• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.63-64
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• 2021

The corrosion inhibition properties of conifer cone (Pinus resinosa) extract were studied in synthetic concrete pore solutions (SCPS) with and without chloride environments by electrochemical methods. The electrochemical impedance spectroscopy (EIS) revealed that the conifer cone (CC) extract showed promising inhibition behavior by diminishing the corrosion rate of steel rebar both solutions i.e. with and without chloride. The extract of conifer cone hinders the corrosion reaction between steel rebar and aggressive ions. Further, it can be verified that the up to 1000mg.L-1 of CC extract can able to reduce the corrosion rate of steel rebar in chloride contaminated concrete.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.112-113
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• 2021

Phosphate based inhibitor is playing a decisive role in inhibiting the corrosion of steel rebar in chloride condition. We have used different amount of ammonium phosphate monobasic (APMB) as corrosion inhibitor in mortar with different amount of chloride ions. The compressive strength, flexural strength, open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization resistance (PPR), scanning electron microscopy (SEM) and Raman spectroscopy were performed to access the effect of inhibitor on corrosion resistance. As the amount of inhibitor is increased, the compressive strength increased. The electrochemical results show that as the amount of inhibitor and chloride ions are increased, the total impedance and corrosion resistance of steel rebar increased attributed to the formation of the stable oxide films onto the steel rebar surface. It is suggested that APMB can work in high concentration of chloride ions present in concrete where phosphate ion helps in formation of stable and protective phosphate based oxide film.

• 한국산학기술학회논문지
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• 제16권11호
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• pp.7917-7924
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• 2015

본 연구에서는 친환경 제설제로 사용이 증가되고 있는 CMA를 바탕으로 고성능흡습제로 사용되어지고 있는 SAP와 sodium carbonate, $MgCl_2$/MgO (M/M)에 대하여 제습MB를 제조하고 필름으로서의 흡습율 및 제습성능을 분석하고, 제습필름 적용물질에 대한 Data를 확보하고자 한다. CMA와 SAP를 혼합한 제습MB의 경우 발포현상과 수분문제로 필름가공성이 어려웠으나, Bentonite와 calcium carbonate 첨가로 해결할 수 있었다. 필름가공시 물질들 간의 표면적 공간을 넓히는 역할로서 발포제를 첨가한 경우, CMA와 M/M의 경우 큰 차이성은 없었지만, 발포제가 첨가된 SC의 제습성은 3.15 g/g로 높은 결과를 알 수 있었다. 또한 방청성 테스트의 결과 CMA 제습필름 경우 부식발생은 없었으며, SC의 경우 점 부식 발생, M/M의 경우 부식발생이 일어났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 가을 학술논문 발표대회
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• pp.37-38
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• 2022

During the past decades, the corrosion of the steel rebar embedded in concrete structure surrounding marine environment is actually problematic and required the suitable preventive method. An eco-friendly corrosion inhibitor mix is investigated to stifle the active corrosion in comparison with other commercial corrosion inhibitors. The hybrid inhibitor enhances the corrosion resistance and the workability of concrete. However, it reduces the compressive strength slightly after 28-day-age. The electrochemical studies and mechanical studies are pointed out the corrosion resistance property, corrosion kinetics, and the mechanical properties of all concrete samples. H-3 is the optimum dose of hybrid inhbitor that meets the demand of both electrochemical property and mechanical property. It performs the noble features due to the formation of optimum amount of P-Zwitterions-(Cl)-Fe complex onto the steel rebar surface.