• Journal of Energy Engineering
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• v.23 no.3
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• pp.181-185
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• 2014

This paper describes the effect of canola biodiesel blended fuel on the combustion and emission characteristics in a four cylinder CRDI(Common-rail direct injection) diesel engine. In this study, using the biodiesel fuel(20%,40% of biodiesel-canola oil and 80%, 60% of ULSD(ultra low sulfur diesel) by volume ratio with change of engine speed and injection pressure. The experiment results of increasing biodiesel ratio fuel show that NOx emissions increased. However, soot emission were reduced BC fuels compared to ULSD. Soot emissions largely increased at low injection pressure.

• KOREAN POULTRY JOURNAL
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• v.15 s.168
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• pp.58-60
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• 1983

• Korean Journal of Food Science and Technology
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• v.49 no.6
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• pp.584-590
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• 2017

Effects of bleaching and deodorization on the quality of imported palm and canola oils were evaluated. Imported palm oil and deacidified canola oil were bleached with acid clay, followed by deodorization. Oxidation-related quality was evaluated by determining fatty acid composition by GC, acid and peroxide values, induction period by Rancimat, and off-flavor compounds by GC-MS. Tocopherols and benzo(a)pyrene were analyzed by HPLC. Acid and peroxide values were decreased by bleaching and deodorization, and tocopherol content was decreased to 60-70% (p<0.05). Aldehydes were major off-flavor compound class of imported oils, most of which were removed after deodorization. No significant change was observed in benzo(a)pyrene content (${\sim}0.4{\mu}g/kg$) of both oils by bleaching and deodorization (p>0.05). The oxidation-related quality of palm and canola oils was more improved after industrial bleaching than by deodorization. These results suggest that a careful control of bleaching during domestic refining can improve the quality of palm and canola oils.

• Journal of the Korean Society of Food Science and Nutrition
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• v.39 no.9
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• pp.1320-1327
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• 2010

Lipase-catalyzed interesterification of canola (CO) and fully hydrogenated soybean oil (FHSBO) at different weight ratios (70:30, 75:25, and 80:20) was performed in a batch type reactor to produce low-trans solid fats. Each reaction was conducted in the shaking water bath for various reaction times (1, 3, 6, 18 and 24 hr) at 70oC and 220 rpm using Lipozyme TLIM (20 wt% of total substrate) from Thermomyces lanuginosus. After 24 hr reaction, solid fat content (SFC) by differential scanning calorimetry (DSC), fatty acid and triacylglycerol (TAG) composition of low-trans solid fats were determined. SFC of the products was reduced when the content of canola oil in the reaction mixture was increased. Major fatty acids were stearic acid (C18:0), oleic acid (C18:1) and linoleic acid (C18:2). Trans fatty acid content in the low-trans solid fats showed less than 0.3 wt%. In the HPLC analysis, major TAG species showed LOO (linoleyl-oleoyl-oleoyl), OOO, POO/SOL, SOO, and SOS.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2009.10a
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• pp.483-484
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• 2009

• Korean Journal of Food Science and Technology
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• v.47 no.5
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• pp.561-566
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• 2015

Effect of the addition of egg yolk lecithin at a concentration of 350 mg/kg on iron-catalyzed autoxidation and chlorophyll-photosensitized oxidation of a water/canola oil emulsion (W/O) during storage at $25^{\circ}C$ was studied based on headspace oxygen consumption and hydroperoxide production. Changes in the phospholipid (PL) composition of the emulsion were determined by high performance liquid chromatography. Headspace oxygen consumption and hydroperoxide content of the emulsion increased with storage time, and addition of egg yolk lecithin did not have any significant effect on these parameters during iron-catalyzed autoxidation and chlorophyll-photosensitized oxidation of the emulsion. PL content of the emulsion decreased during both oxidations, and the degradation rate was higher during autoxidation than during photosensitized oxidation. Phosphatidylcholine content ratio tended to increase during autoxidation. The results suggest that egg yolk lecithin in canola oil emulsion behaves differently during iron-catalyzed autoxidation and chlorophyll-photosensitized oxidation.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.60-60
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• 2017

화석연료의 고갈과 환경오염이 문제시 되면서 친환경 에너지개발에 대한 연구가 진행되고 있다. 그중 바이오디젤은 동,식물성유지 및 폐식용유를 이용하여 생산이 가능할뿐더러 농용엔진에 특별한 개조 없이 사용가능하다. 또한 바이오디젤 자체에 산소를 함유하고 있어 이산화탄소 저감에 효율적이다. 바이오 디젤에 관한 많은 연구가 수행되었으며, 기존의 연구는 단일유지의 폐식용유를 사용하여 바이오디젤을 생산하는 연구가 진행되었다. 하지만 가정에서 배출되는 식물성 폐식용유의 경우 여러 가지가 혼합되어 배출되고 있어, 혼합폐식용유지의 바이오디젤 특성평가가 필요하다. 따라서 본 연구에서는 폐식물성유지(폐대두유, 폐카놀라유, 폐해바라기유)를 중량비(1:4, 1:1.5 1:0.66, 1:0.25)로 혼합하여 바이오디젤을 생산하고, 생산한 바이오디젤을 농용기관에 이용하여 농용기관의 출력특성 및 배기배출물특성 평가를 실시하였다. 실험에 사용된 농용기관은 배기량이 673cc인 직접분사식 디젤기관(ND10DE, Daedong, Korea)이며, 엔진성능평가를 위해 토크는 토크센서(YDL-704s, Setech, Korea)를 사용하였다. 배기배출물 평가는 배기가스분석기(HG-550, Airlex, Germany)를 이용하여 이산화탄소, 질소산화물을의 배출량을 측정하였다. 폐식용유를 이용하여 생산한 바이오디젤과 경유의 기관성능을 비교한 결과 토크와 축출력의 경우 BD의 혼합량이 증가할수록 줄어들었다. 토크는 혼합된 유지에 따라 상용운전범위인 1500rpm~2400rpm에서 평균 대두와 카놀라유를 혼합하여 생산한 BD10은 7.2%, BD20은 12.1% 감소하였고, 대두와 해바라기유를 혼합하여 생산한 BD10은 11.3% BD20은 16.3% 감소하였다. 또한 해바라기와 카놀라유를 혼합하여 생산한 BD10은 8.3%, BD20은 14.6% 감소하였다. 이는 BD의 발열량이 경유에 비해 낮아 토크가 감소한 것으로 판단된다. 또한 배기배출물 평가의 경우 질소산화물은 BD의 함랑이 증가함에 따라 경유에 비해 배출량이 증가하는 경향을 보였고, 이산화탄소는 저감되는 것으로 나타났다. 이는 바이오디젤이 함산소연료이므로, 연료내의 산소로 인해 완전연소를 촉진시켜 이산화탄소를 저감시키고 질소산화물은 증가된 것으로 판단된다.

• Korean Journal of Food Science and Technology
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• v.40 no.6
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• pp.611-620
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• 2008

The principal objective of this study was to assess the effects of phosphatidylcholine (PC) and phosphatidylethanolamine (PE) extracted from egg yolk on the oxidation of tocopherol-stripped canola oil and its browning, as well as their content changes during 12 hr of heating at $180^{\circ}C$. PC and/ or PE contents in the oil were measured at 200, 500, 1,000, or 2,000 ppm. PL contents in the oil and oil browning were determined by high performance liquid chromatography (HPLC) and spectrophotometry, respectively. The oil oxidation was evaluated by the combination of fatty acid composition, conjugated dienoic acid content, and p-anisidine value. PC was degraded at a slower rate than PE during heating and the co-presence of PE reduced its rate of degradation. PE increased oil browning more profoundly than PC did. PC significantly reduced oil oxidation during heating; however, we noted a possible antagonism between PE and PC in reducing the oil oxidation. Egg yolk PC was a better antioxidant in oil oxidation during heating.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.114.1-114.1
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• 2011

Bioenergy production from lignocellulosic biomass and agriculture wastes have been attracted because of its sustainable and non-edible source. Especially, canola is considered as one of the best feedstock for renewable fuel production. Oil extracted canola and its agriculture residues are reuseable for bioethanol production. However, a pretreatment step is required before enzymatic hydrolysis to disrupt recalcitrant lignocellulosic matrix. To increase the sugar conversion, more efficient pretreatment process was necessary for removal of saccharification barriers such as lignin. Alkaline pretreatment makes the lignocellulose swollen through solvation and induces more porous structure for enzyme access. In our previous work, aqueous ammonia (1~20%) was utilized for alkaline reagent to increase the crystallinity of canola residues pretreatment. In this study, significant factors for efficient soaking in aqueous ammonia pretreatment on canola residues was optimized by using the response surface method (RSM). Based on the fundamental experiments, the real values of factors at the center (0) were determined as follows; $70^{\circ}C$ of temperature, 17.5% of ammonia concentration and 18 h of reaction time in the experiment design using central composition design (CCD). A statistical model predicted that the highest removal yield of lignin was 54% at the following optimized reaction conditions: $72.68^{\circ}C$ of temperature, 18.30% of ammonia concentration and 18.30 h of reaction time. Finally, maximum theoretical yields of soaking in aqueous ammonia pretreatment were 42.23% of glucose and 22.68% of xylose.

• Journal of the Korean Society of Food Science and Nutrition
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• v.39 no.9
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• pp.1328-1334
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• 2010

Low-trans spread fat (LTSF) was produced by lipase-catalyzed synthesis of canola (CO) and fully hydrogenated soybean oil (FHSBO) at 65:35 (w/w). Blend of CO and FHSBO with 65:35 ratio was interesterified using Lipozyme TLIM (immobilized Thermomyces lanuginosus, 20% of total substrate) in a 1 L-batch type reactor at $70^{\circ}C$ with 500 rpm for 24 hr. Then, physicochemical melting properties of LTSF were compared with commercial spread fat. At $20^{\circ}C$, solid fat contents (SFC) of commercial spread fat as a control and LTSF were similar, showing 19.1 and 18.1%, respectively. Major compositional fatty acids of LTSF were C18:0, C18:1 and C18:2 (29.2, 41.8 and 13.3 wt%, respectively). Trans fatty acid content of the LTSF (0.2 wt%) was lower than that of commercial spread fat (5.5 wt%). In the RP-HPLC analysis from LTSF, major triacylglycerol (TAG) molecules were SOL (stearoyl-oleoyl-linoleyl), SOO, POS/PSP, and SOS. Also, polymorphic form and x-ray diffraction of LTSF showed coexistence of $\beta$' and $\beta$ form crystals.