• Title/Summary/Keyword: 탄막

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기능성 마이크로스피어의 개발 EVA를 함유한 폴리우레탄 마이크로캡슐의 제조

  • 이희선;김경필;김혜인;박수민
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2003.04a
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    • pp.93-96
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    • 2003
  • 일반적으로 폴리우레탄계 마이크로캡슐은 양말단에 과량의 NCO기를 가지는 폴리우레탄 프리폴리머의 중합에 의한 것으로서, 이어서 수용액상에서 쇄연장제의 첨가에 의해 계면에서 완전한 폴리우레탄막을 중합하는 방법을 취하고 있다. 그러나 이러한 프리폴리머법에 의한 마이크로캡슐의 형성은 여러 가지 제조상의 문제점을 지니고 있다. Vanzo 등이 10$\mu\textrm{m}$이하의 작은 입자를 얻기 위해서는 비교적 고농도의 분산제와 높은 교반속도를 사용할 필요가 있었으며, 또한 그 입자크기분포의 제어가 어려웠다. (중략)

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A Design and Implementation of Dragon Dive Game (Dragon Dive 게임 설계 및 구현)

  • Park, Jin Yang;Jeon, Young Hwan
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2015.07a
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    • pp.59-60
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    • 2015
  • 본 논문에서는 XNA Framework 기반의 모바일 게임 Dragon Dive를 설계하고 구현한다. 이 모바일 게임은 종 스크롤 형식의 탄막 슈팅 게임의 방식을 채택하고 있으며 100초 동안 최대 점수를 획득하는 게임이다. 플레이어는 정해진 시간동안 화면 위에서 내려오는 3종류의 몬스터를 제거하고, 제거한 몬스터의 수에 따라 Dragon 캐릭터의 모양과 미사일의 연사 속도가 증가한다. 그리고 제거하지 못한 몬스터가 10마리이상 되면 게임이 종료된다.

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Aging Effect on the Antimicrobial Activity of Nanometal (Au, Ag)-Titanium Dioxide Nanocomposites (Aging 효과에 따른 나노메탈(Au, Ag)-이산화티탄 복합체의 항균 활성도)

  • Park, Hye-Rim;Lee, Sang-Wha;Yoo, In-Sang
    • Applied Chemistry for Engineering
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    • v.23 no.3
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    • pp.293-296
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    • 2012
  • Nanocomposites were fabricated as titanium dioxide ($TiO_2$) doped with nanometals (Au, Ag) by sonochemical reduction method and sol-gel method in order to investigate their antimicrobial activities. Then, the antimicrobial activity of the resulting samples was compared by the measurement of colony numbers survived on the agar plate incubated for 24 h after the loading E. coli on the solid-state media with the nanocomposites. The initial antimicrobial activity of the metal (Au, Ag)-doped $TiO_2$ was higher than that of the pristine $TiO_2$. Afterwards the nanocomposite samples were kept at $4^{\circ}C$ for a long time and the aged samples exhibited the different antimicrobial activity. With the elapse of aging times, Ag-doped $TiO_2$ with $TiO_2$ coating ($Ag-TiO_2$@$TiO_x$) exhibited the higher antimicrobial activity than those of $Ag-TiO_2$and $Au-TiO_2$. The $TiO_2$ coating on the $Ag-TiO_2$ may prevent the oxidation of Ag nanometals and stabilize colloidal nanocomposites.

Examining the Korean Wave Wanghong Media of China - Based on Viewing Satisfaction and Cultural Acceptance (한류 왕홍 미디어에 관한 연구 - 시청만족도와 문화 수용성을 중심으로)

  • Lin, Tang;Cho, Hee Jung;Lee, Hye Eun
    • The Journal of the Korea Contents Association
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    • v.20 no.5
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    • pp.105-117
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    • 2020
  • This study defined the Creators who produce video contents related to Korean Wave in the form of one-person media and takes an influential role in China as the 'Korean Wave(Hallyu) Wanghong Media'. This study aimed at examining the effects of viewing motivation and behavior on satisfaction and cultural acceptance. The survey was conducted on 240 respondents who have watched the contents on China's Bilibili video site. As a result, among five different motivations, the higher the level of 'cultural curiosity', 'entertainment', and 'empathy', the higher the satisfaction. Examining the effect of viewing behavior on satisfaction, 'frequency', the act of 'sharing' and 'participating' had positive effects. Furthermore, 'cultural curiosity' and 'satisfaction' were the factors of positive influence on cultural acceptance. The results of this study can enhance the understanding of Korean Wave Wanghong Media and further contribute to continuous development.

Controlled Drug Delivery through Poly(acrylic acid-g-urethane) Porous Membrane (폴리아크릴산이 그라프트된 다공성 폴리우레탄막을 통한 약물의 방출조절)

  • Kim, Jin Hong;Lee, Young Moo;Jung, Chung Nam
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.296-304
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    • 1992
  • Porous polyurethane membrane was prepared by the phase inversion process with variable permeability in response to pH and solvent composition. Hydrophilic polymers were grafted on the surface of the symmetric porous membrane. Porous polyurethane membrane was obtained in DMSO/methanol. It was subsequently grafted with acrylamide on the surface with ceric ammonium nitrate(CAN) as a initiator, followed by the hydrolysis to obtain poly(acrylic acid-g-urethane) (PAA-g-PU) membrane. The change in permeability of vitamine $B_2$(riboflavin) was investigated through PAA-g-PU. For PAA-g-PU membrane, permeability increased with the decrease in pH, and with an increase in solvent content in sink solution.

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Pervaporation Separation of Ethanol Aqueous Solution through Carbonate-type Polyurethane Membrane III. The Effect of Zwitterionic Group (카보네이트형 폴리우레탄막을 이용한 에탄올 수용액의 투과증발분리 III. 양쪽이온성기에 의한 영향)

  • Oh, Boo Keun;Lee, Young Moo;Noh, Si Tae
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.605-613
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    • 1992
  • NCO-terminated prepolymers were synthesized by reacting carbonate-type polyol(PTMCG)($M_w=1,000$ and 2,000) with MDI and N-methyldiethanolamine, as a chain extender. Carbonate-type polyurethane containg zwitterionic group was prepared by reacting the prepolymer with 1,3-propane sultone. From the IR and NMR spectra of model reactions, it was known that the ionization occurred under the same condition. The structure of zwitterionic carbonate-type polyurethane(ZPU) therefore could be confirmed from the model reactions. Glass transition temperature(Tg) ranged between $-15{\sim}-30^{\circ}C$ from the thermal data. Tg was between $-15{\sim}-18^{\circ}C$ for a series of ZPU10 samples and between $-25{\sim}-26^{\circ}C$ for a series of ZPU20 polymers. Tensile strength increased with mole ratio of ionic content. On the contrary, elongation was rather dropped with mole ratio of ionic content. ZPU10-30 having better tensile strength and less elongation was selected as a membrane for the concentration of ethanol aqueous solution through pervaporation. To obtain the better selectivity, it was crosslinked with HMDI. In the swelling test, it showed the higher swelling degree at around 50wt% ethanol concentration due to the plastization effect of ethanol. To optimize the separation capacity, two operating factors-feed concentration and temperature-were considered. The overall separation capacity was as follows : separation factor, 2~83.2 ; the flux, $25.4{\sim}58.8g/m^2hr$.

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Pervaporation Separation of Ethanol Aqueous Solution through Carbonate-type Polyurethane Membrane II. The Effect of Pendent Anionic Group (카보네이트형 폴리우레탄막을 이용한 에탄올 수용액의 투과증발분리 II. 음이온성기에 의한 영향)

  • Han, In Ki;Oh, Boo Keum;Lee, Young Moo;Noh, Si Tae
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.595-604
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    • 1992
  • Carbonate-type polyurethane resins containing anionic moieties were systhesized from NCO-terminated prepolymer method. Membranes were manufactured from the polymer solution and the separation of aqueous ethanol solution was investigated. To enhance the property of urethane resin, carbonate-type polyol(PTMCG) was used. ${\alpha}^{\prime},{\alpha}^{{\prime}{\prime}}$-dimethylolpropionic acid was used as a chain extender to increase the hydrophilicily of the urethane membrane. The ionization of the pendent carboxylic groups in urethane resin was carried out using trimthylamine. To confirm the formation of anionic groups in urethane resin, IR spectra of model compounds were compared with those of urethane resins. It was confirmed that the concentration of hard segment and hydrogen bond contributed to the property of the concentration of hard segment and hydrogen bond contributed to the property of urethane resin in which the mole ratio of chain extender and polyol was from 3:1 to urethane resin in which the mole ratio of chain extender and polyol was from 3:1 to 5:1. The carbonate-type polyurethane containing pendent carboxylic grop(PU) had Tg of around-$25^{\circ}C$ and Tm, $45^{\circ}C$ measured by DSC. Transition temperatures of one containing pendent anionic group(APU) prepared from the ionization of PU shifted to $8{\sim}10^{\circ}C$ lower temperature region than those of PU. Pervaporation membrane was prepared through the casting method. N, N-dimethylformamide (DMF) were used as a solvent and hexamethylene diisocyanate(HMDl) as a crosslinking agent. Swelling degree increased with ethanol concentration in mixure and the control of the swelling degree of the membrane could be achieved by crossliking. The results of pervaporation were as follows : separation factor, 2.3~9.8 ; flux, $27{\sim}79.5g/m^2hr$. Pervaporation separation capacity could be enhanced by reducing the molecular weight of polyol from 2,000 to 1,000.

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