• Title/Summary/Keyword: 침출법

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Impurity analysis and acid leaching purification of silica minerals (실리카광물의 산침출 정제와 불순물 분석법 연구)

  • Lee, Kil Yong;Yoon, Yoon Yeol;Cho, Soo Young;Chae, Young-Bae
    • Analytical Science and Technology
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    • v.20 no.6
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    • pp.516-523
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    • 2007
  • Purification of silica mineral has been investigated by acid leaching of pulverized silica. A series of studies has been carried out on the effect of leaching silica powder as a function of the leaching time at the constant temperature of $80^{\circ}C$ in oxalic acid, aqua regia, and two mixed acids of HF/HCl, $HF/HNO_3$. The impurities of silica and leachantes were measured by neutron activation analysis (NAA), inductively coupled plasma atomic emission spectrometry (ICP-AES), atomic absorption spectrometry, x-ray fluorescence (XRF) method and wet analysis (WA). Certain metals, such as sodium, calcium, iron, aluminium and titanium, have been found in concentrations of hundreds or even thousands of mg/kg. Comparison of purification processes of silica and analytical methods of impurities in the silica was conducted in this study.

Leaching of copper from waste PCBs with electro-generated chlorine -Analysis of experimental factors on the leaching by the factorial design- (전해생성염소(電解生成鹽素)에 의한 폐인쇄회로기판(廢印刷回路基板)으로부터 구리 침출(浸出) -실험계획법(實驗計劃法) 적용(適用)에 의한 침출(浸出) 영향인자(影響因子)의 분석(分析)-)

  • Kim, Eun-Young;Lee, Jae-Chun;Kim, Min-Seuk;Jung, Jin-Ki;Yoo, Kyoung-Keun
    • Resources Recycling
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    • v.17 no.6
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    • pp.24-33
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    • 2008
  • The leaching of Cu from waste PCBs was investigated with electro-generated chlorine as an oxidant. The leaching experiments were carried out according to the design of experiments to analyze quantitatively the effect of parameters on copper leaching. From the analysis of variance (ANOVA) it was suggested that the effective parameters were current density, temperature, concentration of HCl, and the interaction between the concentration of HCl and temperature. Especially, the effect of current density was analyzed to contribute to the interpretation of result for copper leaching up to 95.7%. A multiple regression model obtained from the analysis of effective parameters explained 99% of leaching results. From the model equation, it was found that the effect of HCl concentration on copper leaching increased with temperature.

Chemical leaching of radioactive cement and paraffin waste form generated from NPPs (원전 발생 고화체 폐기물 핵종분석을 위한 침출 조건)

  • Lee Jeong-Jin;Ahn Hong-Joo;Pyo Hyung-Yeal;;;Jee Kwang-Young
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.278-283
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    • 2005
  • Cement and paraffin waste form were prepared with a acid extraction method for the analysis of radionuclides generated from nuclear power plants. The acid extraction method was carried out with $HNO_3-HCl$ acid. At first, we compared the method with the microwave acid digestion method using SRM. The solutions of decomposed SRM were then analyzed by AAS and ICP-AES. The acid extraction method had shown good results as microwave acid digestion method. This method provided recovery values greater than $80\%$ for metallic elements.

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제주도 비위생매립지 주변 수리지질환경 파악을 위한 전기, 전자탐사 적용

  • 송성호;용환호;김기표;안중기;김창용
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.112-115
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    • 2003
  • 쓰레기매립장의 침출수 누출 탐지를 위한 물리탐사법은 침출수의 전기전도도를 대상으로 한 전기탐사법이 주로 적용되어 왔다. 이 연구는 제주도에 위치한 비위생매립지를 대상으로 주변 수리지질환경 파악을 위한 전기비저항 탐사와 더불어 매립장 경계부와 토양층을 통한 침출수 누출 영역을 효율적으로 규명하기 위하여 다중주파수를 이용한 소형루프 전자탐사를 병행하여 수행하였으며, 아울러 오염지역의 천부 지하수 유동 방향을 추정하기 위하여 침출수의 유동에 의해 발생될 수 있는 자연전위를 모니터링 하였다. 전기비저항 탐사 및 자연전위 모니터링 결과 매립지 주변을 통한 침출수의 누출 가능성은 거의 없는 것으로 나타났으며, 이는 주변 하천에서 정기적으로 실시한 수질 분석 결과와 일치된다. 또한 소형루프 전자탐사 자료에 대하여 공간 필터링 및 1차원 역산법을 적용한 결과 매립장 경계부의 위치 및 매립장 내부의 심도별 매립물에 의한 저비저항 이상대를 효과적으로 도출 할 수 있었다.

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Convergence Process for the Removal of Heavy Metals in the Abandoned Mine (휴폐광산의 중금속제어를 위한 융합공정 개발)

  • Dho, Hyonseung
    • Journal of the Korea Convergence Society
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    • v.7 no.1
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    • pp.155-160
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    • 2016
  • The convergence process utilized both leaching and ion exchange techniques has been investigated for the heavy metals removal in the abandoned mine of Chungyang Province, Korea. The contaminated soil samples by heavy metals from Samkwang mine were analysed by statistical analyses. The highly contaminated soils was initially separated by the flotation process. The selectivity indices were increased with increasing flotation reagents. The selectivity of separation was then improved by the use of both leaching and ion exchange processes in order to extract the heavy metals. The results of this study showed that the higher the sulfuric acid concentration, the leaching rate of heavy metals was increased. The lecheate then was removed by the ion exchange method. The anticipating results might imply that convergence process utilized both leaching and ion exchange techniques would somehow apply for the removal of heavy metals in the abandoned mine.

Review on bioleaching of uranium from low-grade ore (저품위(低品位) 우라늄철(鑛)의 미생물 침출법(浸出法))

  • Patra, A.K.;Pradhan, D.;Kim, D.J.;Ahn, J.G;Yoon, H.S.
    • Resources Recycling
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    • v.20 no.2
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    • pp.30-44
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    • 2011
  • This review describes the involvement of different microorganisms for the recovery of uranium from the ore. Mainly Acidithiobacillus forrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans are found to be the most widely used bacteria in the bioleaching process of uranium. The bioleaching of uranium generally follows indirect mechanism in which bacteria provide the ferric iron required to oxidize $U^{4+}$. Commercial applications of bioleaching have been incorporated for extracting valuable metals, due to its favorable process economics and reduced environmental problems compared to conventional metal recovery processes such as smelting. At present the uranium is recovered through main bioleaching techniques employed by heap, dump and in situ leaching. Process development has included recognition of the importance of aeration of bioheaps, and improvements in stirred tank reactor design and operation. Concurrently, knowledge of the key microorganisms involved in these processes has advanced, aided by advances in molecular biology to characterize microbial populations.

A Study on Fabrication of 3D Dual Pore Scaffold by Fused Deposition Modeling and Salt-Leaching Method (열 용해 적층법과 염 침출법을 이용한 3 차원 이중 공 인공지지체 제작에 관한 연구)

  • Shim, Hae-Ri;Kim, Jong Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.12
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    • pp.1229-1235
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    • 2015
  • Scaffold fabrication technology using a 3D printer was developed for damaged bone tissue regeneration. A scaffold for bone tissue regeneration application should be biocompatible, biodegradable, and have an adequate mechanical strength. Moreover, the scaffold should have pores of satisfactory quantity and interconnection. In this study, we used the polymer deposition system (PDS) based on fused deposition modeling (FDM) to fabricate a 3D scaffold. The materials used were polycaprolactone (PCL) and alginic acid sodium salt (sodium alginate, SA). The salt-leaching method was used to fabricate dual pores on the 3D scaffold. The 3D scaffold with dual pores was observed using SEM-EDS (scanning electron microscope-energy dispersive spectroscopy) and evaluated through in-vitro tests using MG63 cells.

T-RFLP Analysis of Microbial Community Structure in Leachate from Landfill Sites (폐기물매립장 침출수내 미생물군집 구조 해석을 위한 T-RFLP의 활용)

  • Yu, Jae-Cheul;Ishigaki, Tomonori;Kamagata, Yoichi;Lee, Tae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.4
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    • pp.369-378
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    • 2010
  • Microorganisms are key-role player for stabilization of landfill sites. In order to evaluate the availability of T-RFLP(Terminal Restriction Fragment Length Polymorphism) for monitoring microbial community variations during stabilization of landfill sites, the phylogenic diversity of microbial community in the leachate from 4 different full-scale landfills was characterized by T-RFLP based on bacterial 16S rDNA. Main population of microbial community analyzed by T-RFLP was significantly similar with that of microbial community analyzed by clone library analysis. The results of T-RFLP analysis for main population of microbial community in the leachate from landfills with different landfill structures, waste types and landfill ages showed apparently different microbial diversity and structures. Therefore, long-term monitoring of microbial community in leachate from landfill sites by using T-RFLP is expected to be available for evaluation of landfill stability.

Recovery and Separation of Nickel from the Spent Ni-Cd Batteries (폐 Ni-Cd전지로부터 Ni의 분리 및 회수에 관한 연구)

  • 김종화;남기열
    • Resources Recycling
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    • v.9 no.2
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    • pp.11-17
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    • 2000
  • Consumption of nickel is continuously increasing and the wastes of secondary battery, ferrite and catalyst containing Ni are also generated periodically. Among those wastes, the aim of this research is the recovery of nickel from used Ni-Cd recharge battery. Battery consisted of Ni 24 wt%, Fe 30 wt% and Cd 18.5 wt%. Metal was recovered by solvent extraction after leaching. Cadmium was leached completely in 1N-HCl and Ni was recovered above 70%. 30 vol% MSP-8 separated Cd and Ni completely from acidic leaching solution. In addition $NH_4NO_3$ as one of ammonium salt type leachants showed an excellent leaching selectivity to Ni and Cd. Ni in leached solution was recovered completely by LIX-extractant and more than 70% of Cd in raffinate was by D2EHPA.

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