• Journal of Conservation Science
• /
• v.17 s.17
• /
• pp.5-18
• /
• 2005

Rock materials of the Stone Lantern in the Gwanchoksa temple was composed of dark grey granodiorite. This Stone Lantern is partly structural distortion as S-shape, especially, rocks of the upper supports and under the roof materials were highly deterioration due to the surface exfoliation, and strong secondary contaminations owing to the discoloration by oxidation of inserted iron plates between the rock properties, and white grey to dark black contaminants along the rain path way. Rock surface of the Stone Lantern occurred as partly green patches because of coated by algae, lichen and moss. This biological problems are need for cleaning and treatments. The Stone Lantern have to be considered to conservation method that can reduce weathering factors with long-term monitoring about environmental change for structural stability, surface degradation and mechanical weathering. Materials of the Stone Lantern and basement rocks of the area are consisted of same petrogenetic granodiotite based on occurrences, petrological and geochemical characteristics.

• Applied Chemistry for Engineering
• /
• v.8 no.4
• /
• pp.679-684
• /
• 1997

The major constituents in spent FCC catalysts are Si, Al, Fe, Ti, alkali metals and some others. The spent catalyst is also composed small amounts of rare metals such as Ce, Nd, Ni and V. The selective adsorption and concentration of Ce and Nd from the leaching solution of spent FCC catalysts with sulfuric acid($0.25mol/dm^3$) were carried out by the column method with a chelate resin having a functional group of aminophosphoric acid type. Ce and Nd were separated from eluate liquor containing Al, Nd and V by the precipitation process with oxalic acid. Vanadium is purified from chloride ion coexistance by solvent extraction, employing tri-n-octyl phosphine oxide as extractant with Al in the raffinate solution. Rare metals with the purity of 99 percent were obtained from the spent FCC catalyst.

• Journal of Life Science
• /
• v.8 no.5
• /
• pp.497-503
• /
• 1998

Cyclodextrinase from B. stearothemophilus KJ16 that can produce both cyclodextrin(CD) glucanotransferase and cyclodextrinase was purified 87.6-fold with 7% yield by ammonium sulfate precipitation, DEAE-cellulose chromatog-raphy, Sephadex G-100 chromatography, and FPLC. The molecular weight of the purified enzyme was about 68,000 dalton by SDS-PAGE. The optimal pH and temperature were 6.0 and 55$^{\circ}C$, respectively. The enzyme was stable at 5$0^{\circ}C$ for 2 hr in the pH range of 5.5 and 8.5. The enzyme activity was inhibited strongly by mercaptoethanol, di-thiothreitol, p-chloromercuribenzoate, N-bromosuccinimide, $Cu^{+2}$and $Hg^{+2}$. The purified enzyme hydrolyzed CDs with$\gamma$-CD>$\beta$-CD>$\alpha$-CD. The enzyme also hydrolyzed linear maltodextrins and polysaccharides, but the rates of hyd-rolysis for such substrates were slow as compared to that for $\gamma$-CD. The final degradation products with all substrates were maltose and glucose. Maltose was not further hydrolyzed.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.37 no.9
• /
• pp.837-845
• /
• 2013

An airlift pump can be used to pump liquids and sediments within itself, which cannot easily be pumped up by a conventional method, by using the airlift effect. This characteristic of the airlift pump can be exploited in a DCFC (Direct Carbon Fuel Cell) so that molten fuel with high temperature may be carried or transported. The basic characteristics of airlift are investigated. A simple system is constructed, where the reservoir is filled with water, a tube is inserted, and air is supplied from the bottom of the tube. Then, water is lifted and its flow rate is measured. Bubble patterns in the tube are observed in a range of air flow rates with the parameters of the tube diameter and submergence ratio, leading to four distinct regimes. The pumping performance is predicted, and the correlation between the supplied gas flow rate and the induced flow rate of water is found.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2020.06a
• /
• pp.339-339
• /
• 2020

도시화로 인한 불투수면적의 증가와 기후 변화로 인한 강우패턴의 변화 자연적 물순환 체계에 악영향을 미치며. 이를 해결하기 위하여 국내에서는 도시 내 빗물관리 및 비점오염원 저감이 가능한 저영향개발(Low Impact Development, LID)를 적용하고 있다. 건기시 도로, 주차장등 차량통행 및 유동인구가 많은 지역에서는 입자상 물질들이 많이 발생되어 노면에 축적되어 있다가 강우시 강우유출수를 통해 시설로 유입된다. 이로 인해 시설 내 오염물질 및 퇴적물이 축적되어 여재 공극막힘현상 및 침투율저하의 문제가 발생되어 시설 내 효율이 감소된다. 따라서, 레인가든의 장기 모니터링을 통해 시설 내 유입되는 오염물질의 성상 분석 및 시설 내부의 퇴적물 분석을 통해 LID시설 운영의 효율성 평가를 수행하였다. 모니터링은 강우시 모니터링과 건기시 집수구역, 침강지, 시설 상부, 중부, 하부 등 총 5곳에서 채취하여 분석을 수행하였다. 모니터링은 평균 선행건기 일수는 5.46±4.7 days, 평균 강우량은 14.31±11.4 mm, 평균 강우강도는 5.33±6.7 mm/hr의 강우사상에서 모니터링을 수행하였다. 시설 내 평균 유입수농도는 TSS 98.0 ± 32.7 mg / L, COD 133.6 ± 6.3 mg / L, TN 5.77 ± 4.05 mg, TP 0.54 ± 0.03 mg / L으로 분석되었다. 유입부 내 퇴적물 종류는 Sandy Clay Loam으로 나타났으며, Cr 0.36mg / kg, Cu 5.17 mg / kg and Pb 6.04 mg / kg으로 중금속의 함유량이 높은것으로 분석되었다. 퇴적물은 침강지 및 시설 유입부에서의 입자크기는 49-113㎛ 약 60%의 퇴적물이 축적되어 제거되는 것으로 나타났다. 시설 내 침강지에서 50㎛ 이상의 입자들이 여과, 흡착 및 침전으로 인하여 40% 이상의 입자들이 제거되는 것으로 분석되었으며, 50㎛ 미만의 입자들은 시설 내 중간부, 유출부에서 제거되는 것으로 분석되었다. 침강지에서 유입수 대부분의 입자상물질들이 흡착 및 여과로 인한 제거가 이루어지기에 침강지 여재부는 넓은 표면적, 우수한 흡착능 및 여과율을 고려하여 선정하영 하며, 잦은 교체를 위하여 중량성이 낮은 우드칩 등이 적당한 것으로 사료된다.

• Journal of KSNVE
• /
• v.5 no.3
• /
• pp.275-283
• /
• 1995

본 글에서는 지능구조물의 개념설명과 더불어 ERF의 특성, ERF를 함유란 함유 한 지능구조물 시스템의 구성, 동적 모델링과 진동제어 그리고 그 응용성에 관한 연구 현황과 방향에 대해 살펴보았다. 설명한 바와 같이 지능구조물은 새로운 차원의 신생 하는 첨단분야로서, 소음 및 진동에 관련된 무한한 잠재력과 다양한 응용성으로 미루 어 볼때 아주 매력적인 연구 분야이다. 그러나, 여러 응용 시스템의 상품화 단계로의 도약에 있어서 각 시스템 구성 요소 분야별 해결해야할 연구 사항들이 있다. 먼저, 액추에이팅을 수행하는 ERF 자체의 내구성 문제로서 고온에서 ERF의 효과 하락과 장시간 사용시 ERF에 의한 마멸, 고체 입자의 침전에 의한 초기 상태 불안정 등이 있다. 아울러 기존의 장치의 성능을 능가하기 위해 보다 큰 효과를 나타내는 새로운 차원의 ERF개발이 요구된다. 그리고 센서기술 분야에서는 호스트 재료에 보다 쉽게 결합이 되고 여러가지 형태의 요구조건을 만족시킬 수 있으며 외부 환경조건에 강건 하고 다양한 센서 개발이 요구된다. 또한, 보다 일번적인 동적 모델링을 통해 적용 시스템에 적합하고 강건한 제어기에 대한 연구가 진행되어야 한다. 마지막으로 능동 제어기를 실제로 구현하기 위한 호스트 재료 각 요소마다 센서의 설치, 페회로 피드백 시스템 장착, 상호간의 인터페이스 등의 기술 발전이 요구되며, 아울러 보다 효율적 인 시스템의 성능 특성을 실현할 수 있는 호스트 재료와 기계 메카니즘이 필요로 된다. 이상의 설명에서 알 수 있듯이 지능구조물에 대한 연구는 어느 한 분야에서만 아니라 기계, 전기전자, 토목, 물리, 재료과학 등 통합형식에 의한 접근 방향으로 추진되어야 할 것이다.서 세탁기의 진동 소음을 저감시키기 위해 진동 소음원에 대해 논술하고, 진동해석을 위해 컴퓨터 시뮬레이션 결과를 이용한 저진동 기술 개발에 대하여 기술하고자 한다.rotary piston)식 압축기는 약 20여년 전 부터 냉방용 압축기에서부터 널리 쓰이게 되었다. 약 10여년전부터 상용화 된 스크롤(scroll) 형 압축기도 현재 상대적으로 용량이 큰 가정용 냉방기를 중심으로 많이 쓰이고 있다. 스크류형 압축기는 보통 중대형 상업용에 주로 쓰인다. 해결하려 하였고, 수치해석은 피스톤의 운동을 배제한 단순화한 흡배기계의 정상상태 유동해석이 주를 이루어왔다. Taghaui and Dupont 등[5]은 KIVA코드를 사용하여 흡기포트와 연소실 그리고 밸브의 움직임을 동시에 고려한 수치해석을 도입하였다. 하지만 이들이 밸브의 운동을 고려하기 위해 사용한 이동격자는 격자점은 시간에 따라 변화하지만 그 격자의 수가 일정하게 유지되어 있어서 밸브의 완전개폐를 해석할 수가 없다. 강희정[6]은 단일 실린더와 단일 배기밸브를 갖는 문제로 단순화하여 피스톤과 밸브의 움직임을 고려하므로써 배기행정 후 소음이 어떻게 전파해 나가는가를 연구하였다. 본 연구에서도 최소밸브간격과 최대밸브간격 사이에서만 계산이 가능하나 흡기의 경우는 밸브가 닫힐 때 생기는 압력파가 중요하므로 실린더와 밸브사이에 벽면조건을 주어 밸브의 개폐를 모사하였다.술을 보유하고자 한다. 이용한 해마의 부피측정은 해마경화증 환자의 진단에 있어 육안적인 MR 진단이 어려운 제한된 경우에만 실제적 도움을 줄 수 있는 보조적인 방법으로 생각된다.ofile whereas relaxivity at high field is not affected by τS.

• The Journal of Engineering Geology
• /
• v.8 no.2
• /
• pp.175-188
• /
• 1998

This paper describes the internal structures and K-Ar ages of fault gouges collected from the Dongnae fault zone. This fault zone is internally zoned and occurs in the multiple fault cores. A fault core consists of thin gouge and narrow cataclastic zones that are bounded by a much thicker damage zone. Intensity of deformation and alteration increases from damage zone through cataclastic zone to gouge zone. It is thought that cataclasis of brittle deformation was the dominant strain-accomodation mechanism in the early stage of deformation to form the gouge zone and that crushed materials in the regions of maximum localization of fault slip subsequently moved by cataclastic flow. Deformation mechanism drastically changed from brittle processes to fluid-assisted flow along the gouge zone as the high porosity and permeability of pulverzied materials during faulting facilitated the influx of the hydrothermal fluids. Subsequently, the fluids reacted with gouge materials to form clay minerals. Fracturing and alteration could have repeatedly taken place in the gouge zone by elevated fluid pressures generated from the reduction of pore volume due to the formation of clay minerals and precipitation of other materials. XRD analysis revealed that the most common clay minerals of the gouge zones are illite and smectite with minor zeolite and kaolinite. Most of illites are composed of 1Md polytype, indicating the products of hydrothermal alteration. The major activities of the Dongnae fault can be divided into two periods based upon K-Ar age data of the fault gouges : 51.4∼57.5Ma and 40.3∼43.6Ma. Judging from the enviromental condition of clay mineral formation, it is inferred that the hydrothermal alteration of older period occured at higher temperature than that of younger period.

• Economic and Environmental Geology
• /
• v.35 no.3
• /
• pp.203-210
• /
• 2002

In order to elucidate the growth mechanism of sulfide chimney formed as a result of seafloor hydrothermal mineralization, we carried out the mineralogical and fluid inclusion studies on the inactive, sulfide- and silica-rich chimney which has been recovered from a hydrothermal field in the Cleft segment of the Juan de Fuca Ridge. According to previous studies, many active and inactive vents are present in the Cleft segment. The sulfide- and silica-rich chimney is composed of amorphous silica, pyrite, sphalerite and wurtzite with minor amounts of chalcopyrite and marcasite. The interior part of the chimney is highly porous and represents a flow channel. Open spaces within chimneys are typically coated with colloform layers of amorphous silica. The FeS content of Zn-sulfides varies widely from 13.9 to 34.3 mole% with Fe-rich core and Fe-poor rims. This variation possibly reflects the change of physicochemical characteristics of hydrothermal fluids. Chemical and mineralogical compositions of the each growth zone are also varied, possibly due to a thermal gradient. Based on the microthermometric measurements of liquid-rich, two-phase inclusions in amorphous silica that was precipitated in the late stage of mineralization, minimum trapping temperatures are estimated to be about 1140 to 145$^{\circ}$C with the salinities between 3.2 and 4.8 wt.% NaCI equiv. Although the actual fluid temperatures of the vent are not available, this study suggests that the lowtemperature conditions were predominant during the mineralization in the hydrothermal field at Cleft segment. Comparing with the previously reported chimney types, the morphology, colloform texture, bulk chemistry, and a characteristic mineral assemblage (pyrite + marcasite + wurtzite + amorphous silica) of this chimney indicate that the chimney have been formed from a relatively low-temperature (<250$^{\circ}$C) hydrothermal fluid that was changed by sluggish fluid flow and conductive cooling.

• Economic and Environmental Geology
• /
• v.34 no.3
• /
• pp.271-281
• /
• 2001

The characteristics of the heavy metal contamination in the soils affected by the tailings of the Palbong mine have been studied. The soils in the studied area consist mostly of loam by the particle size analysis, but a little of it, located near the stream, consist of loamy sand to sandy loam, finally to loam downward. The organic contents of soils are significantly low aoom 2 percent and the pH is in acidic ranging 6.0 $\pm$ 0.1. The samples of the parent rocks, the normal soils, the tailings and the channel deposits from the studied area were chemically analysed. From the result, the heavy metal concenlration of the soils is a little Jow compared with that of the parent rocks, shows the hydrologic process of the surface and the groundwater. The contamination of the tailings from the ore mining are high in lead, copper and arsenic. In the channel deposits the concenlrations of lead and copper are abnormally high but that of arsenic is uniquely low. And most of heavy metal contamination are decreased with the distance from the mine. It is caused by the properties of the surface and the ground water during the process of the heavy metal migration. The correlation-coefficient between sand and silt contents and the concentrations of Cd, Cu and Pb are significant but the amounts of As and Hg are increased with the clay contents. The dispersion of the heavy metals with the distance shows that the concentrations of them in the soils sampled at distance of 100 m to 200 m along the stream started near the Palbong mine are extremely high compared with those from other distances. These discrepancies are significant in Cd, Cu, Pb and Hg, but low in As. All the samples contain below detection limit of Cr+6 In the present stream water the concentrations of the heavy metals are not detected. So, it is interpreted that the concentrations in the soils are caused by the activities of the mining during the operation and have been continued by the dispersion from the tailings since after the closure of the mining, especially by the surface and ground water. The concentrations are diminished with the distance from the mining site, but in the interval of 800-2000 m increases abruptly. In the soil samples counted on the dispersion direction by wind, the lowering of the concentration is relatively uniform with the distance from the mining site. So, the rapid increase of the heavy metal concentrations is presumed to have been caused by the ground-water movement. In the migration of the heavy metals, the groundwater conditions, such as pH, Eh, the contents of colloidal particles, and Mn and Fe oxides are closely involveo. Integrating with these factors, it is interpreted that the groundwater conditions which have caused the heavy metal contamination of the studied area are those that the pH is about 3 in oxidized conditions, the contents of the colloidal particles are low, and Mn and Fe oxides are not involved in the migration of the heavy metals. Meanwhile, the vegetables growing on the soils in the studied area are not affected by the contamination of the heavy metals.

• Journal of the Korean Society of Groundwater Environment
• /
• v.5 no.4
• /
• pp.177-191
• /
• 1998

For various kinds of waters including surface water, shallow groundwater (＜70 m deep) and deep groundwater (500∼810 m deep) from the Pungki area, an integrated study based on hydrochemical, multivariate statistical, thermodynamic, environmental isotopic (tritium, oxygen-hydrogen, carbon and sulfur), and mass-balance approaches was attempted to elucidate the hydrogeochemical and hydrologic characteristics of the groundwater system in the gneiss area. Shallow groundwaters are typified as the 'Ca-HCO$_3$'type with higher concentrations of Ca, Mg, SO$_4$and NO$_3$, whereas deep groundwaters are the 'Na-HCO$_3$'type with elevated concentrations of Na, Ba, Li, H$_2$S, F and Cl and are supersaturated with respect to calcite. The waters in the area are largely classified into two groups: 1) surface waters and most of shallow groundwaters, and 2) deep groundwaters and one sample of shallow groundwater. Seasonal compositional variations are recognized for the former. Multivariate statistical analysis indicates that three factors may explain about 86% of the compositional variations observed in deep groundwaters. These are: 1) plagioclase dissolution and calcite precipitation, 2) sulfate reduction, and 3) acid hydrolysis of hydroxyl-bearing minerals(mainly mica). By combining with results of thermodynamic calculation, four appropriate models of water/ rock interaction, each showing the dissolution of plagioclase, kaolinite and micas and the precipitation of calcite, illite, laumontite, chlorite and smectite, are proposed by mass balance modelling in order to explain the water quality of deep groundwaters. Oxygen-hydrogen isotope data indicate that deep groundwaters were originated from a local meteoric water recharged from distant, topograpically high mountainous region and underwent larger degrees of water/rock interaction during the regional deep circulation, whereas the shallow groundwaters were recharged from nearby, topograpically low region. Tritium data show that the recharge time was the pre-thermonuclear age for deep groundwaters (＜0.2 TU) but the post-thermonuclear age for shallow groundwaters (5.66∼7.79 TU). The $\delta$$\^$34/S values of dissolved sulfate indicate that high amounts of dissolved H$_2$S (up to 3.9 mg/1), a characteristic of deep groundwaters in this area, might be derived from the reduction of sulfate. The $\delta$$\^$13/C values of dissolved carbonates are controlled by not only the dissolution of carbonate minerals by dissolved soil CO$_2$(for shallow groundwaters) but also the reprecipitation of calcite (for deep groundwaters). An integrated model of the origin, flow and chemical evolution for the groundwaters in this area is proposed in this study.