• Title/Summary/Keyword: 칼슘용출

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Strength and Durability Characteristics of Low-alkali Mortar for Artificial Reefs Produced by 3D Printers (인공어초 3D 프린터 출력을 위한 저알칼리 모르타르의 강도와 내구성능)

  • Lee, Byung-Jae;Kim, Bong-Kyun;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.67-72
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    • 2022
  • Concrete prevents corrosion of reinforcing bars due to its strong alkalinity. However, in the sea, strong alkali components with a pH of 12 to 13 are eluted, which adversely affects the ecological environment and growth of marine organisms. In this study, the mechanical properties and durability of the low alkali mortar were evaluated for the development of a low alkali mortar for the 3D printed artificial reefs. As a result of evaluation of strength characteristics, the α-35 mixture, which were produced with fly ash, silica fume and α-hemihydrate gypsum, satisfied the strength requirement 27 MPa in terms of compressive strength. As a result of pH measurement, it was found that mixing with alpha-type hemihydrate gypsum resulted in minimizing pH due to the the formation of calcium sulfate instead of calcium hydroxide production. As a result of the chloride ion penetration resistance test, the α-35 mixture exhibited the best performance, 3844C. As a result of measuring the length change over time, the α-35 mixture showed the shrinkage 33.5% less compared to the Plain mix.

Study on the Morphological Change and Reduction Plan of Nitrogen and Phosphorous in Litter and Manure of Cow House (우사의 깔짚과 퇴비에 있는 질소와 인의 형태적 변화와 저감 방안에 관한 연구)

  • Kim, Younjung;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.65 no.4
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    • pp.249-253
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    • 2021
  • Litter and manure were obtained at a cow house of a livestock farm in Andondg city. We examined the change of formation of nitrogen and phosphorous from these samples and tried to suggest a more useful and realistic way for removing them. Constituent and its content of sample were identified by XRF. NO2-, NO3-, and PO43- ions and NH4+, T-P and T-N released from sample were analyzed using ion chromatograph and UV/Vis spectrometry, respectively. As the results of this study, the ammonia nitrogen in the early stage of cow excretion is a need to make an ammonia gas state that can be immediately volatile by increasing the pH. Nitrogen and phosphorous, the main source of nutrition in green algal bloom can be removed by transforming insoluble salts such as calcium phosphate (CaHPO4·3H2O) and struvite (NH4MgPO4·6H2O), respectively, with addition of Ca and Mg after stimulating fermentation of manure.

Antioxidant Activities of Cedrela sinensis Tender Leaf Powder Extracts obtained from Different Solvents (추출용매에 따른 참죽나무 순 분말 추출물의 항산화 활성)

  • Kim, Min Jung;Han, Young Sil
    • The Korean Journal of Food And Nutrition
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    • v.27 no.6
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    • pp.1059-1066
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    • 2014
  • In this study, the nutritional value, total polyphenol content, total flavonoid content, and antioxidant activity of freeze-dried Cedrela sinensis tender leaf powder were examined. Among the nutritional values, the crude protein, crude fiber, calcium, and potassium were abundantly present in Cedrela sinensis. The Cedrela sinensis powder was extracted with two solvents, 70% ethanol and distilled water (D.W.), to evaluate its functional properties. Total polyphenol and flavonoid contents were measured in the two different extracts, and the extracts were screened for their potential antioxidant activities using tests such as DPPH radical scavenging activity, ferric reducing antioxidant power (FRAP), and ABTS radical scavenging assay. Although both extracts exhibited good antioxidant activities against trolox, the ethanolic extract exhibited higher antioxidant activities than the D.W. extract. These results indicated that the Cedrela sinensis powder is a high-valued food ingredient and the extraction with 70% ethanol will be useful as a nutritional source with natural antioxidant activities.

A Study on the Quality Characteristics of Fish Stock by Additions of White Wine (백포도주를 첨가한 생선 육수의 품질 특성에 관한 연구)

  • Kang, Tae-Gu;Choi, Soo-Keun;Yoon, Hye-Hyun
    • Culinary science and hospitality research
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    • v.15 no.3
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    • pp.213-224
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    • 2009
  • The present study analyzed the sensory characteristics of fish stock, which is the base of seafood sauce, such as moisture, ash, pH, mineral, free amino acid and sensory properties according to the additions of white wine in order to improve its taste and nutrition using its effect on the minerals and free amino acid of fish bones. As white wine was added more, water and ash contained in fish bones increased and pH decreased. When 11.5% of white wine was added, minerals such as calcium, potassium and magnesium showed the highest contents; and when 7.7% of white wine was added, sodium and phosphorus showed the highest contents. The total amount of free amino acid and general acceptance were highest when 7.7% of white wine was added. The results of this study as presented above suggest that 7.7% of white wine is most appropriate in preparing fish stock.

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Effects of Sepiae os Addition on the Quality of Kimchi durong Fermentation (오적골(烏賊骨) 첨가가 김치의 이화학적 품질에 미치는 영향)

  • 이미정;김한수;이승철;박우포
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.4
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    • pp.592-596
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    • 2000
  • This study was carried out investigate the effect of sepiae as on the kimchi ferentation. Quality indices were pH, titratable acidity, reducing sugar content, microbial counts, and redness kimchi juice. Sepiae as retarded the decreasing rate of pH and the increasing rate of titratable acidity in kimchi during fermentation at 1$0^{\circ}C$, and the effect was more conspicouous at 1.5% than at 0.5%. Kimchi added with 1.5% sepiae as maintained a similar pH and titratable acidity after 5 days. Microbial counts of total and lactic bacteria were higher in sepiae os added kimchi than control control. Regardless of the of sepoae os, the redness of kimchi juice was gradually increased during storage.

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Development of the Dissolution Test for Dobesilate Calcium Tablets and Acepifylline Tablets (도베실산칼슘 정 및 아세피필린 정의 용출시험법 개발)

  • Park, Chan-Ho;Lee, Jin-Ha;Kim, Eun-Jung;Sohn, Kyung-Hee;Kim, Young-Ok;Kim, Dong-Sup;Song, Young-Me;Sah, Hong-Kee;Choi, Hoo-Kyun
    • YAKHAK HOEJI
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    • v.55 no.2
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    • pp.131-137
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    • 2011
  • The dissolution test method and an analytical procedure by HPLC were developed and validated for dobesilate calcium tablets and acepifylline tablets. These drugs were not yet characterized by the dissolution specifications in Korean Pharmaceutical Codex. So, with each reference and test drugs, we did the preliminary and standard experiments based on the Korean Pharmacopeia Guideline of dissolution testing for solid oral dosage forms. The dissolution test for dobesilate calcium tablets was carried out under sink conditions as following: dissolution medium water, paddle rotation speed 50 rpm and vessel volume 900 ml. More than 90% of its label amount was released within 30 min in this method. Also the dissolution test for acepifylline tablets was carried out under sink conditions as follows: dissolution medium water, paddle rotation speed 100 rpm and vessel volume 900 ml. More than 90% of its label amount was released within 45 min in this method. The dissolution samples were analyzed with a precise and accurate HPLC method. The developed dissolution test showed specificity, linearity, precision and accuracy within the acceptable range. The dissolution testing method described above was adequate for the purpose and may be proposed as a pharmacopeial standard to assess the performance of dobesilate calcium tablets and acepifylline tablets.

Salinity Content in Soil on Chemical Composition and Productivity of Rice in Reclaimed Saline Paddy Field (토양의 염분농도 차이가 벼의 수량에 미치는 영향)

  • 권병선;백선영;임준택;신동영;김학진;현규환;신정식
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2003.04a
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    • pp.79-82
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    • 2003
  • 대부분의 신 간척지 논은 점토 함량이 적은 반면 미사 함량이 많고 토양 콜로이드의 분산제 역할을 하는 Na함량이 높기 때문에 이러한 토양은 입단화가 저해되고 투수성이 불량해 진다. 이러한 투수와 더불어 다량의 SiO$_2$, F$_2$, MR, MgO 등이 하층으로 용출되어 투수성과 통기성을 저하시키고 간척지 토양의 토양 물리화학적 불량에 의한 저수확답의 원인의 되어 벼의 재배가 어렵고 생산성이 낮아 경제성을 기대하기 어렵다. (김, 1992 : 고건, 1988 ;단야, 1983 ; 전중등, 1974). 따라서 본 실험에서는 토양의 염분농도차이가 토양화학성과 수량에 미치는 영향을 검토하여 간척지 토양의 경제성을 높이는데 기초자료로 활용코자 시험한 결과는 다음과 같다. 1. 출수기는 0.1%의 염분농도 토양은 8월15일, 0.4%의 염분농도 토양은 8월 20일, 0.8%의 염분 농도 토양은 8월 25일로서 0.1%의 염분농도 토양이 가장 빨랐다. 2. 쌀수량은 토양의 염분농도가 0.1%로 낮은 토양이 599kg/10a로 가장 많았고, 다음으로는 0,4%의 염분농도 토양이 568kg/10a이었고 0.8%의 염분농도 토양은 446kg/10a로 가장 낮았으며 쌀수량 구성요소 역시 같은 경향으로 0.1%의 염분농도 토양에서 가장 우수하였고 다음으로는 0.4%, 0.8%순으로 나타났었다. 3. 쌀수량과 토양의 이화학적 특성간의 상관에서는 pH와는 부의 상관, 유기물, 인산, 질소, 가리, 칼슘, 마그네슘의 함량간에는 정의상관이있다. 4. 전남광양만 간척지에서 쌀수량과 수량 구성요소면에서 볼때에 적합한 토양의 염분농도는 0.1%이라고 사료된다.

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Effects of simulated acid rain on garlic in spraying copper hydroxide solution (쿠퍼 수화제 살포시 마늘에 미치는 인공산성비의 영향)

  • Chung, Bong-Jin;Lee, Seong-Dal;Myung, Eul-Jae;Kim, Yong-Tae;Kim, Seung-Ho
    • The Korean Journal of Pesticide Science
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    • v.6 no.3
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    • pp.175-182
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    • 2002
  • This experiment was conducted to investigate the effects of acid rain in spraying copper hydroxide 77% wettable power(WP) on leaf surface morphology and crop injury of the garlic(Allium sativum L.). Leaf chlorosis, hooked leaves, wrinkled epidermal cells and increased stomata open of garlic were induced by foliar application of simulated acid rain(SAR). It was become to be severe in application of copper hydroxide solution after application of SAR, but those yield of garlic was not significantly different from the untreated control. Leaf chlorosis was sharply increased above 100 ppm of copper ions. Amount of solved copper ions in copper hydroxide solution was remarkably increased below pH 5.5 and the residue in garlic leaves was significantly increased by application of copper hydroxide solution after spraying SAR compared with application of copper hydroxide solution only. When calcium carbonate was applied together with copper hydroxide leaf chlorosis was less than copper hydroxide only.

Evaluating the Effectiveness of In-Situ Carbonation in Floor Dry Cement Mortar Applications (바닥용 건조시멘트 모르타르 배합 내 In-situ 탄산화 적용을 위한 CO2 주입 특성 및 물리적 특성 검토)

  • Kim, Jin-Sung;Cho, Sung-Hyun;Kim, Chun-Sik
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.1
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    • pp.1-10
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    • 2024
  • In-situ carbonation technology represents a form of mineral carbonation that integrates CO2 into the fabrication process of cementitious construction materials, capturing CO2 as calcium carbonate(CaCO3) through a reaction between calcium ions(Ca2+) and CO2 released during cement hydration. This investigation examines the application of in-situ carbonation technology to a variety of floor dry cement mortar formulations commonly used in local construction projects. It assesses the effects of varying the CO2 injection flow rate and total volume of CO2 injected. Additionally, the study evaluates the impact of reducing the quantity of cement used as a binder on the final product's quality.

Trace Metals in Surface Sediments of Garolim Bay, Korea (가로림만 표층 퇴적물 내 미량금속 분포 특성)

  • PARK, KYOUNGKYU;CHOI, MANSIK;JOE, DONGJIN;JANG, DONGJUN;PARK, SOJUNG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.25 no.2
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    • pp.9-25
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    • 2020
  • In 2010 and 2015, total 77 surface sediment samples were collected to assess the anthropogenic effects of trace metals in surface sediments of Garolim Bay, and the physical characteristics (particle size and specific surface area) and geochemical components (major (Al, Ca, Fe, K, Ba) and trace metals (Mn, Cs, Cr, Co, Ni, Cu, Zn, Pb), organic carbon and calcium carbonate) were analyzed. Mean grain size of Garolim Bay surface sediments ranged from 0.51-5.58 Ø (mean 3.98 Ø) and increased from the inlet of bay to the inner bay, and from the waterway to the land. Most of the metal concentrations except for some elements showed the similar distribution to those of mean grain size and specific surface area. As the particle size decreased and the specific surface area increased, the metal concentration increased. In order to estimate the factors controlling the concentration of trace metals, factor analysis was performed, and three factors were extracted (92.7% of the total variation). Factor 1 accounted for 71.3% of the total variation, which was a grain size factor. Factor 2 accounted for 14.2% of the total variation, Factor 3 accounted for 7.2% of the total variance. Enrichment factor was calculated using the particle size corrected background concentration. Metals with a enrichment factor of 1.5 or higher and the number of samples were 4 for Cr (St. 1, 16, 27, 39) and 1 for Pb (St. 39), but there were little differences in the concentrations of 1M HCl leached metals for these metals. The percentage of 1M HCl leached fraction to total metal concentration decreased in the order of Pb~Co>Cu>Zn~Mn>Ni>Cr. Comparing this value with contaminated and clean sediments in other coastal areas, the percentages for each metal were similar regardless of the trace metal levels in all regions. This fact might be resulted from the reaction between the 1M HCl solution and the different sediment constituents, indicating that there is a limit to apply this percentage of leached metal to the estimation of the contamination extent.