• 제목/요약/키워드: 크롬 합금$LaCrO_3$ 분산

검색결과 1건 처리시간 0.017초

고체 산화물 연료전지용 Cr계 금속 연결재 제조 및 특성 연구 (Fabrication and Characterization of Cr Alloy for Metallic Interconnect of Solid Oxide Fuel Cell)

  • 송락현
    • 한국수소및신에너지학회논문집
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    • 제16권1호
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    • pp.58-65
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    • 2005
  • The $LaCrO_3$-dispersed Cr alloys for metallic interconnect of solid oxide fuel cell were prepared as a function of $LaCrO_3$ content in the range of 5 to 25 vol.% and were sintered at 1500$^{\circ}C$ under an Ar atmosphere with 5 vol.% $H_2$. The sintering and oxidation behaviors of these alloys were examined. The alloys indicated a good sinterability above 95% relative density at a given sintering condition, and their sintering densities is independent on $LaCrO_3$ content. The $LaCrO_3$ particles of the sintered alloys were concentrated on interfaces of Cr particles, and the size of the Cr particles increased with decreasing $LaCrO_3$ content, which is caused by inhibited grain growth of Cr particle by $LaCrO_3$ particle. The oxidation test showed all $LaCrO_3$-dispersed Cr alloys have good oxidation resistance as compared with pure Cr, which is attributed to presence of $LaCrO_3$ at the interface at which the oxidation reaction occurs rapidly. The Cr alloys with about 15 vol.% $LaCrO_3$ are very resistant to oxidation.