• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.4
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• pp.180-188
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• 2013

The glass of E-glass fiber composition was fabricated by using refused coal ore which is obtained as by-product from Dogye coal mine in Samcheok. We used silica-alumina refused coal ore which has low carbon content relatively, and the amount of refused coal ore has been changed from 0 to 35 % in batch composition. E-glass was fabricated by the melting of mixed batch materials at $1550^{\circ}C$ for 2 hrs with different refused coal ore composition of 0~35 %. We obtained a transparent and clear glass with high visible light transmittance value of 81~84%, thermal expansion coefficient of $5.39{\sim}5.61{\times}10^{-6}/^{\circ}C$ and softening point of $851{\sim}860^{\circ}C$. The glass fiber samples were also obtained through fiberizing equipment at $1150^{\circ}C$, and tested chemical resistance and tensile strength to evaluate the mechanical property as a reinforced glass fiber of composite material. As the result, we identified the properties of E-glass fiber by using refused coal ore are plenty good enough compare to that of normal E-glass without refused coal ore, and confirmed the possibility of refused coal ore as for the raw material of E-glass fiber.

• Journal of the Korean Chemical Society
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• v.42 no.1
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• pp.122-134
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• 1998

In this review, we describe the electrochemical properties of spinel-type lithium manganese oxides $(Li_xMn_2O_4)$ and their failure modes encountered in 4 V lithium rechargable cells. The long-term cyclability (reversibility) of spinel electrodes is determined partly by the purity, size and distribution of spinel particles, and also by the microstructure of electrode plates. A proper selection of electrolytes is another important task in cyclability enhancements. In the spinel preparation, impurity formation and cation mixing should be minimized. The carbon content in composite cathodes should also be minimized to the extent where the cell polarization does not bring about adverse effects on cell performances. The binder content should be optimized on the basis of dispersion of component materials and mechanical strength of the plates. Cathodic capacity losses arising from solvent oxidation and spinel dissolution can be mitigated by using electrolytes composed of carbonates and/or fluorine-containing lithium salts. The carbon additives may be selected after a trade-off between the cell polarization in composite cathodes and the solvent oxidation on carbon surface.

• Composites Research
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• v.33 no.5
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• pp.296-301
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• 2020

Laminated composite materials have excellent in-plane properties, but are vulnerable in thickness directions, making it easy to delamination when bending and torsion loads are applied. Thickness directional reinforcement methods of composite materials that delay delamination include Z-pinning, Stitching, Tufting, etc., and typically Z-pinning and Stitching method are commonly used. The Z-pinning is reinforcement method by inserting metal or carbon pin in the thickness direction of prepreg, and the conventional stitching process is a method of reinforcing the mechanical properties in the thickness direction by intersecting the upper and lower fibers on the preform. In this paper, I-fiber stitching method, which complement and improve weakness of Z-pinning and Stitching method, was proposed, and the static strength of composite single-lap joints using I-fiber stitching process were evaluated. The single-lap joints were fabricated by a co-curing method using an autoclave vacuum bag process. The thickness of the composite adherend was fixed, and 5 types of specimens were manufactured with varying the stitching pattern (5×5, 7×7) and angle (0°, 45°). From the test, the failure load of the specimen reinforced by the I-fiber stitching process was increased by up to 143% compared to that of specimen without reinforcement.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.58-58
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• 2011

CNT 나노기술을 응용한 IT산업용 적층간지용 ESD(정전방전, Electrostatic Dissipation)PU 발포필름의 제조 가공기술 및 상품화 개발은 전자제품 패키지에 요구되는 쿠션성과 정전방전 기능을 갖는 폴리우레탄 발포 필름의 제조기술을 확립함으로써 가능 할 수 있다. 특히 IT산업용 필름제품이 개발되면 ESD 성능을 발휘하게 됨으로서 정전기 쇼크에 의한 각종 전자제품의 오작동이나 파손 방지가 가능하게 되어 포장재, 자동차, 전자제품의 하우징 등으로 사용될 수 있게 된다. 현재까지 ESD 기능을 부여하기 위해서 사용되는 충전재로는 금속섬유, 금속플레이크, 탄소섬유, 카본블랙 등이 있으며, 최근 탄소나노튜브를 응용한 연구가 많이 진행되고 있는데 탄소나노튜브는 직경이 수십nm, 종횡비 1000이상의 나노섬유형태로 서 전기전도성이 구리수준으로 알려져 있고 소량을 충전할 시 기계적 특성도 오히려 증대하는 장점을 가지고 있으며 전기적 특성으로는 상대적으로 낮은 나노튜브 함량에서는 ESD를 들 수 있고 높은 함량에서는 전자파 차폐성까지 기대되고 있다. 본 연구에서는 우수한 인장강도, 기계적 강도, 열적 안정성, 내약품성을 가지면서 습식 또는 용융공정을 통해 용이하게 시트, 필름, 코팅제를 제조할 수 있는 방수, 투습방수성을 가지는 유연재료인 폴리우레탄(PU) 1액형 PU에 MWNT 함량이 3wt%인 IPA/MWNT 분산용액을 PU 함량 대비 20, 30, 40파트로 함유시켜 $120^{\circ}C$에서 2분 건조시켜 제조한 그라운드 필름에 2액형 PU와 IPA/MWNT 분산용액에 발포제를 첨가하여 발포온도 140, 150, $160^{\circ}C$에서 5분간 건조시켜 시료 필름을 제조하였다. 제조된 필름의 전기전도성 측정은 부피저항과, 표면저항을 각각 측정하여 확인하였으며, 필름의 마찰 대전압은 E.S.T-7 마찰 대전압 시험기를 이용하여 표면 마찰 대전압과 반감기를 측정하여 확인하고, 필름의 물리적 특성은 인장시험기를 이용하여 breaking stress, breaking strain을 구하였다. 필름의 표면 특성은 영상 현미경 시스템을 사용하여 ${\times}1000$ 배율로 측정하여 분산특성과의 연관성을 확인하였다.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.5
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• pp.491-497
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• 2015

This paper reports an experimental study for evaluating the effect of temperature on the mode I, mode II and mixed-mode interlaminar fracture toughness of adhesive joints with a curved cross-section of filament-wound dome-separated composite pressure vessel. Mode I and mixed-mode interlaminar fracture toughness were evaluated using DCB specimens, while mode II interlaminar fracture toughness was determined using ENF specimens. $[{\pm}10^{\circ}]_6$, $[{\pm}27^{\circ}]_6$ and ($[{\pm}10^{\circ}]_3/FM73/[{\pm}27^{\circ}]_3$) winding specimens with the curved cross-section were considered. In-situ temperature environments were simulated with a range of $-30^{\circ}C-60^{\circ}C$ using an environmental chamber and furnace. Experimental results on the effect of temperature indicate that interlaminar fracture toughness tends to be high at low temperature and is degraded with increase in temperature. For specimen types, it was found that interlaminar fracture toughness of $[{\pm}10^{\circ}]_3/FM73/[{\pm}27^{\circ}]_3$ winding specimens considered as adhesive joints of dome and helical part was higher than other specimens.

• Tribology and Lubricants
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• v.12 no.1
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• pp.1-5
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• 1996

자성유체는 자연에서 추출한 것이 아니라 자화성(Magnetizability)과 유도성(Flowability)을 동시에 갖도록 합성한 특수액체이다. 자성유체는 1960년대 중반에 미국의 NASA에서 처음 개발된 이후로 윤활, 밀봉, 감쇄, 의료 등의 분야에서 응용연구가 많이 진행되었기 때문에 고도의 정밀도를 요하는 항공, 우주산업, 컴퓨터와 반도체 분야 등에서 실용화가 크게 진전되고 있다. 특수물질일 자성유체는 전기적으로 도체인 10nm 정도의 미세한 자기입자(Magnetic particles)에 코팅을 한 후, 이것을 물, 탄화수소, 플루오르카본, 에스터 등의 매개유체(Carrier Fluids)에 혼합시켜서 콜로이드 상태로 사용하게 된다. 자성유체는 미세한 자기입자들이 매개유체내에서 서로 충돌하면서 반발력을 발생시켜서 상호간에 늘 콜로이드 상태를 유지하고 있으며, 이 특수유체가 자기장의 영향을 받게 되면 점도가 증가하면서 특이한 성질을 갖게 된다. 상대 접촉 운동면에 경계마찰이나 혼합마찰을 하게 되면 윤활상태는 비교적 나쁘다. 이러한 마찰지역에 콜로이드상의 자성유체 윤활제를 공급하면 기존의 윤활제에 비하여 대단히 효과적으로 윤활을 할 수 있게 된다. 그러나 자성유체 윤활제가 마찰부위에 원활하게 공급하기 위해서는 미끄럼 마찰부에서 자기장을 잘 형성시킬 수 있는 도체이어야 하기 때문에 특별한 윤활 시스템 설계가 제시되어야 한다. 자성유체 윤활제는 합성으로 제조된 특수물질로 여러가지 장점을 갖고는 있으나 기존 윤활유와의 적합성, 마찰열, 밀봉압력 등의 조건에서 제한적으로 사용될 수 밖에 없으므로 항공, 우주 산업이나 석유 화학분야와 같이 특수 환경에서만 사용되고, 또한 기존의 광유계 윤활제에 비하여 대단히 고가하는 문제점을 갖고 있다. 그러나 윤활 마찰면의 다양화와 가혹한 사용조건은 자성유체 윤활제의 연구개발 필요성을 크게 증대시키고 있다.xed Effects Model)을 결정하고, 각각에 해당하는 통계모형을 구축하였다. 이 결과 (1) 업종 및 기업규모별로 그룹간에 유의한 특성이 발견되었으며, (2) R&D 및 광고투자는 기업의 시장성과를 설명하는 중요한 변수이나, (3) R&D 투자의 경우는 광고에 비해 불확실성이 존재하는 것으로 나타났고, (4) 수리모형에서 도출된 한계원리가 통계모형에서도 유효한 것으로 드러났다.등을 토대로 한 10대 산업을 육성하기 위하여 과학기술부는 기술수요조사를 바탕으로 49개 주요기술을 도출하여, 과학기술 일류 국가 실현, 국민소득 2만불 달성이라는 국가적 슬로건을 내걸고 “차세대 성장동력” 창출을 위한 범정부차원의 기획과 연구비의 집중투자를 추진하고 있다.달성하기 위해서는 종합류류 전산망의 시급한 구축과 함께 화물차의 적재율을 높이고 공차율을 낮출 수 있는 운송체계의 수립이 필요한 것으로 판단된다. 그라나 이러한 화물전용차선의 효과는 단기적인 치유책일 수밖에 없기 때문에 물류유통 시설의 확충을 위한 사회간접자본의 구축을 서둘러 시행하여야 할 것이다.으로 처리한 Machine oil, Phenthoate EC 및 Trichlorfon WP는 비교적 약효가 낮았다.>$^{\circ}$E/$\leq$30$^{\circ}$NW 단열군이 연구지역 내에서 지하수 유동성이 가장 높은 단열군으로 추정된다. 이러한 사실은 3개 시추공을 대상으로 실시한 시추공 내 물리검층과 정압주입시험에서도 확인된다.. It was resulted from increase of weight of single cocoon. "Manta"2.5ppm produced 22.2kg of cocoon. It is equal to 9% increase in index, as compared to that of control. In case

• Horticultural Science & Technology
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• v.28 no.4
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• pp.585-592
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• 2010

This study was conducted to investigate the effect of 1-MCP, an ethylene action inhibitor, and several postharvest treatments including ethylene scrubbing on fruit quality and respiration for keeping marketability in 'Janhowon Hwangdo' peach ($Prunus$ $persica$ Batsch). 1-MCP at the rate of $1.0{\mu}L{\cdot}L^{-1}$ showed best results in maintenance of fruit firmness and external appearance such as skin color. The ethylene production was strongly reduced by 1-MCP treatment at 0.5 or $1.0{\mu}L{\cdot}L^{-1}$ but respiration rate was only suppressed at $1.0{\mu}L{\cdot}L^{-1}$ during 6 days of shelf life at $20^{\circ}C$. Mature fruits (harvested 1 week before full commercial maturity) were much highly responsive to $1.0{\mu}L{\cdot}L^{-1}$ of 1-MCP compared to those of commercial maturity. At the concentration of $0.5{\mu}L{\cdot}L^{-1}$ of 1-MCP did not affect fruit marketability compared to untreated control. Beneficial effects of carbon ceramic as an ethylene scrubber were also found such as delay of firmness loss and deterioration of external appearance at $10^{\circ}C$, but these positive effects on fruit quality remained for only 5 days. The application of ethylene scrubber on the shipping carton boxes was effective on keeping firmness of immature fruit pretreated with 1-MCP when compared with mature fruit.

• Journal of Energy Engineering
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• v.24 no.3
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• pp.89-95
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• 2015

Carbon felts manufactured by (Co)CNF were subjected to heat treatment under different temperatures to use for the electrode of a redox-flow battery. BET and weight loss were tested to investigate the physical properties of the carbon felt according to the heat treatment conditions. SEM and XPS were also analyzed to characterize their surface area. In addition, electrical resistance, CV (cyclic voltammetry) and RFB charge on the electrode properties were examined in accordance with the heat treatment conditions with the discharge performance. The changes of physical properties on the carbon felt surface was confirmed via SEM and BET analysis, The most addition of oxygen functional groups on the carbon felt surface was obtained when one hour heat treatment at $550^{\circ}C$ and it was confirmed by XPS analysis. After resulting the CV tests, the active area of the electrode was the largest at $550^{\circ}C$ heat treatment. The heat treatment experiment of vanadium redox flow battery using the carbon felts were tested at $400^{\circ}C$, $500^{\circ}C$ and $550^{\circ}C$. As a result, the charge-discharge energy efficiency of the heat treatment electrode was 72.9% and 79.8%, at $400^{\circ}C$ and $500^{\circ}C$, respectively. The efficiency of the heat treatment electrode at $550^{\circ}C$ was the best as 79.8% at $550^{\circ}C$.

• Journal of Environmental Impact Assessment
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• v.27 no.5
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• pp.431-446
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• 2018

In this study, chemical characteristics of $PM_{2.5}$ samples collected in an agricultural area in Nonsan of Korea were investigated focusing on of black carbon, 3 inorganic ions and 22 trace elements. It was found that the relative error and relative standard deviation of many trace elements fell below 10%, which indicates good analytical accuracy and precision. The mean values of $PM_{2.5}$ in an agricultural area were exceeded by new Korean air quality standard of March 2018. The concentration of $PM_{2.5}$ was well correlated with those of black carbon and ions. The concentrations of trace elements were in a wide range of seven orders of a magnitude. Based on these $PM_{2.5}$ data sets, a total of 6 sources were identified using PMF (Positive Matrix Factorization; secondary aerosol (34.4%), soil/road dust (20.1%), biomass burning (16.9%), incineration/fuel combustion (13.2%), vehicle exhaust(12.2%), sea-salt (3.17%). Results of our study indicate that it is very important to control illegal burning activities in agricultural area.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.5
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• pp.146-152
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• 2018

In this study, to improve the performance of asphalt mixtures for plastic deformation occurring mainly in Korea, complex modifiers were prepared by mixing powders and liquid type modifiers. The main constituents were powdery diatomaceous earth, mica and carbon black, and liquid type solid 70% SBR latex. The tensile strength ratios for the two asphalt mixtures used in the test were above 0.80 for the Ministry of Land Transportation (2017) asphalt mixture production and construction guidelines. The effects of increasing the tensile strength in the dry state was more than 14% when the composite modifier was added. The deformation rate per minute by the wheel tracking test load was an average of 0.07 to 0.147 for each mixture. The strain rate per minute was improved by the modifier, and the dynamic stability was improved by almost 100% from 295 to 590. In addition, the final settling was reduced from 11.38 mm to 9.57 mm. A plastic deformation test using the triaxial compression test showed that the amount of deformation entering the plastic deformation failure zone at the end of the second stage section and in the third stage plastic deformation section was 1.76 mm for the conventional mixture and 1.50 mm for the complex modifier mixture. The average slope of the complex modifier asphalt mixture mixed with the multi-functional modifier was 0.005 mm/sec. The plastic deformation rate is relatively small in the section where the road pavement exhibits stable common performance, i.e. the traffic load.