• Title/Summary/Keyword: 침투확산

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Al 확산침투처리를 통한 Inconel 617의 코팅층의 상분석 및 고온산화특성평가

  • Im, Jeong-Hun;Jo, Tae-Seon;Kim, Dae-Geon;Kim, Yeong-Do
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.51-51
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    • 2009
  • Ni 기 초내열합금은 원자력 발전설비의 열교환기용 재료를 비롯한 발전용 가스터빈, 제트엔진, 화학공장용 튜브 및 파이프재료 등 우수한 고온 기계적 특성 및 고온 내식성을 요구하는 각종 부품재에 광범위하게 이용되고 있다. Al 확산침투처리는 Ni기 초내열합금에 Al 혼합분말을 이용하여 금속간합화물을 코팅함으로써 고온산화특성 향상에 효과적인 방법이다. 본 연구에서는 Al 확산침투처리를 통하여 Inconel 617 표면에 Aluminide 코팅층을 형성함으로써 고온 내산화특성을 향상시키고자 하였다. Al 확산침투처리는 Al :$Al_2O_3$ : $NH_4Cl$ = 15g : 83g : 2g(wt.%)의 비율의 혼합분말을 사용하여 $900^{\circ}C$에서 1 시간 동안 Ar 분위기에서 수행되었다. Al 확산침투처리 후 $950^{\circ}C$에서 1000 시간 동안 air 분위기에서 열화시험을 수행하였다. Al 확산침투처리 후 고온열화를 통해 고온산화특성을 평가였으며, 고온 열화에 의해 형성된 코팅층의 석출물과 계면상의 상분석을 수행하였다.

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염/담수 분포특성을 이용한 해수침투보호구역 설정

  • 황세호;신제현;박권규;박윤성;이상규
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.151-154
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    • 2004
  • 본 논문에서는 국내의 서-남해 연안지역에서 광범위하게 발생하고 있는 해수침투의 확산방지를 위하여 해수침투보호구역이라는 개념을 소개한다. 해수침투보호구역을 설정하기 위해서는 해당 지역 해수침투대의 고분해능 염분농도분포가 필요하며 이와 같은 염분농도분포도는 물리탐사 기술로 작성이 가능하다. 전남 영광지역에서 물리탐사 기술로 작성한 해수침투대의 고분해능 염분농도 분포도는 시험시추 결과, 매우 신뢰성이 높았으며 염분농도의 공간적인 분포도에서 해수침투로 인한 지하수 개발 제한지역, 보호구역 등에 대한 설정이 가능하였다. 향후, 해수침투의 확산방지와 지속적인 지하수의 개발이 가능한 해수침투보호구역설정에 대한 후속적인 조치가 필요할 것으로 판단된다.

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Prediction Model of Absorbed Quantity and Diffusivity of Salf in Radish during Salting (무우의 염절임시 소금의 침투량과 확산도 예측모델)

  • 최용희;권태연
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.6
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    • pp.572-581
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    • 1991
  • For the development of a model to predict absorbed salt quantity in radish during salting, absorbed salt quantity and water content change in radish by the hour were measured at 5%, 10%, 15% brine concentration and $10^{\circ}C,\;20^{\circ}C,\;30^{\circ}C$ respectively. Absorbed salt quantity in radish by the time showed logarithmic function, absorbed salt quantity by brine concentration and temperature showed linear relation. A model to predict absorbed salt quantity in radish at each time, brine concentration and temperature was calculated by the regression program of SPSS. Apparent diffusivity of salt in radish was calculated from appropriated diffusion equation solution of Fick's second law using computer simulation. Salt diffusivity in radish increased as brine concentration increased and the effect of temperature could by expressed by Arrhenius equation. A model equation which could predict salt diffusivity was developed by regression analysis. To specify relation between salt quantity which absorbed into radish and water content which removed out of it, Flux ratio(${\Delta}W/{\Delta}S$) was calcuated. The values showed that the removed water content was greater than the absorbed salt quantity.

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A Study on the Assessment of Chloride Penetration Due to Diffusion in NPP Concrete Structures (원전콘크리트 구조물의 확산에 의한 염소이온 침투평가에 관한 연구)

  • Kim, Do-Gyeum;Lee, Jang-Hwa;Kim, Ki-Beom;Lee, Ho-Jae
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2011.04a
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    • pp.404-405
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    • 2011
  • 원전구조물의 방사성 폐기물 처분시설의 경우 지하수에 해수가 유입되어 콘크리트에 염소이온 침투가 발생할 수 있으며, 콘크리트 내부에 존재하는 인장철근의 부식에 의한 내구성 저하 및 수명 단축이 주된 문제가 된다. 본 논문에서는 원전콘크리트 구조물에서의 확산에 의한 염소이온 침투에 대한 수학적 모델을 제시하였다. 콘크리트 중의 염소이온의 침투는 콘크리트의 노출환경, 습윤상태에 따라 확산(Diffusion), 대류(Absorption), 전기적 이동(Migration)에 의해 발생한다. 이러한 조건을 모두 고려하여 제시한 방정식에 의해 염소이온의 침투를 예측할 수 있다.

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Analysis of Chloride ion Penetration for In-Situation Harbor Concrete Structures (현장 항만 콘크리트 구조물에 대한 염소이온 침투 해석)

  • Han Sang-Hun
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.751-760
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    • 2005
  • The chloride penetration model, which considers diffusion and sorption, is proposed. The FEM program developed on the basis of the diffusion and sorption model provides the estimation of chloride concentration variation according to cyclic humidity and temperature. The humidity diffusion analysis is carried out, and the chloride ion diffusion and sorption analysis are conducted on the basis of the pre-estimated humidity data in each element. Each element has different variables at different ages and locations in analysis. At early ages, the difference of relative humidity between inner and outer concretes causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference of relative humidity between inner md outer concretes with age, the effect of sorption on the chloride ion penetration decreases with age. The cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and increases the quantity of chloride ion around steel at later ages. Therefore, the in-situ analysis of chloride ion Penetration for harbor concrete structures must be Performed considering the cyclic humidity conditionandthelongtermsorption.

Chloride Penetration into Concrete in Tidal Zone by Diffusion-Convection Analysis (확산과 이송을 고려한 콘크리트의 염소이온 침투해석)

  • Kim, Ki-Hyun;Cha, Soo-Won;Jung, Hyung-Mok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.22 no.6
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    • pp.607-615
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    • 2009
  • Analysis of chloride penetration into concrete is performed considering the repeated wetting and drying conditions of tidal zone, by means of the developed finite element program which enables the diffusion-convection analysis to be conducted. Heat conduction and moisture diffusion are also included in the finite element analysis program in order that their effects to chloride penetration may be considered. For the efficiency of calculation, the analyses of temperature, relative humidity and free chloride concentration are conducted successively in that order, by treating the convection of chloride due to moisture diffusion as an source or sink term. By comparing the analysis result from finite element analysis, where main variable is a wetting and drying period, with the chloride profiles from ACI Life-365 method, it is shown that the Life-365 method gives an accurate result for the submerged zone but does not consider the differences of wetting and drying period. To obtain an accurate chloride profile in the tidal zone, it is confirmed that the diffusion-convection finite element analysis should be applied.

Mechanism of Action of Fatty Alcohol Ethoxylate on Foliar Penetration of Dimethomorph into Cucumber (Fatty Alcohol Ethoxylate에 의해 유도되는 Dimethomorph의 오이 엽면 침투 기작)

  • Yu, Ju-Hyun
    • The Korean Journal of Pesticide Science
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    • v.12 no.2
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    • pp.127-133
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    • 2008
  • The foliar uptake of dimethomorph into cucumber was assessed by spray application of aqueous dimethomorph solution containing fatty alcohol ethoxylate (FAE) or fatty acid alkyl ester as activator adjuvants. Afterward, the possible mechanism of action of FAE on foliar penetration of active ingredient was suggested by speculating on the effect of lipophile and hydrophile of FAEs. The amount of absorbed dimethomorph induced by polyoxyethylene mono-9-octadecenyl ether (6 moles ethylene oxide, $C_{18=9}E_6$) was linearly related to the concentrations of surfactant as well as dimethomorph in spray solution, suggesting that it is simply a diffusion phenomenon of the solute molecule through a cuticular membrane from leaf surface. Octadecanol attached to FAE was most effective lipophile on the leaf penetration of dimethomorph. And, the more ethylene oxide had the polyoxyethylene chain of FAE up to 20 moles, the higher the uptake rate was. Therefore, the role of lipophile of FAE on dimethomorph penetration to cucumber leaf, probably, is to modify the physico-chemical properties of cuticular membrane to be permeable to dimethomorph, and the polyoxyethylene chain having less than 20 moles ethylene oxide, which is moderately permeable to cuticular membrane by its molar volume, is to let the physically-modified cuticular membrane to be maintained for a longtime.

Chloride Penetration of Concrete Mixed with High Volume Fly Ash and Blast Furnace Slag (FA 및 BFS를 다량 혼입한 콘크리트의 염분침투성)

  • Park, Ki-Cheul;Lim, Nam-Gi
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.1
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    • pp.90-99
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    • 2015
  • This study examined dynamic and characteristics and chloride penetration of concrete mixed with large amount of FA and BFS, which are considered for positive application to construction fields with purpose of long-tern durability of concrete structures. As a result of strength test on FA and BFS, FA concrete showed higher increase of strength compared to OPC, when FA4000 and FA5000 were mixed 30%, respectively. For BFS concrete, those mixed with 30% and 50% of BFS8000, respectively, showed higher or equivalent strength compare to OPC. As a result of test of chloride penetration on FA and BFS, diffusion coefficients of concrete mixed with 30% FA4000 and FA5000, respectively, showed to restrain average 6.5% of diffusion coefficient compared to OPC. And in case of BFS concrete, those mixed with BFS6000 and BFS8000, restrained diffusion of chloride ions 253% and 336%, respectively, compared to OPC. Therefore, Mixing 50% of BFS was most efficient in order to maximize restraint of chloride penetration according to metathesis of large amount. For relation between compression strength and diffusion coefficient of FA and BFS concrete, as strength increased, diffusion coefficient decreased. In this study, when mixing FA and BFS to concrete for long-run durability and restraint against chloride penetration, for FA, mixing it to concrete with less or equivalent 30% of replacement rate was most efficient. And for BFS, as fineness was higher and mixing it to concrete with less or equivalent 50% of replacement rate, there were results of higher strength compared to OPC and more efficient restraint of chloride ions.

Evaluation of Numerical Experiment of Pollution Dispersion on the Sewer Crack Occurrence (하수관거 균열발생에 따른 오염확산의 수치실험 평가)

  • Park, Jaesung;Bae, Wooseok;Lee, Hojin
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.3
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    • pp.5-9
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    • 2008
  • Because sewer is embedded in land, the pollutant permeating to underground so fast can cause contamination of soil when crack of sewer occurs. In this study, numerical modelling on dispersion of pollutant at sewer crack was performed. Based upon the study, the following conclusions were obtained. It was shown that transfer direction of pollutant was similar to the flow with topography slope of surface. It was exposed that the pollutant permeated to 8~10m depth. It is expected to offer efficiency in sewer management in the future through this research.

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Tension infiltrometer를 이용한 토양의 침투특성 분석

  • 하규철;전철민;김재곤
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.362-365
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    • 2004
  • 토양오염의 확산과정중의 서로 다른 지질적 기반위에 놓인 토양에 대한 침투특성과 4단계 이상의 장력을 적용하여 침투율을 산정하였다. 장력과 침투율과는 지수함수로 비선형 회귀시켜서 산정하였으며, 단지 몇단계의 장력만으로 구하여진 값보다 더 많은 불포화대수리특성과 신뢰성있는 포화수리전도도를 제공할 수 있을 것이다. 구하여진 침투율은 토양분석결과를 비교했을 경우 점토함량이 적은 시료에서 적게나오는 경향이 있고, sand가 많은 토양의 경우 높게 산정되었다.

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