• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.310-316
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• 2020

Terpene-modified phenolic resins were used to improve the tires wet traction related to the driving safety and also rolling resistance related to fuel efficiency. In this work, alpha-pinene, beta pinene, and delta limonene resins, which constitute different basic structures of terpene-modified phenolic resins, were individually added to the tread compounds of tires and their physical properties were compared with those of the alkyl phenol resin compounds. Alkyl phenolic resins showed no significant difference in tangent delta from terpene-modified phenolic resins at 0 ℃, which is related to wet traction, but showed higher tangent delta at 80 ℃, which is related to rolling resistance, indicating smaller fuel efficiency improvement effects. Among the terpene-modified phenolic resins, beta pinene one showed improved wet traction and fuel efficiency compared to those of other resins. Delta limonene resin showed the best wet traction improvement effect, and alkyl phenolic resins showed relatively high tensile strength and abrasion property. All terpene-modified resins exhibited better rolling resistance than those of alkyl phenolic ones so that they can be said to have better fuel efficiency improvement effects and also to improve other properties compared to those of blanks. Terpene-modified phenolic resins could be used when mixing tire compounds referring to the properties of the phenolic resins revealed in this work, which could result in preparing compounds with improved wet traction and rolling resistance.

• Tribology and Lubricants
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• v.31 no.3
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• pp.102-108
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• 2015

In this research, we experimentally investigated the sealing performance of elastomeric rotary lip seals for washing machines. In general, NBR is used as a material for elastomeric rotary lip seals in washing machines, but the mixing formula of the rubber material can affect the sealing performance. In this study, we manufactured rotary lip seals using three kinds of NBRs with a different mixing formula, and examined the sealing performance using an acceleration test mode. The results of an SEM investigation into the surfaces of three kinds of specimens showed a much smaller wear volume and better sealing performance for the specimens with smaller particle sizes of mixing composition than for the specimen with the larger. Repeated deformation and recovery by the shaft-to-seal eccentricity on rotation were shown to cause a phase difference in the rubber material, and we measured the recovery ratio to find the influence of this phase difference on the sealing performance. As another method for checking the phase difference, we also measured tan ä, and a lower tan ä was revealed as the recovery ratio increased for each specimen. Specimens with a higher recovery ratio (lower tan ä) were shown to have a better sealing performance. Consequently, specimens with a smaller particle size in the mixing composition had a better sealing performance because they show a higher recovery ratio.

• Polymer(Korea)
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• v.36 no.2
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• pp.235-244
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• 2012

A thiazole type accelerator MBT (2-mercapto benzothiazole) was added into silica filled natural rubber (NR) compound with various concentrations (0, 1, 2, 3, 4 phr). The effects of MBT on the cure rate, mechanical property, degree of rubber-filler interaction (${\alpha}_F$), crosslinking density, and viscoelastic property ($tan{\delta}$) were investigated. As accelerator concentration increased, the $t_{s2}$ and $t_{90}$ decreased and the crosslinking density and modulus at 300% elongation increased. The tensile strength and elongation increased up to 3 phr and no further increased at 4 phr. The $tan{\delta}$ value measured at room temperature was higher than that of the $70^{\circ}C$. The ${\alpha}_F$ value was not affected by the addition of MBT. The mechanisms for the vulcanization rate were reviewed.