• Title/Summary/Keyword: 침전제

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A Study on the Purification by Protein Precipitants and Washing of Agar (단백질(蛋白質) 침전제(沈澱制)의 처리(處理) 및 수세(水洗)에 의한 한천(寒天)의 정제(精製))

  • Lee, Ho-Suck;Rhee, Chul;Yang, Han-Chul
    • Korean Journal of Food Science and Technology
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    • v.17 no.5
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    • pp.340-344
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    • 1985
  • In this study, an effective method for purifying of crude agar was attempted, and at the same time, the effect of crude protein and ash contained in impurified agar on the gel strength of the agar were investigated. In order to reduce the content of protein of crude agar, the agar extract was treated with a protein precipitant such as tricholoroacetic acid(TCA) or perchloric acid(PCA), whereas washing with deionized water was applied to decrease the ash content of agar extract. Among the protein precipitants used in the experiment PCA reduced the crude proteins of crude agar most efficiently; addition of 0.01% PCA resulted in the reduction of crude protein content by 3%, and the gel strength of agar thereby increased from 220g/$cm^{2}$ to 402g/$cm^{2}$. High ash content of crude agar was removed by means of washing treatment and it decreased from 8.1% to 2.7%, leading to the gel strength of 530g/$cm^{2}4$.

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Synthesis of Zn-intermediate from alkali agents and its transformation to ZnO crystallinity (알칼리 침전제에 의해 제조된 아연 중간생성물 및 산화아연 결정화)

  • Jang, Dae-Hwan;Kim, Bo-Ram;Kim, Dae-Weon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.6
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    • pp.270-275
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    • 2021
  • ZnO was synthesized according to the transformation behavior and crystallization conditions of Zn-intermediate obtained by zinc sulfate as a precursor and NaOH, Na2CO3 as a alkali agents. For ZnO crystallization, Zn4(OH)6SO4·H2O and Zn5(OH)6(CO3)2·H2O as a Zn-intermediate were calcined at 400℃ and 800℃ for 1 h, respectively, based on decomposition temperature from TGA. Zn4(OH)6SO4·H2O was confirmed to have mixed Zn4(OH)6SO4·H2O and ZnO at 400℃, and was completely thermally decomposed at 800℃ to form ZnO phase. The prepared Zn5(OH)6(CO3)2·H2O as a Zn-intermediate by the reaction with Na2CO3 was transformed to a complete ZnO crystallization over 400℃. Nano-sized ZnO can be synthesized at a relatively lower calcination temperature through the reaction with Na2CO3.

Performance characteristics of inline mixing and coagulation system (인라인 혼화 및 응집 시스템의 성능특성)

  • Kim, Dong-Jun;Park, Sang-Kyoo;Yang, Hei-Cheon
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.3
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    • pp.269-275
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    • 2014
  • The objective of this study was to investigate the performance characteristics of an inline mixing and coagulation system for water treatment based on the process intensification concept. Three-stage inline mixing and coagulation system was composed of the reservoirs of source wastewater, the fixed quantity injection pumps of coagulants, the mixing and coagulation tubes, a sedimentation tank and a control panel. In the equal dosage of coagulant and coagulant aids, the turbidity removal with increasing the dosage of coagulant aids was about 3 times higher than that with increasing the dosage of coagulant. In the condition of the equal mixing and coagulation time, the turbidity removal of inline mixing and coagulation system was about 4.6 times higher than that of mechanical type.

An Evaluation of Solid Removal Efficiency in Coagulation System for Treating Combined Sewer Overflows by Return Sludge (CSOs처리를 위한 응집침전시스템에서 슬러지 반송에 의한 고형물 처리효율평가)

  • Ha, Sung-Ryong;Lee, Seung-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.3
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    • pp.171-178
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    • 2013
  • In this study, the sludge that occurs in the initial operation of coagulation system developed for the treatment of CSOs were returned to the flocculation reactor. The purposes of this study were to analyze the Characteristics of flocs that are generated through the recycling sludge and settling characteristics of sludge, and to evaluate the possibility that high concentrations of particulate matter in the initial inflow of CSOs could be used as an weighted coagulant additive. As a result, the concentration of treated CSOs pollutants at the beginning of the CSOs influent with a large amount of particulate matter over 20 ${\mu}m$ was low, after gradually increasing the concentrations of them. The flocs generated from the sludge return were similar in size compared to flocs generated through injection of micro sands, and settling velocity in case of return sludge injection was decreased from 55.1 cm/min to 21.5 cm/min. SVI value of the sludge accumulated at the bottom of the sedimentation tank was 72, and settled sludge volume decreased rapidly due to the consolidation of sludge to the time it takes to 10 minutes. these mean that sludge used for recycling has good settling characteristic. A condition of returned sludge which is 0.1% return of 0.3% extraction was formed in the balance of settlement and extraction. In this case, This condition was to be adequate to maintain the proper concentration such as 100~200 mg/L of TS and 50~100 mg/L of VS in the flocculation reactor. The usage of the return sludge containing particulate matters of CSOs as an weighted coagulant additive was able to secure a stable treated water quality despite the change of influent water quality dynamically. Furthermore, it can be expected to reduce the alum dosage along with the sludge production.

Synthesis and characterization of ADN based green monopropellants (ADN계열 액상추진제의 합성 및 특성 연구)

  • Kim, Wooram;Kwon, Younja;Jo, Young Min
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.409-411
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    • 2017
  • 미사일 추력기 체계에 적용되는 하이드라진[$N_2H_4$]추진제는 MSDS-OHS 유해성 분류상 급성독성 물질로서 사용이 제한되고 있는 바, 다양한 대체물질이 개발 중이다. 최근 해외에서 안전성과 취급이 우수한 질산 히드록실암모늄[$NH_3OHNO_3$]과 암모늄 디나이트라마이드[$NH_4N(NO_2)_2$] 기반 단일계 액상추진제가 개발중이며, 이 물질들을 이용한 추력기 시스템 적용 시험이 진행되고 있다. 그러나 저온에서의 연로물질 산성화 반응으로 인한 디나이트라마이드[$N(NO_2)_2{^-}$] 물질의 분해는 나이트레이트[$NO_3{^-}$] 이온 생성을 촉진시키며, 부수적으로 발생하는 침전물은 촉매 및 노즐의 막힘 현상을 유발하므로 추력기 성능의 저해요인으로 작용한다. 그러므로 저온분해 방지를 위한 첨가제 조성 개발 및 열분해 특성 연구가 최근의 관심사이다. 본 연구는 합성/정제/추출한 암모늄 디나이트라마이드 산화제를 주요 조성물로 적용하였으며, 염기성 안정화제를 질량비율 4~5% 첨가하여 산성화 반응을 억제시킨 단일계 액상추진제(KMP) 형태로 제조하였다. 합성한 추진제는 시차주사열량계(DSC)를 이용하여 분해온도를 측정하여 열안정성을 평가해보았다.

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The Study of Plate Powder Coated Nano Sized ZnO Synthesis and Effect of Sensory Texture Improvement (나노 ZnO 입자가 코팅된 판상 분체의 합성과 사용감 증진 효과에 대한 연구)

  • Jin-Hwa , Lee;Ju-Yeol, Han;Sang-Gil, Lee;Hyeong-Bae, Pyo;Dong-Kyu, Lee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.173-180
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    • 2004
  • Nano sized ZnO particle as 20-30nm applies for material, pigments, rubber additives, gas sensors, varistors, fluorescent substance as well as new material such as photo-catalyst, sensitizer, fluorescent material. ZnO with a particle size in the range 20-30nm has provided to be an excellent UV blocking material in the cosmetics industry, which can be used in sunscreen product to enhance the sun protection factor and natural makeup effect. But pure ZnO particles application limits for getting worse wearing feeling. We make high-functional inorganic-composite that coated with nano-ZnO on the plate-type particle such as sericite, boron nitride and bismuthoxychloride. In this experiment, we synthesized composite powder using hydrothermal precipitation method. The starting material was ZnCl$_2$ Precipitation materials were used hexamethylenetetramine(HMT) and urea. We make an experiment with changing as synthesis factors that are concentrations of starting material, precipitation materials, nuclear formation material, reaction time, and reaction temperature. We analyzed composite powder's shape, crystallization and UV-blocking ability with FE-SEM, XRD, FT-IR, TGA-DTA, In vitro SPF test. The user test was conducted by product's formulator. In the results of this study, nanometer sized ZnD was coated regardless of the type of plate-powder at fixed condition range. When the coated plate-powders were applied in pressed powder product, the glaze of powder itself decreased, but natural make-up effect, spreadability, and adhesionability were increased.

Photocatalytic Reaction of Sensitizer, Rose Bengal and Supersensitizer, Thiourea (감응제 Rose Bengal과 초감응제 Thiourea의 광촉매 반응)

  • Yoon, Kil-Joong
    • Analytical Science and Technology
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    • v.9 no.1
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    • pp.62-71
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    • 1996
  • The enhancement of the solar energy conversion efficiency into the electrical energy by the dye sensitization with a photoelectrochemical cell was studied. The magnitude of the rose bengal sensitized photocurrent containing the supersensitizer, thiourea was five times greater than that in the absence of thiourea. It was observed, however, that the long time span of irradiation causes the decrease in the photocurrent. Spectroscopic analysis of the dye solution showed that the dye molecule was photobleached and the insoluble aggregate which settles down in the solution, was formed as a result of the possible photocatalytic reaction and the disappearance of dye from the solution was the cause of the decreased photocurrent in the sensitization run.

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Possible Alternative Antioxidant Research Applied to Tin-based Plating Solution for Semiconductor Package (반도체 패키지용 주석계 도금액에 적용 가능한 대체 산화방지제 연구)

  • Go, Jeong-U;Lee, Geum-Seop;Lee, Hyeong-Geun;Kim, Gyeong-Tae;Park, Gyu-Bin;Son, Jin-Ho;Park, Hyeon-Guk;O, Jeong-Hun;Yun, Nam-Sik;Lee, Seung-Won
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.165.2-165.2
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    • 2016
  • 현재, 솔더범프용 주석계 도금액의 필수성분인 산화방지제의 경우, 국내외 경쟁사에서는 가격 및 성능이 우수한 벤젠/페놀 계열을 적용 중이다. 그러나, 최근 대형 고객사에서 페놀류 산화방지지제를 환경규제물질로 규정함에 따라, 자사에서는, 특허 이슈 해소 가능한 친환경 대체 산화방지제 개발을 해오고 있다. 본 연구에서는, 반도체 패키지용 주석계 도금액의 산화방지제 종류와 농도에 따른 주요 특성 (Particle, 전류 효율, 안정성 (변색, 침전 외), 범프 두께의 편차, 감광제의 침해, Reflow 후 빈공간 등)에 대하여 살펴보았다.

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Economic Value of Industrial Water Use (공업용수의 수종별 경제적 가치 추정)

  • Lee, Joo-Suk;Park, Sun-Young;Ryu, Mun-Hyun;Yoo, Seung-Hoon
    • Journal of Korea Water Resources Association
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    • v.45 no.4
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    • pp.373-381
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    • 2012
  • The information on the economic value of industrial water use is widely demanded in policy analysis area as well as academic research area. Therefore, this study attempts to obtain more accurate economic value of industrial water use using the economic theory. To this end, we conducted a survey of 1,017 manufacturing firms and estimated the economic value of industrial water use based on the concept of value of marginal product (VMP). Moreover, this study tried to estimate the VMP of three industrial water types, river water, precipitated water, and purified water. The results show that the VMPs of river water, precipitated water and purified water are estimated to be 769.24 won/$m^3$, 896.76 won/$m^3$ and 1,861.95 won/$m^3$, respectively. The value for the precipitated water found in this study is not significantly different from that (885.1 won/$m^3$) used in the pre-feasibility test implemented by Korea Development Institute (KDI). These imply that the latter is appropriate for evaluating the economic benefit of supplying industrial water, though it is based on 2003 Industry Survey.

Synthesis of indium hydroxide powders by a precipitation method (침전법을 이용한 Indium hydroxide 분말의 합성 연구)

  • Choi, Eun-Kyoung;Lee, Won-Jun;Han, Kyu-Sung;Kim, Ung-Soo;Kim, Jin-Ho;Hwang, Kwang-Teak;Kim, Jong-Young;Hwang, Hae-Jin;Shim, Kwang-Bo;Cho, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.3
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    • pp.122-129
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    • 2017
  • For the production of a high-density ITO target, $In_2O_3$ powders with a small particle size and low agglomeration should be synthesized. The purpose of this study is to control the size and shape of the Indium hydroxide precursor which affects the properties of the $In_2O_3$ powder. As a starting raw material, Indium metal was dissolved in a Nitric acid ($HNO_3$) solution. The effect of concentration, pH, and temperature on the properties of Indium hydroxide was investigated using ammonium hydroxide as a precipitant. Crystallite size of each sample was analyzed by X-ray diffraction and the shape and the size of the powder was analyzed by transmission electron microscopy. As a result, the particle size of Indium hydroxide was increased with increase in the concentration of $In(NO_3)_3$ and the particle size and shape of the Indium hydroxide remained unchanged with increase in the pH of the solution. The particle size increased with increase in the precipitation temperature during precipitation.