• Title/Summary/Keyword: 탄소 분말

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Characterization of Fe-ACF/$TiO_2$ composite Photocatalysts Effect Via Degradation of MB Solution (Fe-ACF/$TiO_2$ 복합체의 특성과 MB용액의 분해에서 포토-펜톤 효과)

  • Zhang, Kan;Meng, Ze-Da;Ko, Weon-Bae;Oh, Won-Chun
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.290-298
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    • 2009
  • In this paper, the Fe-activated carbon fiber (ACF)/$TiO_2$ composite catalysts were prepared by a sol-gel method. The synthesized photocatalysts were used for the photo degradation of Methylene blue solution under UV light. From Brunauer-Emmett-Teller measurements (BET) data, it was shown the blocking of the micropores on the surface of ACF by treatment of Fe and Ti compound. As shown in SEM images, the ferric compounds and titanium dioxides were fixed onto the ACF surfaces. The result of X-ray powder diffraction showed that the crystal phase contained a mixing anatase and rutile structure and the 'FeO+$TiO_2$' from the composites. The EDX spectra for the elemental analysis showed the presence of C, O, and Ti with Fe peaks. Degradation activity of MB could be attributed to +OH radicals derived from electron/hole pair's reactions due to photolysis of $TiO_2$ and photo-Fenton effect of Fe.

An Experimental Study on the Development of Electro Magnetic Pulse Shielding Cement Using Milled Carbon Fiber (저 직경 카본섬유를 사용한 전자기 펄스 차폐 시멘트 개발에 관한 실험적 연구)

  • Min, Tae-Beom
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.429-435
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    • 2020
  • In this study, physical properties and EMP shielding performance evaluation of cement paste according to the amount of milled carbon fiber was conducted to develop EMP shielding cement using carbon fiber. The length of the milled carbon fiber used was 100㎛, and it was used as a cement admixture because it showed a powdery form to the naked eye. As a result of the experiment, when 5% of the amount of cement was used, the milled carbon fiber was effective in compressive strength and EMP shielding, and the shielding effect did not increase when used beyond that. As a result of examining the EMP shielding performance according to the thickness of the specimen, the plain without milled carbon fiber had no effect of increasing the shielding rate according to the thickness. The shielding performance of the specimens using the milled carbon fiber increased as the thickness increased. Therefore, in order to increase the EMP shielding rate when comparing and evaluating the performance according to the amount of milled carbon fiber used and the thickness of the specimen, 5% of the milled carbon fiber used is optimal. In addition, the method of increasing the thickness is considered to be effective.

Mechanical and Electrical Properties of Low-Cement Mortar Using a Large Amount of Industrial By-Products (산업부산물을 다량활용한 저시멘트 모르타르의 역학적·전기적 특성)

  • Kim, Young-Min;Im, Geon-Woo;Lim, Chang-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.43-44
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    • 2023
  • This study evaluated the mechanical and electrical properties of low-cement mortar using a large amount of industrial by-products to reduce carbon emissions from the cement industry. As types of industrial by-products, blast furnace slag and fly ash, which are representative materials, were used, and ultra-high fly ash was mixed and evaluated to solve the problem of initial strength loss. In addition, in order to evaluate the electrical properties, 1% of MWCNT was incorporated relative to the powder mass. As experimental items, the compressive strength was measured on the 1st, 3rd, 7th and 28th days of age, and the rate of change in electrical resistance was measured on the 28th day of age. As a result of the experiment, the initial strength of the test specimen mixed with blast furnace slag and fly ash was significantly lower than that of 100% cement, and the specimen mixed with blast furnace slag showed strength equal to that of cement at 28 days of age. As an electrical characteristic, the electrical resistance was reduced when the load was loaded, and this reason is judged to be the effect of improving the conductivity as the connection between CNTs is narrowed by the compressive load.

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Investigation of direct growth behavior of carbon nanotubes on cathode powder materials in lithium-ion batteries (리튬이차전지 양극 분말 소재 위 탄소나노튜브의 직접 성장 거동 고찰)

  • Hyun-Ho Han;Jong-Hwan Lee;Goo-Hwan Jeong
    • Journal of the Korean institute of surface engineering
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    • v.57 no.1
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    • pp.22-30
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    • 2024
  • This study reports a direct growth of carbon nanotubes (CNTs) on the surface of LiCoO2 (LCO) powders to apply as highly efficient cathode materials in lithium-ion batteries (LIB). The CNT synthesis was performed using a thermal chemical vapor deposition apparatus with temperatures from 575 to 625 ℃. Ferritin molecules as growth catalyst of CNTs were mixed in deionized (DI) water with various concentrations from 0.05 to 1.0 mg/mL. Then, the LCO powders was dissolved in the ferritin solution at a ratio of 1g/mL. To obtain catalytic iron nanoparticles on the LCO surface, the LCO-ferritin suspension was dropped in silicon dioxide substrates and calcined under air at 550℃. Subsequently, the direct growth of CNTs on LCO powders was performed using a mixture of acetylene (10 sccm) and hydrogen (100 sccm) for 10 min. The growth behavior was characterized by scanning and transmission electron microscopy, Raman scattering spectroscopy, X-ray diffraction, and thermogravimetric analysis. The optimized condition yielding high structural quality and amount of CNTs was 600 ℃ and 0.5 mg/mL. The obtained materials will be developed as cathode materials in LIB.

Application of a Undaria pinnatifida for industrial cultivation of Lactobacillus (유산균의 산업적 배양을 위한 미역의 유용성 평가)

  • Chang, Bo Yoon;Han, Ji Hye;Kim, Ju-Hee;Cha, Bum-Suk;Ann, Sung-Ho;Kim, Sung Yeon
    • Food Science and Preservation
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    • v.22 no.2
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    • pp.251-255
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    • 2015
  • To optimize the medium composition of Undaria pinnatifida as a pH modulator the growth of Lactobacillus plantarum industrial scale, we analyzed the pH and growth characteristics of L. plantarum in basal medium. Subsequently, the medium compositions addition of carbon, nitrogen sources and buffering agents were optimized. When 0.5% yeast extract and 2% glucose, L. plantarum grew to maximum cell density in experimental condition. However, the growth of L. plantarum rapidly pH 4.0 in basal medium. A high alkali-ash value and low cost-effective utilization n the waste part as examined. ddition of U. pinnatifida extract alleviated the serious decrease. Among them, juice of U. pinnatifida was most helpful for the growth of L. plantarum ($36.3{\pm}1.810^8CFU/mL$). These results show that U. pinnatifida be large-scale cultivation of L. plantarum. This optimized U. pinnatifida medium can be used for safe and economical production of Lactobacillus.

Electrochemical Determination of Ag(I) Ion at Chemically Modified Carbon-Paste Electrode Containing 1,5,9,13-Tetrathiacyclohexadecane (1,5,9,13-Tetrathiacyclohexadecane 수식전극을 사용한 Ag(I)의 전기화학적 정량)

  • Ha, Kwang Soo;Jang, Mi-Kyeong;Seo, Moo Lyong
    • Analytical Science and Technology
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    • v.10 no.3
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    • pp.187-195
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    • 1997
  • Chemically modified electrodes(CMEs) for Ag(I) were constructed by incoporating 1,5,9,13-tetrathiacyclohexadecane([16]-ane-$S_4$) with a conventional carbon-paste mixture composed of graphite powder and nujol oil. Ag(I) ion was chemically deposited onto the surface of the modified electrode with [16]-ane-$S_4$ by immersion of the electrode in the acetate buffer solution(pH=4.5) containing $5.0{\times}10^{-4}M$ Ag(I) ion. And then the electrode deposited with Ag(I) was reduced at -0.3V vs. S.C.E. Well-defined stripping voltammetric peaks could be obtained by scanning the potential to the positive direction. The CME surface was regenerated with exposure to 0.1M $HNO_3$ solution and was reused for the determination of Ag(I) ion. When deposition/measurement/regeneration cycles were 10 times, the response could be reproduced with relative standard deviation of 6.08%. In case of differential pulse stripping voltammetry, the calibration curve for Ag(I) was linear over the range of $5.0{\times}10^{-7}{\sim}1.5{\times}10^{-6}M$. And the detection limit was $2.0{\times}10^{-7}M$. Various ions such as Cd(II), Ni(II), Pb(II), Zn(II), Mn(II), Mg(II), EDTA, and oxalate(II) did not influence the determination of Ag(I) ion, except Cu(II) ion.

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Studies on the Microbial Glucose Isomerase Part 2. Culture Conditions of Streptomytes sp. K-14 in Producing Glucose Isomerase (미생물의 포도당 이성화효소에 관한 연구 (제2보) Streptomyces sp. K-14 균주의 배양특성에 하여)

  • Tai Wha Chung;Moon H. Han
    • Microbiology and Biotechnology Letters
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    • v.4 no.4
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    • pp.145-151
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    • 1976
  • Cultural characteristics of a strain of Streptomyces sp. K-14 (KFCC 35051) producing glucose isomerase were demonstrated. The glucose isomerase was produced when the strain was grown in the medium containing pure xylan or xylan.containing materials such as wheat bran or com cob. The optimum condition was attained in a culture medium composed of 3 % wheat bran or com cob, 2 % com steep liquor, 0.1% $MgSO_4$$7H_2O$ and 0.012 % $CoSO_4$$7H_2O$ for the production of the glucose isomera,e. The production of the enzyme reached to a maximum level when the strain was cultured for 40 hrs $30^{\circ}C$ and pH 7.0.

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Studies on the Artificial Cultivation of Lentinus edodes on sawdust media (표고버섯 톱밥 인공재배(人工栽培)에 관(關)한 연구(硏究))

  • Kim, Han-Kyung;Park, Yong-Hwan;Cha, Dong-Yule;Chung, Hwan-Chae
    • The Korean Journal of Mycology
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    • v.15 no.1
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    • pp.42-47
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    • 1987
  • 4 strains of the oak mushroom Lentinus edodes including the strain ASI 3046 were collected home and abroad to investigate the characterics of mycelial growth on synthetic media and sawdust media. The possibility of artificial culture of Lentinus edodes on media composed of different saw dusts and adding materials was investigated. Results were as follows: The optimum temperature for growth ranged from $22^{\circ}C$ to $26^{\circ}C$ among the lineages of Lentinus edodes. The optimal growth temperature for ASI 3046 strain and ASI 3047 strain was $26^{\circ}C$ and $22^{\circ}C$, respectively. The optimal carbon source for ASI 3046 strain was glucose, and peptone and ammoinum tartrate were proved excellent as nitrogen sources. When Lentinus edodes was cultured on sawdust media by varying the mixing ratio of different sawdusts and adding materials, mixed sawdust media composed of oak sawdust(50%, v/v), poplar sawdust(50%, v/v), acorn powder(5%, v/v) and rice bran(10%, v/v) showed higher yields of fruit bodies. Results showed that the ideal strain of Lentinus edodes for artificial culture on sawdust media was strain ASI 3046.

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Eeffect of Wood Xylem Flour in Liquid Culture on Mycelial Biomass of Lentinus lepideus and Lentinus edodes (목분 첨가 액체배양에 의한 잣버섯 및 표고 균사배양의 촉진 효과)

  • Lee, Wi-Young;Ahn, Jin-Kwon;Park, Eung-Jun;Ka, Kang-Hyeon
    • The Korean Journal of Mycology
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    • v.36 no.1
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    • pp.45-50
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    • 2008
  • This study was carried out to investigate the promoting effect of wood flour on the mycelial growth of Lentinus lepideus and Lentinus edodes. To determine the optimal culture condition, we first examined the tissue origin of pine flour (Pinus densiflora) including needle, bark, root and xylem. Only the xylem-derived flour increased mycelial growth compared to no treatment control. The addition of the xylem flour (5 g/l) showed the highest increase and the glucose level in the basal medium was best at 10 g/l. The smaller particle size of the xylem flour showed the positive effect on mycelial growth; two-fold increase when supplemented with flour of which particle size is less than $106\;{\mu}m$ in diameter compared to $425\;{\mu}m$. The addition of the xylem flour continuously increased the mycelial production for 25 days while mycelia stopped growing within 15 days without the xylem flour. In addition, when woody flour obtained from the different tree species was applied to L. edodes mycelial culture, all treatments accelerated mycelial production compared to the control. Based on all results described above, we conclude that the supplementation of woody flour to culture medium may be an another promising way to increase mycelial production of economically important fungi.

Isolation and Characterization of Cathepsin B inhilbitor Produced by Streptomyces luteogriseus KT-10 (Streptomyces luteogriseus KT-10 이 생산하는 Cathepsin B 저해물질의 분리 및 특성)

  • 한길환;김상달
    • Microbiology and Biotechnology Letters
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    • v.29 no.2
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    • pp.84-89
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    • 2001
  • Isolation and Characterization of Cathepsin B inhibitor Produced by Streptomyces luteogriseus KT-IO. Han, Kil~Hwan and Sang~Dal Kim*. Department of Applied Microbiology, Yeungnam Universit}/t Kyongsan 712749, Korea - The cathepsin B inhibitor produced by Streptomyces luteogriseus KT-IO was very stable in heat, acidic and alkaline conditions. The cathepsin B inhibitor was isolated from the extracted fraction of culture broth with butanol, methanol and chloroform subsequently, the inhibitor was purified with following several column chromatography sLlch as DEAE-Sephadex A-25, Sephadex G-15, silica gel 60, Sephadex LH-20, and preparative HPLC. The cathepsin B inhibitor showed positively to detective reaction of ninhydrine, 5% H2S04, iodine, but negatively to the reaction of Ehrlich's reagent, DNS, aniline. The molecular formular of cathepsin B inhibitor was elucidated by JR, lH and 13C-NMR, FAB mass and elemental analyzer. Consequently, it was identified as C4HlI04N6. The cathepsin B inhibitor had the mode of competitive inhibition with the reaction of cathepsin B.

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