• Title/Summary/Keyword: 친환경반응

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Storability and Material Compatibility Test of Blended Hydrogen Peroxide Propellant (블렌딩 기법을 적용한 과산화수소 추진제의 저장성 및 재료 적합성 평가)

  • Lee, Jeong-Sub;Jang, Dong-Wuk;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.150-158
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    • 2011
  • Blending method was applied to increase the performance of hydrogen peroxide which is called green propellant. 90 wt.% hydrogen peroxide was blended with ethanol which is less toxic fuel, and there was no storability decrease due to fuel addition. Inconel X750 and Tophet A showed good compatibility and high heat resistance, and SUS 316L was compatible. Al2O3, Y2O3, and ZrO2, were coated on the material to improve heat resistance, and it was proved from endurance test that Y2O3 coating is not suitable and adhesive strength between coating and material is related with allowable temperature of material. Thruster test was performed to confirm the performance increase by blending method, and chamber temperature was $870^{\circ}C$ which is higher than $760^{\circ}C$ that is adiabatic chamber temperature of 90 wt.% hydrogen peroxide.

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Evaluation of the Performance on Coating on Roller Compacted Concrete Pavement for Bike Roads (자전거도로용 롤러 전압 콘크리트 포장의 코팅에 따른 성능 평가)

  • Lee, Chang-Ho;Lee, Seung-Woo;Kim, Seong-Kil
    • International Journal of Highway Engineering
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    • v.13 no.1
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    • pp.79-86
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    • 2011
  • Recently, usage bicycle is encouraged to reduce fuel consumption and air pollution. For this purpose, bike road constructions are actively performed. However, types of pavement used in bike roads have high construction cost and performance comparing the required capacity of bike roads. Thus, an economical pavement type for construction is necessary for the effective development. Roller compacted concrete pavement have good requirements, such as easy construction and low costs, high structural performance of hydration and internal communication aggregation on compaction for bicycle roads. However, the pool landscape surface and resistance to deicer damage cannot be applied to the construction of bicycle roads. Thus, for solving this problem used coating which may have effect of improving the landscape and environmental resistance. To examine this effect were evaluated performance of roller compacted concrete pavement on the coating.

Synthesis of Vegetable Oil-Based Poly(β-amino ester) (식물성 오일 기반 Poly(β-amino ester) 합성)

  • Jang, Na-Ri;Kim, Beom Soo
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1064-1067
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    • 2012
  • Recently, there is a growing interest in vegetable oils, cheap and abundant renewable natural resources. Vegetable oils can be used as raw materials for ecofriendly biodegradable polymer materials. In this study, poly(${\beta}$-amino esters) were synthesized by polymerization reaction of acrylated epoxidized soybean oil (AESO) and 2-aminoethanol. Various polymer films were prepared by changing the molar ratio of AESO to 2-aminoethanol. The formation of C-N bonds in poly(${\beta}$-amino ester) was confirmed using FT-IR. Gel contents higher than 98% confirmed the synthesis of crosslinked polymer networks. Tensile strengths and elongation at breaks of polymer films ranged from 0.3 to 1.3 MPa and 32 to 55%, respectively. Polymer films degraded 2 to 7% of the initial weight in 35 days in phosphate buffer solution (pH 7.2) containing lipase enzyme.

Problems and Solutions of Anion Exchange Membranes for Anion Exchange Membrane Fuel Cell (AEMFC) (음이온교환막연료전지용 음이온교환막의 문제점과 해결방안)

  • Son, Tae Yang;Kim, Tae Hyun;Kim, Hyoung Juhn;Nam, Sang Yong
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.489-496
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    • 2018
  • Fuel cells are seen as eco-friendly energy resources that convert chemical energy into electrical energy. However, proton exchange membrane fuel cells (PEMFCs) have problems such as the use of expensive platinum catalysts for the reduction of conductivity under high temperature humidification conditions. Thus, an anion exchange membrane fuel cell (AEMFC) is attracting a great attention. Anion exchange fuel cells use non - Pt catalysts and have the advantage of better efficiency because of the lower activation energy of the oxygen reduction reaction. However, there are various problems to be solved including problems such as the electrode damage and reduction of ion conductivity by being exposed to the carbon dioxide. Therefore, this mini review proposes various solutions for different problems of anion exchange fuel cells through a wide range of research papers.

A Comprehensive Review of PEMFC Durability Test Protocol of Pt Catalyst and MEA (수소연료전지 백금촉매 및 MEA 장기내구성 평가 방법의 비교)

  • Ham, Kahyun;Chung, Sunki;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.659-666
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    • 2019
  • Proton exchange membrane fuel cells (PEMFCs) generate electricity by electrochemical reactions of hydrogen and oxygen. PEMFCs are expected to alternate electric power generator using fossil fuels with various advantages of high power density, low operating temperature, and environmental-friendly products. PEMFCs have widely been used in a number of applications such as fuel cell vehicles (FCVs) and stationary fuel cell systems. However, there are remaining technical issues, particularly the long-term durability of each part of fuel cells. Degradation of a carbon supported-platinum catalyst in the anode and cathode follows various mechanistic origins in different fuel cell operating conditions, and thus accelerated stress test (AST) is suggested to evaluate the durability of electrocatalyst. In this article, comparable protocols of the AST durability test are intensively explained.

Environment-friendly Coating Technology of UV/EB Radiation Curing (친환경 UV/EB 경화형 기능성 코팅 기술)

  • Lee, Jung-Bok;Lee, Jin-Hui;Sung, Ki-Chun
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.159-173
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    • 2012
  • UV-Curing technology can be classified into two categories for radical curing and cation curing. It also has mainly focused on surface finishing technology to improve functionality of various substrates such as plastics and metals. On the other hand, EB technology has dealt with cross-linking reactions as well as polymerization process to create novel functional materials. Both technologies have advantages in energy utilizing efficiency and environmental friendly when compared to conventional thermoset coatings. Consequently, UV cured coatings also permits a reduction in the $CO_2$ and VOCs emitted in the drying and curing process. This review mainly shows radical curing technology which is commonly used in UV curing coatings and also describes the technology trends of cation curing which has been attracted attention recently.

The performance evaluation for H2 reforming of the plate type hydrogen generation system (평판형 수소생산시스템의 수소개질 성능평가)

  • Heo, Su-Bin;Yun, Bong-Seock;Lee, Do-Hyung
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.602-608
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    • 2014
  • Hydrogen energy, a field of low-carbon substitute energy, can be produced by fossile fuel reforming and electrolysis of water etc. We developed 1kW class flat type reformer for PEM Fuel Cells. The PEMFC is highly sensitive to carbon monoxide because CO has detrimental effects on the performance of the fuel cell. Thus, reformed gas supplied to Fuel cell system, which maintained CO concentration below 10ppm. After applying optimum drive condition, reformed gas was measured with gas chromatography and could find out about each experimental condition of $H_2$ and CO concentration. As a results, The 1kW class plate type hydrogen generation system's optimum condition is A/F ratio ${\alpha}=1.3$, STR temperature 1023K, S/C ratio 3, and $PrOx1{\cdot}2$ 30cc/min. It turns out that installation of PrOx 2 stage is more efficient for reducing CO concentration.

Eco-friendly Fabrication Process of Al-Ti-C Grain Refiner

  • Cho, Hoon;Kim, Bong-Hwan
    • Journal of Korea Foundry Society
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    • v.30 no.4
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    • pp.147-150
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    • 2010
  • An eco-friendly production technique of Al-8.6Ti-0.025C refiner was developed by melting a Al-Ti master alloy in a graphite crucible, in which the potential nucleation site, TiC effectively formed by the spontaneous in-situ reaction between excessive Ti and carbon from graphite crucible. The A3003 alloy refined by the Al-8.6Ti-0.025C showed effectively refined macrostructure and enhanced mechanical properties comparable to the commercial Al-Ti-B refiner. The effective refinement was achieved in a shorter compare to the melt-treating time commercial Al-Ti-B refiner.

Deicing Performance of Environment-friendly Deicing Agents (친환경 제설제인 CMO의 성능평가 분석)

  • Lee, Seung-Woo;Woo, Chang-Wan;Kim, Jong-Oh;Park, Hee-Mun
    • International Journal of Highway Engineering
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    • v.7 no.3 s.25
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    • pp.53-62
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    • 2005
  • Efficient snow-removing work is one of important processes of winter road management. Calcium chloride has been used as a typical deicing agent in Korea. It presents superial performance as snow deicing agents, however it has been known to give serious environmental problem and to deteriorate durability of concrete structure in road by corrosion. The environment-friendly road deicing agents made from the waste material which is liquid phase organic matter that is Ca Mg and reactant of organic acid (nitric acid and propionic acid) have been introduced by number of researchers. They indicated the calcium magnesium salt of organic acids have advantage over the calcium choride in terms of lower production unit cost by resources recycling and can solve environmental problem and durability deterioration of structures. In this study, the deicing performance of calcium magnesium salt of organic acids(CMO) is investigated based on the series of experiments including the test for heat of dissolution, freezing point, ice melting test and ice penetration test.

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Dielectric and piezoelectric properties of (1-x)$(Na_{0.5}K_{0.5})NbO_3$ - $x(Ba_{(1-y)}Sr_y)TiO_3$ ceramics ((1-x)$(Na_{0.5}K_{0.5})NbO_3$ - $x(Ba_{(1-y)}Sr_y)TiO_3$의 유전 및 압전 특성)

  • Kim, Mi-Ro;Song, Hyun-Cheol;Choi, Ji-Won;Cho, Young-Soo;Kim, Hyun-Jai;Yoon, Seok-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.59-59
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    • 2008
  • Pb(Zr,Ti)$O_3$(PZT)는 현재 가장 우수한 압전특성을 가진 압전 재료로써, 압전효과와 역압전효과를 이용한 압전 액추에이터, 압전 트랜스듀서, 센서, 레조네이터 등의 활동에 대한 연구과 활발하게 이루어 지고 있다. 그러나 압전성이 우수한 PZT 세라믹스들은 Pb 성분이 포함되어 있기 때문에 환경오염뿐 아니라, 경제적인 측면에서도 많은 문제점을 가지고 있어 최근에는 유해원소인 Pb를 포함하지 않는 친환경 압전 세라믹스에 관한 연구가 활발히 진행되고 있다. (Na, K)$NbO_3$은 뛰어난 특성을 가지고 있어 Pb를 기본조성으로 하는 압전세라믹스를 대체할 수 있는 대표적인 물질중의 하나로 알려져 있다. 그러나, potassium의 수분과의 반응성과, 소결시 휘발로 인해 높은 소결밀도의 NKN을 제조하기 어렵다. 이러한 단점을 보안하기 위해 Hot pressing, Hot forging, SPS 등 여러가지 방법을 이용하여 연구가 수행되고 있지만, 고가의 제조공정을 이용해야만 한다. 본 연구에서는 $BaSrTiO_3$의 새로운 고용체를 추가시켜 기본 NKN 조성보다 소결밀도, 유전 및 압전특성을 향상시키고자 하였다.

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