• Title/Summary/Keyword: 컬럼 실험

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황산을 이용한 동전기적방법에 의한 방사능오염토양 복원 연구

  • 오원진;김계남
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.2
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    • pp.145-153
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    • 2004
  • H$_2$SO$_4$ and citric acid were used as additives for the electrokinetic remediation experiment to increase removal efficiency of $^{137}$ Cs and $^{60}$ Co from the radioactive soil waste stored for more than 10 years. The average effluent velocity discharged from the elctrokinectic remediation experimental column was 2.0${\times}$10$^{-2}$ cm/min and the discharged soil wastewater volume for 10 days is 3.6 pore volume of the column. 97% of $^{60}$ Co in the column was decontaminated for 10 days of operation, while only 54% of $^{137}$ Cs was decontaminated. These results are considered that the absorption equilibrium coefficient of $^{137}$ Cs is higher than that of $^{60}$ Co. The predicted values of the residual concentration by the proposed mathematical model were well coincided with the experimental results within the experimental error range

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A Study on the Effects of Heat Pump Using Standing Column Well on Soil and Groundwater Microorganisms (스탠딩컬럼웰을 적용한 지열히트펌프의 토양 및 지하수 미생물에 대한 영향 연구)

  • Jun, Jungeui;Park, Sisam;Na, Sangmin;Rhee, Keonjoong;Park, Jaewoo
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.7
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    • pp.93-101
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    • 2009
  • Standing column well (SCW) heat pump system produces geothermal energy by the heat exchange of the groundwater. If SCW system changed the temperature of soil and groundwater, it could also change species or population of microorganisms. Therefore it is needed to research about the effect of temperature change on microorganisms to use eco-friendly geothermal energy. We produced the simulative heat pump system (SHPS) and observed the change of the soil temperature in SHPS. Characteristic analysis of microorganisms isolated from soil was performed and groundwater temperature variation was evaluated. Also the bleeding effect in SHPS was investigated and the results are included. As the results, the population of microorganisms was increased about 90%, as the groundwater temperature increased 2-3 celsius degree. However the species of microorganism was little influenced by the temperature change of the soil.

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The Evaluation on the Environmental Effect of Coal-Ash and Phosphogypsum as the Evapotranspiration Final Cover Material (증발산 원리를 이용한 매립장 최종 복토공법의 복토재로서 석탄재와 인산석고의 환경적 영향 평가)

  • Yu, Chan;Yang, Kee-Sok
    • Journal of the Korean GEO-environmental Society
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    • v.6 no.1
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    • pp.15-21
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    • 2005
  • In this study, the utilization of coal-ash and phosphogypsum was considered as the evapotranspiration final landfill cover(ET cover) material. Cover material considered was the mixture of the weathered granite soil, coal-ash and phosphogypsum and so we sequentially performed the leaching test, column test and field model test to investigate the environmental effects of mixtures of coal-ash and phosphogypsum. In the leaching test, all materials had lower heavy metal concentration than the regulated threshold values. The column test and the review of related regulations were carried out to determine the optimum mixing ratio(OMR) and OMR was soil(4):coal-ash(1): phosphogypsum(1) on the volume base, which was applied to field model test. Field model tests were continued from February to June, 2004 in the soil box that was constructed with cement block. It was verified that coal-ash and phospogypsum mixed with soil was safe environmentally and the mixture of both wastes could improve the water retention capacity of cover materials.

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Shadow Recovery for Column-based Databases (컬럼-기반 데이터베이스를 위한 그림자 복구)

  • Byun, Si-Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.4
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    • pp.2784-2790
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    • 2015
  • The column-oriented database storage is a very advanced model for large-volume data transactions because of its superior I/O performance. Traditional data storages exploit row-oriented storage where the attributes of a record are placed contiguously in hard disk for fast write operations. However, for search-mostly data warehouse systems, column-oriented storage has become a more proper model because of its superior read performance. Recently, solid state drive using flash memory is largely recognized as the preferred storage media for high-speed data analysis systems. In this research, we propose a new transaction recovery scheme for a column-oriented database environment which is based on a flash media file system. We improved traditional shadow paging schemes by reusing old data pages which are supposed to be invalidated in the course of writing a new data page in the flash file system environment. In order to reuse these data pages, we exploit reused shadow list structure in our column-oriented shadow recovery(CoSR) scheme. CoSR scheme minimizes the additional storage overhead for keeping shadow pages and minimizes the I/O performance degradation caused by column data compression of traditional recovery schemes. Based on the results of the performance evaluation, we conclude that CoSR outperforms the traditional schemes by 17%.

Removal of Dissolved Heavy Metals through Biosorption onto Indigenous Bacterial Biofilm Developed in Soil (토양 내 토착 미생물에 의한 바이오필름 형성과 흡착을 통한 용존 중금속 제거)

  • Kim, Sang-Ho;Chon, Hyo-Taek;Lee, Jong-Un
    • Economic and Environmental Geology
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    • v.42 no.5
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    • pp.435-444
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    • 2009
  • In situ stabilization of heavy metals through adsorption onto indigenous bacterial biofilm developed on soil particles was investigated. Biofilms were developed in soil columns by supply of various carbon sources such as acetate, lactate and glucose. During development of biofilms, acetate, lactate, and glucose solutions were flew out from the soil columns with volume ratios of 98.5%, 97.3%, and 94.7%, respectively, when compared with soil column supplied with deionized water. Decrease in effluent amounts through the soil columns amended with carbon sources over time indicated the formation of biofilms resulting in decrease of soil porosity. Solutions of Cd, Cr(VI), Cu, Pb, and Zn were injected into the biofilms supported on soil particles in the columns, and the dissolved heavy metals in effluents were determined. Concentrations of dissolved Cd, Cr(VI), Cu, and Zn in the effluents through biofilm columns were lower than those of control column supplied with deionized water. The result was likely due to enhanced adsorption of the metals onto biofilms. Efficiency of metal removal by biofilms depended on the type of carbon sources supplied. The enhanced removal of dissolved heavy metals by bacterial biofilms in this study may be effectively applied to technical development of in situ stabilization of heavy metals in natural soil formation contaminated with heavy metals.

Evaluation of accuracy for measurement of Dioxins (PCDDs/PCDFs) by using certified reference material (CRM) (인증표준물질(Certified reference materials, CRM)을 이용한 이옥신류(PCDDs/PCDFs) 측정의 정확도 평가)

  • Youn, Yeu Young;Park, Deok Hie;Lim, Young Hee;Cho, Hye Sung
    • Analytical Science and Technology
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    • v.22 no.5
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    • pp.376-385
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    • 2009
  • In our study, the accuracy for measurement of seventeen 2,3,7,8-substituted PCDDs/PCDFs in certified reference material (CRM) which is the sample of homogeneous sediment matrix taken from an area known to have significant chemical contamination, particularly PCBs (polychlorinated biphenyls), was evaluated. Though the methodology in this study followed the official method of unintentionally produced persistent organic pollutants (UPOPs) announced by the Ministry of Environment of the Republic of Korea in 2007, there were slight changes using additional purification step by activated carbon column because the interferences of sample were not sufficiently removed when only multi-silica column and alumina column have been used for purification. The |En| number proposed by the Korea Research Institute of Standards and Science was used for a valuation basis of the accuracy. The |En| numbers of seventeen 2,3,7,8-substituted PCDDs/PCDFs have been indicated as 1 and below, they were decided "Pass" in this test, when DB-5MS column and SP-2331 column were used together. Because 1,2,3,7,8-PeCDD and #169-HxCB were not separated on DB-5MS column, the ions of 1,2,3,7,8-PeCDD were selected at M/M+2 instead of M+2/M+4 suggested by EPA 1613. It is possible to distinguish them in HRGC/HRMS analysis.

Mineralogical and Geochemical Changes During the Reaction of Cr(VI) with Organic Carbon (6가 크롬과 유기탄소와의 반응에 따른 광물학적 지구화학적 변화)

  • Kim, Yeongkyoo;Park, Young-Gyu
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.3
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    • pp.151-160
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    • 2013
  • A column experiment was carried out to study the reaction of Cr(VI) with organic carbon. Chemical analysis for the effluent collected at different times after the reaction of Cr(VI) with organic carbon in compost and SEM observation for the solid samples remaining after the reaction were conducted. Cr(VI) supplied to the column was not detected in the effluent from column at initial stage, but the concentration of Cr(VI) increased abruptly and maintained the initial supplied concentration (20 mg/kg), indicating that Cr(VI) was effectively removed from the solution at the first state. In general, the concentrations of cations and anions with the exception of $PO_4$ increased and decreased again. Considering that most of these ions were not detected or showed very low concentration, these ions are considered to originate from the organic carbon in the column. SEM observation showed that Cr was coprecipitated with Fe on the surface of organic carbon with small amount of other metals such as Mn, No, and Co. This indicated that on the reduction condition on the organic carbon, Cr(VI) was reduced to $Cr(OH)_3$ and coprecipitated with $Fe(OH)_3$, and that Fe is very important in the precipitation of Cr. After the soluble Fe and Mn are not dissolved any more, $Cr(OH)_3$ is not precipitated. Different from other ions, the concentrations of $PO_4$ decreased and increased, which was thought to be the result of the release of $PO_4$ from organic carbon and sorption on the precipitates. After the maximum sorption on the precipitates and no further release of Fe, the concentration of $PO_4$ returns to its original value measured for the ones released from the organic carbon.

Fundamental Study on Adsorption Capacity and Utilization of Coal Waste as Adsorbents (석탄폐석의 흡착능 및 흡착제로의 활용방안에 관한 기초 연구)

  • 한동준;임재명;이찬기;이해승
    • Journal of Korea Soil Environment Society
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    • v.2 no.2
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    • pp.61-72
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    • 1997
  • This research aims to remove the heavy metals, nonbiodegradable COD(NBDCOD), and color using the coal waste. The experimental by heat treatment was performed to advance the adsorption capacity. The results are as follows ; i) The coal waste had the adsorption capacity of heavy metals and the rates were in the range of 20 to 30 percents. ii) The heat treatment was the optimum condition that the reaction time was 6 hours at $500^{\circ}C$, , iii) In the column experimen, non-treated coal waste removed the COD and color in the range of 20 to 60 percents. iv) Heat-treated coal waste showed higher removal rate of the color in biological effluent, and heavy metal and COD removal rates were changed by the filteration rates.

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A study on soil drainage characteristics of undisturbed soil columns and their responses to rainfall (불교란 토양칼럼에서의 자연강우에 대한 토양배수특성 연구)

  • Lee Ju-Young;Lee Ki-Chul;Chon Chul-Min;Kim Jae-Gon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.379-382
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    • 2006
  • 본 연구에서는 다양한 토지이용의 불교란 토양칼럼 시료를 대상으로 토양 물리화학 특성 및 자연강우에 대한 토양배수 양상을 분석하였다. 공극률은 토양컬럼에서의 유효공극률과 투수계수 및 자연강우에 대한 배수율과 대체로 정의 상관관계를 보인다. 미국 통일분류법에 따라 토양을 분류하였을 때 소성성이 낮은 실트질 토양과 점토질 토양은 유효공극률이 낮으면서 배수율도 낮고, 소성성이 없는 실트질이 섞인 자갈(유구-논)과 실트질 모래는 유효공극률이 비교적 높으면서 배수율이 다소 높았다. 불교란 토양컬럼을 완전 포화상태에서 자연배수할 때 대부분의 토양은 50시간 전후로 거의 다. 배수되며 $150{\sim}200$시간 경과되면 거의 모든 토양에서 완전배수가 되었다. 일부 500여시간이 경과되어도 지속적으로 배수되는 토양이 있는데 이는 토양수분보유특성에 기인하는 것으로 사료된다. 배수량으로 가정한 함양량 실측실험에서는 오송(전의)임야 > 무주-밭, 무주-논 > 유구-임야 > 김해-밭 > 유구-논, 유구-밭 순으로 높았으며 이들 시료들의 함양률은 50% 이상이었다. 토성에 따른 자연강우 배수상태를 보면, 소성성이 낮은 실트질 토양의 배수율이 낮고, 실트질 모래는 다양한 배수상태를 보이나 대체로 배수율이 높다. 그리고 1차, 2차 실험에서 선행 강우 5mm 미만은 토양배수에 영향을 미치지 않았다.

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