• Journal of the Korea Organic Resources Recycling Association
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• v.32 no.1
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• pp.39-47
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• 2024

In this study, LiDAR-detective black material is synthesized by recycling silicon sludge (SS) that is generated from semiconductor manufacturing process, and its recognition is confirmed using two types of LiDAR sensors (MEMS and Rotating LiDAR). In detail, metal impurities on the surface of SS is removed, followed by coating of titanium dioxide (TiO₂) and subsequent chemical reduction to obtain SS-derived black TiO₂ (SS/bTiO₂) material. As-prepared SS/bTiO₂ is mixed with transparent paint to prepare hydrophilic black paints and applied to a glass substrate using a spray gun. SS/bTiO₂-based paint shows similar blackness (L^*=15.7) compared to commercial carbon black-based paint, and remarkable NIR reflectance (26.5R%, 905nm). Furthermore, MEMS and Rotating LiDAR have successfully detected the SS/bTiO₂-based paint. This is attributed to the occurrence of high reflection of light at the interface between the black TiO₂ and the silicon sludge according to the Fresnel's reflection principle. Hence, the new application field to effectively recycle silicon sludge generated in the semiconductor manufacturing process has been presented.

• Korean Journal of Environment and Ecology
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• v.28 no.3
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• pp.357-364
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• 2014

This study aimed to determine effects of the use of water-retention additive, hydrophilic polymer, for extensive green roofs on growth of Juniperus chinensis var. sargentii and Euonymus fortunei 'Emerald and Gold' for woody plants, and Carex kobomugi and Carex pumila for herbaceous plants. Five different contents of hydrophilic polymer including 0% (Control), 1.0%, 2.5%, 5.0%, and 10% (polymer: medium (w/w), dry weight basis) were added to each of the container filed with a 100 kg of growth medium. Ten of plants were transplanted in each of square container ($1m(L){\times}1m(W){\times}0.3m$ (H)) built on the roof platforms in randomized complete block design in the $20^{th}$ of May, 2013. In results, excessively high volumetric soil water content, about 97-98%, was found in the substrate under elevated hydrophilic polymer concentration of at least 2.5%, during the entire growing period. The moisture content of the substrate containing 1.0% of hydrophilic polymer was higher about 20% in the range between 70% and 80%, compared tho that of Control substrate in the range between 50% and 60%, for 27 days after transplanting prior to abundant rainfall, indicating that the application of hydrophilic polymer to the extensive green roof substrate is effective to eliminate drought condition by retaining water in the substrate. Euonymus fortunei 'Emerald and Gold' and Carex kobomugi resulting in higher plant growth with 2.5% than those of the other treatment plants. Juniperus chinensis var. sargentii was observed the highest growth under 1.0% hydrophilic polymer treatement, and Carex pumila was founded the best growth with Control respectively. Plants that grown in both the 1.0% and 2.5% hydrophilic polymer survived all, while the plants that grown in the 5.0% and 10% hydrophilic polymer died after 3 months. These results suggest that advantage of the addition of hydrophilic polymer may be greater in drought-tolerant plants, but the mixture proportion of hydrophilic polymer should be determined according to the different features of the plant species being grown.

• Spatial Information Research
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• v.4 no.1
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• pp.21-42
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• 1996

The Anyang-cheon is one of the Han River tributaries in Seoul Metropolitan area. It is 35.1km long, has a basin area of 287km2 and touches seven cities of Kyounggi Province and part of Seoul. The purpose of this study were 1) to reconstruct the ancient stream network and to investigate the change of landuse in Anyang-cheon watershed between 1957 and 1991,2) to measure the change of the hydrologic ¬acteristics with urbanization, 3) to suggest the institutional solutions to reduce natural hazard as the area has urbanizedThe main results are as follows: 1.Anyang-cheon river basin has experienced the rapid urbanization and industrialization since 1957. Anyang-cheon stream network was oversimplified in the watershed. The total stream length decreased atributaries in the upper part of river basin have eliminated or buried undergrolmd in pipes. 2.Urbanization impacted to all of the area of Anyang-cht'On watershed. Urbanization in Anyang-cheon watershed corresponds to the large portion of flat area, especially flood - prone zone of river side, and the small portion of Greenbelt to constrain urban expantion in cities. 3.The urbanization of Anyang-cheon watershed produces fundamental changes in watershed hydrology. As infiltration is reduced by the creation of extensive pavement, concrete surface, and sewer pipe, runoff moves more quickly from upland to stream. As a result, runoff from the watershed is flashier, increasing flood hazardAs urban area continue to grow we will need to better utilize stream by protecting and enhancing stream systems.otecting and enhancing stream systems.tems.

• Journal of the Korean Association of Geographic Information Studies
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• v.8 no.3
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• pp.74-83
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• 2005

The Riparian Buffer Zone has many potential values including the preservation of water quality as well as being ecologically friendly. This study aims to quantitatively analyze the landscape structure index of the Riparian Buffer Zone in the Kyoung-an stream and to produce base information necessary for proper management. The study used aerial images that were applied to geometric corrections for a time series from 1966 to 2000 for land data and also used FRAGSTATS, which is a type of ARCVIEW extension module, as an analysis tool. An analysis of land use change and the Landscape Index revealed that the area of farm land has decreased and that the area of residential property has increased. In addition, there was a slight change for land used for purposes other than farming or for residence. The results of analyzing the Landscape Structure Index, revealed that the NP has increased from 437 in 1966 to 695 in 2000. This data reveals that the change of land use is influenced by various artificial factors. The NPS, which represents the declining degree of patch, decreased from 9.441 to 5.934, revealing that the change of land use has been progressing considerably. In regard to forest areas, land use reduced somewhat but did not indicate a significant change. Therefore, an analysis of the total index reveals that the edge of patch has become more complicated and that the variation index of patch has increased significantly. However, this study reveals that barriers to block pollution have weakened as a result and that there is a need to concentrate on the implementation and the management of the Riparian Buffer Zone. Consequently, this study reveals that substantial research is necessary in order to carry out the proper management of the Riparian Buffer Zone, especially in light of the distribution type of each patch and the change in conditions regarding them.

• Journal of the Korean Institute of Gas
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• v.22 no.5
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• pp.53-61
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• 2018

Low-salinity water based polymerflooding (LSPF) is one of promising enhanced oil recovery (EOR) method that has the synergetic effect of combining polymer injection method and low-salinity water injection method. In order to maximize EOR efficiency, it is essential to design low-salinity water appropriately considering the properties of polymer. In this aspect, the main purpose of this study is to investigate the effect of pH and $SO_4{^{2-}}$ ion which one of PDI (Potential Determining Ion) on oil production when applying LSPF to carbonate oil reservoir. First, the stability and adsorption of polymer molecule were analyzed in different pH of injection water and $SO_4{^{2-}}$ concentration in injection water. As a result, regardless of pH and $SO_4{^{2-}}$ concentration, when $SO_4{^{2-}}$ ion was contained in injection water, the stability of polymer solution was obtained. However, from the result of polymer retention analysis, in neutral state of injection water, since $SO_4{^{2-}}$ interfered the adsorption of polymer, the adsorption thickness of polymer was thinner as $SO_4{^{2-}}$ concentration was higher. On the other hand, when injection water was acidic as pH 4, the amount of polymer adsorption increased with the injection of polymer solution, so the mobility of polymer solution was greatly lowered. From the results of wettability alteration due to low-salinity water effect, in the case of neutral injection water injected, as $SO_4{^{2-}}$ concentration was increased, more oil which attached on rock surface was detached, altering wettability from oil-wet to water-wet. On the other hand, in acidic condition, due to complex effect of rock dissolution and polymer adsorption, wettability of the entire core system was less altered relatively to neutral condition. Therefore, it was evaluated that better EOR efficiency was obtained when injecting low-salinity water based polymer solution containing high concentration of $SO_4{^{2-}}$ with neutral condition, enhancing the oil production up to 12.3% compared to low-salinity water injection method.

• Restorative Dentistry and Endodontics
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• v.33 no.1
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• pp.9-19
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• 2008

The purpose of this study was: (1) to compare nanoleakage patterns of a conventional 3-step etch and rinse adhesive system and two experimental hydrophobic adhesive systems and (2) to investigate the change of the nanoleakage patterns after load cycling. Two kinds of hydrophobic experimental adhesives, ethanol containing adhesive (EA) and methanol containing adhesive (MA), were prepared. Thirty extracted human molars were embedded in resin blocks and occlusal thirds of the crowns were removed. The polished dentin surfaces were etched with a 35 % phosphoric acid etching gel and rinsed with water. Scotchbond Multi-Purpose (MP), EA and MA were used for bonding procedure. Z-250 composite resin was built-up on the adhesive-treated surfaces. Five teeth of each dentin adhesive group were subjected to mechanical load cycling. The teeth were sectioned into 2 mm thick slabs and then stained with 50 % ammoniacal silver nitrate. Ten specimens for each group were examined under scanning electron microscope in backscattering electron mode. All photographs were analyzed using image analysis software. Three regions of each specimen were used for evaluation of the silver uptake within the hybrid layer. The area of silver deposition was calculated and expressed in gray value. Data were statistically analyzed by two-way ANOVA and post-hoc testing of multiple comparisons was done with the Scheffe's test. Silver particles were observed in all the groups. However, silver particles were more sparsely distributed in the EA group and the MA group than in the MP group (p < .0001). There were no changes in nanoleakage patterns after load cycling.

• KSBB Journal
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• v.23 no.3
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• pp.231-238
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• 2008

The second family member of tissue inhibitors of matrix metalloproteinases, TIMP-2, is a 21kDa protein which inhibits matrix metalloproteinases 2 (MMP-2). Expression of mammalian proteins in E. coli often forms inclusion bodies that are made up of mis-folded or insoluble protein aggregates. The requirement for the formation of 6 disulfide bonds in the process of the TIMP-2 folding is likely to be incompatible with the reducing environment of E. coli. However, this incompatibility can be often overcome by introducing a mutagenesis that could lead to enhancement of the protein solubility. In this reason, we have attempted to express the soluble TIMP-2 in E. coli by applying a modified staggered extension process (StEP), one of the in vitro PCR-based recombinant mutagenesis methods, and error-prone PCR. C-terminally located CAT fusion protein with respect to mutated TIMP-2 proteins enables us to differentiate the soluble TIMP-2 from the insoluble in E. coli by virtue of chloramphenicol resistance. According to this scheme, E. coli harboring properly-folded CAT fused to TIMP-2 protein was selected, and some of the resulting colonies exhibited an enhanced, soluble expression of TIMP-2 compared to the wild type, implying (i) the StEP technique is successfully employed to enhance the proper folding thereby increasing the solubility of TIMP-2, and (ii) the CAT dependent screening may be a simple and effective method to differentiate the soluble protein expression in E. coli.

• Korean Journal of Food Science and Technology
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• v.25 no.2
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• pp.109-117
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• 1993

To investigate the effects of sodium alginate, gum karaya and gum arabic on the foaming properties of sodium caseinate, surface tension, specific viscosity, turbidity, foaming ability and foam stability of the caseinate solution with added gums were examined. Surface tensions of the 5%(w/v) protein solutions containing gums at pH 7.0 and 8.0 were $43.7{\sim}44.7dyne/cm$ and $43.6{\sim}44.0 dyne/cm$, respectively. Specific viscosities of the solutions with 0.2 and 0.3% sodium alginates were 15.6 and 39.1 at pH 7.0 (control, 2.8), and 12.1 and 8.2 at pH 8.0 (control, 2.6), respectively. Turbidities were $69.5{\sim}74.0$ at pH 7.0 and $68.0{\sim}72.5$ at pH 8.0. The optimum conditions for foaming ability of the solutions were 0.1% conc. and 15 min whipping in addition of sodium alginates; 0.2% conc. and 20 min whipping in gum karaya; 0.1% conc. and 10 min whipping in gum arabic. For foam stability optimal concentrations were 0.3% in sodium alginate and gum karaya at pH 7.0 and 0.2% at pH 8.0. Addition of sodium alginates was most effective to increase foam stability of the solution, but was not effective to increase foaming ability. At same pH, surface tensions and turbidity of the solutions were related to foaming ability and specific viscosities were related to foam stability.

• Journal of Conservation Science
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• v.32 no.2
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• pp.167-178
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• 2016

Despite the size layer is an important part for conserving the artworks in the configuration of oil painting, the conservation scientific approaches of that have not been made yet. Therefore, this study produced standard samples on the basis of the analysis results of oil painting works, and carried out the evaluation of functions of the size layer materials. As a result of literature material, traditionally, animal glue was used for the size layer, whereas synthetic resin have been used in combination with animal glue since the modern age, in particular, it was identified that Polyvinyl Acetate(PVAc) was in general use. As a result of analysis of oil painting works, size layer was detected on the support and it was identified as animal glue. As a result of analysis based on Funaoka canvas for ground, it showed that the lead oxide and the titanium dioxide were the main constituents. On the basis of these results, standard samples were produced. As a result of evaluation on the functions of the size layer materials, in the case of the animal glue, stable result was observed in the shrinkag expansion rate, whereas slight weakness was observed in moisture proofing, color, and tensile strength, and dense cracks were found on surface. As for PVAc(A), moisture proofing, color, and the tensile strength exhibited stable results. Higher shrinkage rate was observed and the cracks with wide gaps were found on surface. As for PVAc(B), tensile strength, shrinkage expansion rate, and surface observation showed stable results, whereas moisture proofing property showed poor results. Different aspects were observed in each experiment, and this phenomena were considered to be due to the density and the adhesion properties between the hydrophilic and hydrophobic molecules in the size layer materials. The results are expected to be used as materials for the oil painting work conservation henceforth.

• Journal of Korean Ophthalmic Optics Society
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• v.17 no.2
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• pp.135-141
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• 2012

Purpose: Polymerization of HEMA(2-hydroxyethyl methacrylate) which can be used in the soft contact lens has been performed by using electron beam(EB) irradiation, and examined the best condition for the polymerization. Comparing the physical properties of the contact lenses to the one fabricated by thermal polymerization method, we check the use possibility of the EB irradiation to the fabrication of the soft contact lens. Methods: We investigated the degree of polymerization of the HEMA according to the composition of the monomer, the additive ratio and the dose of electron beam (0~120 kGy). The degree of polymerization was measured depending on the EB dose to research the best synthetic condition under the EB irradiation. The physical properties of the contact lens such as water content(%), oxygen transmissibility(Dk/t) and optical transmittance were analysed by using the FT-IR results with comparing the two different polymerization method (thermal and electron beam polymerization) with same additive ratio. Results: When the dose of electron beam was above 100 kGy, the degree of polymerization of HEMA was above 99% with regardless using cross-linker and initiator. The water content of the lens fabricated by EB method showed 10% higher than the one by the thermal method which was 40%. The lens fabricated by EB method also showed higher oxygen transmissibility(Dk/t) as same with the water content, and showed twice higher value in the lens fabricated by pure HEMA. According to the FT-IR results, hydrophilic property of the lens fabricated by EB method was increased due to increasing the intermolecular hydrogen bonding. It showed above 90% optical transmittance in the visible range of wavelength on the contact lenses fabricated by the both of two different polymerization method. Conclusions: The polymerization of HEMA without cross-linker and initiator was successful above 100 kGy of EB irradiation. Moreover the lens fabricated from the polymer synthesized by pure HEMA with 100 kGy of EB showed the highest water content and oxygen transmissibility. Therefore EB irradiation is another possible method to synthesize the polymer which can be used for the soft contact lens.