• Title/Summary/Keyword: 탄산암모늄

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Gas Production of Chemical Leavening Agents and Effects on Textures of Cookies (화학 팽창제의 가스 발생과 쿠키의 텍스쳐 비교)

  • Yang, Seong-Yeon;Kim, Sang-Yong;Jang, Kyu-Seob;Oh, Deok-Kun
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1131-1137
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    • 1997
  • The production rates of leavening gases and textures of cookies were investigated with various chemical leavening agents(baking powders). The chemical leavening agents could be divided into three group of a fast-acting group such as potassium bicarbonate, tartaric acid, aluminium ammonium sulfate, and fumaric acid, a slow-acting group such as ammonium bicarbonate, sodium bicarbonate, $glucono-{\delta}-lactone$, and ammonium chloride. and a double-acting group such as anhydro monocalcium phosphate, disodium dihydrogenpyrophosphate, and aluminium potassium sulfate according to the different production rate of gases. The leavening rate of ammonium bicarbonate, which was the highest of all leavening agents used in this experiment, was 131.25%. But its after-taste in a cookie was not good due to the residual ammonia. $Glucono-{\delta}-lactone$ only had no after-taste. The higher leavening rate, the more peaks in texture profile graph. Ammonium bicarbonate showed the most peaks in this experiment. It was found that the number of peak had correlation with brittleness of cookies $(r^2=0.8176)$ and brittleness of cookies was different as to various chemical leavening agents.

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Characteristic of Leaching with Incineration Fly Ash of Industrial Solid Wastes (산업폐기물 소각장에서 발생된 소각비산회의 침출특성)

  • 양종규;김종화;서명교;고태규
    • Resources Recycling
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    • v.8 no.1
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    • pp.18-22
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    • 1999
  • In order to utilize incineration fly ash of industrial wastes as resources, we present the recovery and separation of metals included in the fly ash by leaching with aqueous solution A great quantity of Cu, Pb, and Zn as well as a small amount oftoxic heavy metals are contained in the leach liquor of the fly ash, and the concentration of the ingredients of the fly ash depends on the industrial wastes which are fed into incinerators. In this paper, sequential Ieachiog operations are conducted using $H_2O$, $H_2SO_4$, $(NH_4)_2CO_3$ and NaOH as Icachants. Water soluble copper salt was leached by $H_2O$, Zn and Pb were separated by the NaOH leach liquor, and water insoluble copper was selectively leached as chelate ion with the $(NH_4)_2CO_3$ leach liquor of the third Ieaehant. Results show that the reduction percent of the fly ash in the leaching steps using $H_2O$, $H_2SO_4$, and $(NH_4)_2CO_3$ is 77%, and the other leaching procedures lose the weight of fly ash by above 60%.

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Design and Evaluation of Portable Forward Osmosis Desalination Device (휴대용 정삼투 담수화 장치의 설계 및 평가에 관한 연구)

  • Park, Chul-Woo;Kang, Ho;Jung, Dongho;Cha, Jaechul;Kim, Daejoong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.3
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    • pp.301-305
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    • 2013
  • This study aims to design a portable desalination device and discusses the feasibility of the device for overcoming a shortage of safe drinking water. A low-energy, self-supporting, and portable desalination device is designed based on forward osmosis (FO) using an ammonium bicarbonate solution. Experiments with various concentrations of ammonium bicarbonate solution and sodium chloride solution showed that the portable desalination device's performance such as volume and flow rate of desalting water and time required satisfied drinking water standards. The device performance is controlled by varying the concentration and temperature of the solution.

A Study on Enzyme-induced Carbonate Precipitation Technique for Soil Reinforcement without Releasing an Environmental Contaminant (환경 유해 부산물 누출이 없는 지반 보강용 효소 기반 탄산칼슘 침전 기법 연구)

  • Lee, Seung-Hyung;Kim, Jong-Min
    • Journal of the Korean Geotechnical Society
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    • v.37 no.4
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    • pp.39-47
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    • 2021
  • Recently, the enzyme-induced carbonate precipitation (EICP) technique has been considered as one of the alternatives to the cement-based soil reinforcing method. However, the problem with the emission of ammonium ion has not been solved. In this study, an experimental study on the EICP without releasing an environmental contaminant (Ze-EICP) is performed using calcium-exchanged zeolite. The results show that the Ze-EICP using calcium-exchanged zeolite reduced the amount of ammonium ions by 96.96% and precipitated almost the same amount of calcium carbonate, compared to the EICP using calcium chloride. In addition, the Ze-EICP shows higher strength improvement rate than the EICP due to densification of zeolite and cementation of calcium carbonate.

Crystallization of Neodymium carbonate from Neodymium Chloride Solution (염화네오디뮴 수용액으로부터 탄산네오디뮴 결정화)

  • Kim, Chul-Joo;Yoon, Ho-Sung;Kim, Joon-Soo;Lee, Seung-Won
    • Resources Recycling
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    • v.16 no.2 s.76
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    • pp.23-31
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    • 2007
  • In this study, the crystallization of neodymium carbonate from neodymium chloride solution by addition of ammonium bicarbonate was investigated. The concentration of reactants such as neodymium chloride and ammonium bicarbonate, and reaction temperature play an important part in order to obtain the crystal of neodymium carbonate. It seemed that amorphous neodymium carbonate was prepared by aggregation of primary particles formed through nucleation. If reaction rate was increased by increasing the concentration of reactants and reaction temperature, then neodymium carbonate crystal could be obtained. Lanthanite-type neodymium carbonate[$Nd_2(CO_3)_3{\cdot}8H_2O$] and tengerite-type neodymium carbonate[$Nd_2(CO_3)_3{\cdot}2.5H_2O$] could be obtained with reaction renditions. Lanthanite-type neodymium carbonate was sensitive to temperature. The thermal decomposition of neodymium carbonate contained the processes or dehydration, decarbonation and crystalization of $Nd_2O_3$. The shape of lanthanite-type neodymium carbonate was irregular lump type, and tengerite-type neodymium carbonate had the shape of needle type. The shape of $Nd_2O_3$ was affected by the shape of neodymium carbonate.

Performance Evaluation of Absorbent Solution for Draw Solute Recovery in Forward Osmosis Desalination Process (정삼투식 담수공정의 유도용질 회수를 위한 흡수용액 성능 평가)

  • Kim, Young;Lee, Jong Hoon;Lee, Kong Hoon;Kim, Yu-Chang;Oh, Dong Wook;Lee, Jungho
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.240-244
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    • 2013
  • Although forward osmosis desalination technology has drawn substantial attention as a next-generation desalination method, the energy efficiency of its draw solution treatment process should be improved for its commercialization. When ammonium bicarbonate is used as the draw solute, the system consists of forward-osmosis membrane modules, draw solution separation and recovery processes. Mixed gases of ammonia and carbon dioxide generated during the draws solution separation, need to be recovered to re-concentrate ammonium bicarbonate solution, for continuous operation as well as for the economic feasibility. The diluted ammonium bicarbonate solution has been proposed as the absorbent for the draw solution regeneration. In this study, experiments are conducted to investigate performance and features of the absorption corresponding to absorbent concentration. It is concluded that ammonium bicarbonate solution can be used to recover the generated ammonia and carbon dioxide. The results will be applied to design and operation of pilot-scale forward-osmosis desalination system.

Production of Alumina with High Purity (고순도 알루미나의 제조)

  • Song, Si Jeong;Lee, Man Seung
    • Resources Recycling
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    • v.28 no.1
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    • pp.15-22
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    • 2019
  • There are three hydrometallurgical methods by which pure alumina can be prepared, such as hydrolysis of aluminum alkoxides, thermal decomposition of ammonium alum and thermal cracking of ammonium aluminum carbonate (AACH). The effect of solution pH and temperature and the nature of the impurities on the phase transition and the purity of the alumina thus produced was investigated. Hydrolysis of aluminum alkoxides and thermal decomposition of ammonium alum produce ${\alpha}$ and ${\gamma}$ alumina, while only ${\alpha}$ alumina can be produced by thermal cracking of AACH.

Mineral Carbonation of Serpentinite: Extraction, pH swing, and Carbonation (사문암(Serpentinite)을 이용한 광물탄산화: Mg 추출과 pH swing 및 탄산화)

  • LEE, Seung-Woo;Won, Hyein;Choi, Byoung-Young;Chae, Soochun;Bang, Jun-Hwan;Park, Kwon Gyu
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.4
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    • pp.205-217
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    • 2017
  • Mineral carbonation by indirect method has been studied by serpentinite as cation source. Through the carbonation of $CO_2$ and alkaline earth ions (calcium and magnesium) from serpentinite, the pure carbonates including $MgCO_3$ and $CaCO_3$ were synthesized. The extraction solvent used to extract magnesium (Mg) was ammonium sulfate ($(NH_4)_2SO_4$), and the investigated experimental factors were the concentration of $(NH_4)_2SO_4$, reaction temperature, and ratio of serpentinite to the extraction solvent. From this study, the Mg extraction efficiency of approximately 80 wt% was obtained under the conditions of 2 M $(NH_4)_2SO_4$, $300^{\circ}C$, and a ratio of 5 g of serpentinite/75 mL of extraction solvent. The Mg extraction efficiency was proportional to the concentration and reaction temperature. $NH_3$ produced from the Mg extraction of serpentinite was used as a pH swing agent for carbonation to increase the pH value. About 1.78 M of $NH_3$ as the form of $NH_4{^+}$ was recovered after Mg extraction from serpentinite. And, the main step in Mg extraction process of serpentinite was estimated by geochemical modeling.

Partial Nitrification of Wastewater with Strong N for Anaerobic Nitrogen Removal (혐기성 질소제거를 위한 고농도 질소폐수의 부분질산화)

  • Hwang, In-Su;Min, Kyung-Sok
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.4
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    • pp.414-420
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    • 2006
  • Effluent from an anaerobic digestion system with an elutriated phased treatment(ADEPT, Anaeorbic Digestion Elutriated Phase Treatment) for piggery waste treatment using anaerobic ammonium oxidation(ANAMMOX) process was used as a substrate of partial nitrification reactor. In mesophilic condition($35^{\circ}C$), controlling parameters of nitrite accumulation were HRT, pH, free ammonia(FA) and hydroxylamine rather than dissolved oxygen. Bicarbonate alkalinity consumption ratio including bicarbonate stripping and buffering was 8.78 g $Alk._{comsumed}/g\;NH_4-N_{converted}$. In steady state for 1 day of HRT and $2.7{\sim}4.4mg/L$ of DO, $NO_2-N/NH_4-N$ ratio of partial nitrification effluent was about $1{\sim}3$, which was applicable to ANAMMOX reactor influent for the combined partial nitrification-ANAMMOX process.

Preparation of Nano Size Cerium Oxide from Cerium Carbonate (탄산(炭酸)세륨으로부터 나노크기 산화(酸化)세륨 제조연구(製造硏究))

  • Kim, Sung-Don;Kim, Chul-Joo;Yoon, Ho-Sung
    • Resources Recycling
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    • v.18 no.6
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    • pp.24-29
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    • 2009
  • Since cerium carbonate becomes porous cerium oxide by releasing carbon dioxide and vapour steam during calcination of cerium carbonate, nano size cerium oxide can be obtained by milling calcined cerium carbonate. Therefore cerium carbonate [$Ce_2(CO_3)3{\cdot}XH_2O$] is used generally for the preparation of nano size cerium oxide. In order to obtain nano size cerium oxide from cerium carbonate prepared by reactive crystallization of cerium chloride solution and ammonium bicarnonate solution, the effects of experimental variables in the milling and calcination of cerium carbonate, such as calcination temperature, milling time, rpm of planetary mill, amount of dispersant and ball size for milling on the size of cerium oxide was investigated in this study. Cerium oxide prepared with the conditions of calcination temperature of $700^{\circ}C$, milling time of 5 hour was 160nm mean particle size.