• Title/Summary/Keyword: 키랄전구체

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The diastereoselective synthesis of 2-methyl-5(S)-hexanolide (Carpenter bee pheromone의 2-methyl-5(S)-hexanolide의 부분 입체선택적 합성)

  • Chang, Jay-Hyok;Lee, Sang-Jun;Kim, Jung-Han
    • Applied Biological Chemistry
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    • v.37 no.1
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    • pp.25-29
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    • 1994

  • 2-methyl-5(S)-hexanolide(1); the major component of pheromonal blend of the male carpenter bee was synthesized via Homer-Emmons reaction from Ethyl(S)-3-hydroxybutyrate(2a) which had been obtained by Baker's Yeast reduction in overall yield 39%.

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