
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    • 2003
  • 새송이 버섯은 맛과 향이 좋고 영양적으로 우수하여 성인병 예방과 개선 효과가 있다고 알려져 있으나 재배농가의 급증으로 인한 가격하락과 집중출하로 신선도의 하락 등이 문제가 되고 있어 새송이 버섯의 활용성을 향상시키고, 소비자의 기호를 충족시킬 수 있는 버섯류 가공품 개발이 요구되고 있다. 전통절임식품을 응용한 새로운 버섯류 장류절임 가공법을 개발하기 위하여 절임 전 처리에 따른 품질특성을 비교하였으며, 이를 위하여 먼저 절임 전처리 조건으로 블랜칭처리, 적정 염농도와 처리시간 및 탈염법을 개발하고 건조 등의 전처리에 따른 품질 평가는 수분함량, 염도, 색상, 조직감, 관능특성 등을 평가하였다. 새송이 버섯을 전처리하기 위한 블랜칭 처리조건은 7$0^{\circ}C$에서 10분간 처리한 구가 조직감이 우수하고 갈변이 적었으며 염 침지시간은 침지 72시간까지는 증가하였으나 그 이후로는 증가하지 않았고 4$0^{\circ}C$에서 탈염하는 것이 가장 우수하여 전처리 조건으로 선정하였다. 전처리 방법에 따른 중량변화는 블랜칭 처리가 약 10% 정도 중량이 더 많았으며 이 영향은 건조 후에도 지속되었다. 수분함량도 블랜칭 처리가 높았으며 염도 또한 건조 처리에 따라 높은 함량을 보였으나 블랜칭 처리를 병행했을 경우 낮은 값을 나타내었다. 조직의 강도는 무처리에 비하여 전처리를 함에 따라 많은 힘이 소요되어 질긴 조직 특성을 나타냄을 알 수 있다. 관능평가 결과 블랜칭 처리를 단독으로 실시한 B(B)처리구가 관능적 특성치 모두 높은 값을 보여 전처리 방법으로는 가장 우수한 전처리 방법임을 알 수 있었다.저온 장시간 처리한 경우에 비하여 낮은 수준이지만 약간의 증감 경향을 보이다가 고른 평형 상태를 유지하였다. 산소 농도는 저온 장시간 처리 직후 급격히 저하된 후 다시 증가하였으며 저장 7일 후에는 4$0^{\circ}C$ 3시간 처리구를 제외하고는 평형 상태를 유지하였다. 고온 단시간 처리구의 경우 처리 직후부터 저장 7일 후까지 고른 평형 상태를 유지하였다. 에틸렌의 경우 저온 장시간 처리구는 처리 직후 그 농도가 급격히 상승하였다가 저장 1일 후부터 대조구보다 낮은 값을 나타내었다. 고온 단시간 처리구의 경우 저온 장시간 처리구와는 달리 저장 1일 후부터 그 농도가 다소 상승되었다가 다시 감소는 경향을 보였다. 한편 열처리하여 냉각시킨 직후 및 저장1주 후 사과의 pH, 산도, 당도, 경도, 과육의 갈변도 등을 조사하였던 바 대조구 및 처리구간에 일부 항목에 있어서는 약간의 차이를 나타내었다. 대치할 수 있을 것이라고 사료된다. 수분함량은 기계적 검사보다 관능검사와 더욱 높은 상관관계를 나타냈다.내었다. 항균활성이 우수한 생약재를 농도별로 활성을 조사한 결과, 물 추출물과 10% Ethanol 추출물 모두 낮은 농도에서도 우수한 항균활성을 나타내었다.취와 함께 점질성 갈변물질이 생성되었다. 이와 같은 결과로 볼 때, BAAG의 처리는 BAAC의 경우보다 가격은 저렴하면서도 항균력은 우수한 천연 항균복합제재로써 농산물 식품원료에 적용하여 선도유지 기간을 연장할 수 있는 효과를 기대할 수 있었다. 과일 등의 포장제로서 이용할 가능성을 확인하였다.로 [-wh] 겹의문사는 복수 의미를 지닐 수 없 다. 그러면 단수 의미는 어떻

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Synthesis of poly(dialkyl or monoalkyl)silanes as silicon carbide precursors for ceramic matrix composites (탄화규소 선구물질로서의 폴리(디알킬 또는 모노알킬)실란들의 합성과 세라믹 복합체 응용)

  • Lee, Gyu-Hwan
    • Analytical Science and Technology
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    • v.26 no.1
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    • pp.27-33
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    • 2013
  • Polyalkylsilanes such as poly(dialkyl)silanes and poly(monoalkyl)silanes were synthesized by sonochemical dechlorination-condensation method from (dialkyl or monoalkyl)chlorosilanes with sodium metal. Those polyalkylsilanes were analyzed for the properties such as thermal behaviors from TGA analysis and obtained ceramic yields of 10-20% for poly(dialkyl)silanes and 40-60% for poly(monoalkyl)silanes. Ceramic composite discs were prepared by the combined mixture of polyalkylsilanes and SiC powder and were tested by TGA and analyzed by SEM and XRD for the application as binder for ceramic composite precursors.