• Journal of the Korean Wood Science and Technology
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• v.46 no.1
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• pp.60-66
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• 2018

For new use development of carbonized board, we investigated the effect of carbonization temperature on the surface temperature of carbonized board manufactured from a plywood, particle board, MDF, and wood of Fraxinus rhynchophylla at different carbonization temperature ($400^{\circ}C{\sim}1100^{\circ}C$). The surface temperature of carbonized board precipitously increased until 12 minutes elapsed, after smoothly increased and thereafter which were stable after 20 minutes. The higher carbonization temperature increased density of carbonized board and surface temperature of carbonized board so that density is considered to influence surface temperature change. Moreover, carbonized boards kept heat for a long time because the descent velocity of carbonized boards' surface temperature was slower than that of heater's.

• Journal of the Korean Wood Science and Technology
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• v.30 no.4
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• pp.33-40
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• 2002

This research was to investigate the adsorption characteristics of charcoals of major Korean wood species (thinned trees) and wood-based materials. As carbonization time and temperature increased, methylene-blue adsorption (MBA) of charcoals of thinned trees and wood-based materials increased. Pinus koraiensis charcoal showed the highest MBA. MBA of softwoods was higher than that of hardwoods. There was a negative correlation between air-dried specific gravity before carbonization and MBA of carbonized thinned trees. The MBA of wood-based materials showed similar value, but wood-based materials in MBA was lower than thinned woods. Surface area and total pore volume of thinned trees and wood-based materials increased as carbonization temperature increased. The species showing highest MBA appeared to have the highest surface area at the carbonization temperature of 600℃ as well. There was a positive correlation between surface area, total pore volume and MBA of charcoals. The charcoal of wood-based materials generally exhibited micro pores.

• Journal of the Korean Wood Science and Technology
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• v.35 no.3
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• pp.53-60
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• 2007

Carbon content, properties of micro-pore, and chemical properties of the charcoal prepared from wood powder, wood fiber, and bark of Abies sibirica Ledeb at different temperatures were investigated. The yield of charcoal decreased with increasing the carbonization temperature. The yield of bark charcoal was higher than those of wood and wood fiber charcoal. The content ratio of carbon atom in the charcoal increased with increasing the carbonization temperature, whereas those of hydrogen and oxygen atom were decreased. Ash content of bark charcoal was also higher than those of wood and wood fiber charcoal. The specific surface area of wood and wood fiber charcoal was greater than that of bark charcoal. In all charcoal, the specific surface area and the volume of micro-pore were highest when the carbonization temperature was $600^{\circ}C$, however they tended to decrease when the temperature was reached to $800^{\circ}C$. For the functionality test of chemical groups on the charcoal surface, adsorption test have performed against acidic (HCl) and basic chemicals (NaOH, $Na_2CO_3$, and $NaHCO_3$). As carbonization temperature increased, adsorption amount of HCl increased, while adsorption amounts of NaOH, $Na_2CO_3$, and $NaHCO_3$ were decreased. The charcoal prepared at higher temperature showed basic properties, while the charcoals manufactured at lower temperature presented acidic properties. Therefore, it was considered that the carbonization temperature affected the pH of charcoal.

• Journal of the Korean Wood Science and Technology
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• v.34 no.3
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• pp.8-14
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• 2006

The object of this study was to investigate the carbonization of Quercus variabilis wood samples in pyrolysis system at temperature ranging from 250 to $740^{\circ}C$ to contribute to the knowledge of wood carbonization mechanism. Volume of wood sample decreased with increasing the carbonization temperature, and checks were developed along with radial direction. Weight loss increased with increasing carbonization temperature. During carbonization, tangential direction showed higher shrinkage of vessel diameter than radial direction. SEM observation indicated that the cell walls in wood fibers and parenchyma cells presented the layering structure at $250^{\circ}C$ and $300^{\circ}C$. However, the cross section of cell walls at $340^{\circ}C$ and over showed an amorphous- like structure without cell wall layering. X-ray diffraction presented that the cellulose crystalline substance was still remained in carbonization temperature at $340^{\circ}C$, but it was not detected at $540^{\circ}C$ and over.

• Journal of the Korean Wood Science and Technology
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• v.35 no.3
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• pp.45-52
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• 2007

The anatomical characteristics of Quercus variabilis woods carbonized at 310 to $350^{\circ}C$ were examined with an optical and scanning electron microscopy, and an X-ray diffraction analysis. Dimensional change and weight loss were also investigated. Volume of wood samples decreased with increasing the carbonization temperature, and checks were developed along with radial direction. Vessel diameter in tangential direction showed higher shrinkage than that in radial direction. Weight loss of samples increased with increasing carbonization temperature. Especially, the weight loss rapidly increased at the temperature ranging from 330 to $340^{\circ}C$. SEM study presented that the cell walls of samples carbonized at below $320^{\circ}C$ showed the layering structure. However, it was revealed that the layering structure was disappeared at $330^{\circ}C$ and over and showed an amorphous-like structure without cell wall layering. Interestingly, the existence of cellulose crystalline substance at $340^{\circ}C$ was confirmed by X-ray diffraction analysis and it was not detected at $350^{\circ}C$. Consequently, it is considered that the critical temperature for carbonization of wood was around $350^{\circ}C$.

• Journal of the Korean Wood Science and Technology
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• v.37 no.6
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• pp.517-523
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• 2009

Repeated impregnation and carbonization processes were performed to prepare high-density woodceramics using a sawdust board. The physical properties were investigated to confirm morphological and structural changes of one-time and two-time phenolic resin-treated and carbonized woodceramics. As comparing between one-time and two-time carbonized woodceramics, the weight and the density of the two-time carbonized woodceramics decreased with an increase of the carbonization temperature. When the carbonization temperature was $600^{\circ}C$, the weight increased by 21.7% and density increased by 20.6% from $0.68g/cm^3$ to $0.82g/cm^3$, respectively, as a maximum value.

• Journal of Korea Foresty Energy
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• v.25 no.1
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• pp.9-17
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• 2006

Properties of wood charcoal made from the domestic wood species at $300-900^{\circ}C$ have investigated to understand the correlation between carbonization temperature and chemical and physical characteristics of wood charcoal. In terms of charcoal yield at particular carbonization temperatures, it was drastically decreased until the temperature reaches up to $600^{\circ}C$ and the decrease ratio of yield was reduced at higher temperatures. As the carbonization temperature increased, pH of the wood charcoal increased so that it became basic at last. The wood charcoal prepared at $600{\sim}700^{\circ}C$ showed the highest caloric value and those of wood charcoals made at higher temperature became plateau at a little lower level than the peak. The caloric value of Japanese larch charcoal was a bit higher than that of Red oak charcoal. The carbon content in the wood charcoal was increased as the carbonization temperature increased, whereas the hydrogen content was decreased. Specific surface area of the wood charcoal became larger with increase in temperature up to $600^{\circ}C$ but it was decreased or reduced in the increasing ratio after, and then it rose again at higher temperature than $800^{\circ}C$. Absorption capacity of the wood charcoal against iodine and gaseous acetic acid became greater as the carbonization temperature increased. Japanese larch charcoal presented higher absorption capacity than Red oak charcoal. As the above results, it is revealed that carbonization temperature affects the chemical and physical properties of wood charcoal. Therefore, to use wood charcoal with maximum effect it should be prepared at optimum temperature for proper use.

• Journal of the Korean Wood Science and Technology
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• v.41 no.1
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• pp.58-63
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• 2013

This study is a basic research for practical applications of carbonized boards, which measured thermal conductivity and electrical properties of carbonized boards manufactured at different carbonization temperature ($400{\sim}1,100^{\circ}C$) using a medium density fiberboard, particleboard, plywood and wood (Fraxinus rhynchophylla). The highest value of thermal conductivity was 0.1326 m/k at carbonization temperature of $900^{\circ}C$ in the carbonized particleboard. Overall, the higher density of carbonized board, thermal conductivity was faster. As the electrical resistivity decreased with increased carbonization temperature, it was almost close to conductor after carbonization temperature of $1,000^{\circ}C$. When electricity has worked on the carbonized board by high voltage, the current and the electric power increased and surface temperature of carbonized board was high.

• Journal of the Korean Wood Science and Technology
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• v.37 no.4
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• pp.293-299
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• 2009

In manufacturing the crack-free carbonized boards using fiberboards, shrinking ratio, weight loss and density variation of carbonized boards at each carbonization temperature were investigated. Fiberboards with thickness of 3, 4.5, 6, and 18 mm were carbonized while pressed with pressure plates at different temperature from $400^{\circ}C$ to $1,000^{\circ}C$ using a ordinary laboratory furnace. Either of crack or twist was not observed in fiberboards by adapting the pressing carbonization method. The ratios of shrinkage of length, width, and thickness were 10~25%, 12~25%, and 28~48%, respectively, and shrinkage ratio of thickness was higher than those of length and width with increasing the carbonization temperature. Weight loss tended to increase with increasing the carbonization temperature, but low correlation between weight loss in thickness of fiberboards and carbonization temperature was observed. Density of 3 mm carbonized hardboard had the highest value and it tended to increase with increasing the carbonization temperature.

• Resources Recycling
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• v.26 no.2
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• pp.25-32
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• 2017

Since the heating values of swine manures were very low at 859~1,075 kcal/kg, it was necessary to convert to carbonization residue by carbonization processes among thermal processes. The most important factor in the carbonization process of swine manure is the carbonization temperature, and it was evaluated the optimal range of carbonization temperature for swine manure in this study by the thermal characteristics and the reaction kinetics. The carbonization of swine manure could be described by the 1st order reaction and Arrhenius equation. The frequency factor (lnA) and the activation energy were estimated to be 3.05~13.08 and 6.94~18.05 kcal/mol, respectively. The range of optimal carbonization temperature range of swine manure was $260{\sim}300^{\circ}C$.