• Title/Summary/Keyword: 층간 결함

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Electrochemical Aspects of Lithium and Sodium Intercalation into Two Dimensional FeMo$O_4$Cl (리튬과 소듐이 층간삽입된 FeMo$O_4$Cl의 전기화학적 성질)

  • Chang, Soon Ho;Song, Seung Wan;Choy, Jin Ho
    • Journal of the Korean Chemical Society
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    • v.41 no.9
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    • pp.488-494
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    • 1997
  • Lithium and sodium ions have been intercalated into two dimensional structure of $FeMoO_4Cl$. The electronic localization and the large difference in unit cell parameter between the pristine material and the intercalates lead to the existence of large biphased domains. In the case of the lithium system, a narrow range of $Li_xFeMoO_4Cl$ ($0.95{\leq}x{\leq}1.06$) solid solution has been found around the $LiFeMoO_4Cl$ composition. The OCV curve fitting has been performed using Armand's model. The occurrence of several parts in the charge-discharge curve is related to the electronic and structural modifications of the material during the intercalation process.

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Mode II Interlaminar Fracture Toughness of Hybrid Composites Inserted with Different Types of Non-woven Tissues (종류가 다른 부직포가 삽입된 하이브리드 복합재료의 모드 II 층간파괴인성)

  • Jeong, Jong-Seol;Cheong, Seong-Kyun
    • Composites Research
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    • v.26 no.2
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    • pp.141-145
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    • 2013
  • The mode II interlaminar fracture toughness was evaluated for CFRP laminates with different types of nonwoven tissues and the source of increased mode II interlaminar fracture toughness was examined by SEM analysis in this paper. The interlaminar fracture toughness in mode II is obtained by an end notched flexure test. The experiment is performed using three types of non-woven tissues: 8 $g/m^2$ of carbon tissue, 10 $g/m^2$ of glass tissue, and 8 $g/m^2$ of polyester tissue. On the basis of the specimen with no non-woven tissue, interlaminar fracture toughness on mode II at specimens inserted with non-woven carbon and glass tissues and polyester tissues increases as much as 166.5% and 137.1% and 157.4% respectively. The results show that mode II interlaminar fracture toughness of CFRP laminates inserted with nonwoven tissues increased due to the fiber bridging, fiber breakage, and hackle etc. by SEM analysis.

Wi-Fi-Based Low-Complexity Floor Number Determination Method Based for Multistory Buildings (다층 건물을 위한 Wi-Fi 기반의 저 복잡도 층간 위치 측위 기법)

  • Shi, Jian;Li, Xiang;Jung, Honggyu;Kim, Jinoh;Shin, Yoan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.2
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    • pp.149-156
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    • 2014
  • Floor number determination has attracted considerable attention because many applications require accurate floor number information for providing better localization services in multistory buildings. This paper describes a Wi-Fi-based, low-complexity floor number determination method for multistory buildings. In our scheme, with the exception of floor ID and received signal strength of each WAP, detailed information on the wireless access point (WAP) coordinates is not needed. The multi-wall-floor model is used for the simulation and analysis. The simulation results show that the floor determination accuracy is nearly 100 given an adequate deployment density of WAPs on each floor. The results also show that the proposed method provides a good estimate of floor number even when only a few WAPs are implemented on each floor. Specifically, the proposed method can work under extreme conditions, i.e., where there are no WAPs on a floor.

Structures and Double Layer Performances of Carbons Pyrolized from Carbon Oxides (산화탄소로부터 열분해한 탄소의 구조 및 전기이중층 거동)

  • Kim, Ick-Jun;Yang, Sunhye;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo;An, Kye-Hyeok
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.522-526
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    • 2007
  • Structural features and electrochemical performances of cokes pyrolized from oxidized cokes were examined, and compared with KOH-activated coke. Needle cokes ($d_{002}=3.5{\AA} $), having a graphene layer structure, were changed to a single phase of graphite oxide after oxidation treatment with an acidic solution having an $NaCLO_3$/needle coke composition ratio of above 7.5, and the inter-layer distance of the oxidized coke was expanded to $6.9{\AA} $ with increasing oxygen content. After heating at $200^{\circ}C$, the oxidized coke was pyrolized to the graphene layer structure with inter-layer distance of $3.6{\AA} $. However, the change of the inter-layer distance of the needle coke was not observed in the KOH activation process. On the other hand, an intercalation of electrolyte ions into the pyrolized coke, observed at first charge, occurred at 1.0 V, in which the value was lower than that of KOH-activation coke. The cell capacitor using pyrolized coke exhibited a lower internal resistance of $0.57{\Omega}$ in 1 kHz, and a larger capacitance per weight and volume of 30.3 F/g and 26.9 F/ml at the two-electrode system in the potential range 0~2.5 V than those of the cell capacitor using KOH-activation of coke. This better electrochemical performance may be associated with structure defects in the graphene layer derived from the process of the inter-layer expansion and shrinkage.

2차원 층상 물질인 GaS, GaSe의 Van der Waals 상호작용에 대한 제일원리연구

  • Cha, Seon-Gyeong;An, Da-Bin
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.400-404
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    • 2015
  • 2차원 물질인 metal mono chalcogenides(MMC) 중 GaS와 GaSe를 대상으로 하여 층과 층 사이의 van der Waals(vdW) 상호작용을 density functional theory(DFT) 계산을 이용해 연구하였다. Local density approximation(LDA)와 generalized gradient approximation (GGA)의 두 가지 다른 exchange correlation functional을 이용하고, 또한 두 개의 층 사이에 작용하는 van der Waals 상호작용을 고려한 LDA-D2, GGA-D2 계산을 수행하였다. 이와 같은 네 가지 방법으로 층간거리를 바꾸어 binding energy curve를 계산하였다. 그 결과 GGA-D2계산이 MMC의 층간 상호 작용을 가장 잘 기술하였다.

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Evaluation of Judging Structural Performance Based Design in Steel Structure (강구조 건축물의 성능기반설계를 위한 성능규정치의 평가)

  • Oh, Sang-Hoon;Oh, Young-Suk;Hong, Soon-Jo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2009.04a
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    • pp.557-560
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    • 2009
  • 본 연구에서는 건물의 규모, 용도 및 형식 등에 따라 다양하게 요구되는 성능에 대응할 수 있도록 하기 위한 성능설계에 대한 개념을 검증하고, 강구조 건축물의 특성을 고려한 성능레벨 및 성능한계에 대한 분류방법을 제안하였다. 또한 강구조 건축물의 경우 강도가 높고 경량인 특성에 의해 다른 구조형식에서는 크게 고려하지 않아도 되는 거주성능 및 진동특성을 제어하여 기능을 유지하기 위한 성능레벨을 설정하여 구조물이 항복하기 전의 성능레벨을 기능유지 및 무손상의 2단계로 제시하고, 이 때의 한계치를 기능한계 및 손상한계로 구분하였다. 강구조 건축물의 손상한계를 정의하기 위해 강구조 건축물의 설계 예를 이용하여 항복 층간변형각을 조사하였다. 그 결과 구조물의 손상발생을 억제할 수 있는 손상한계를 규정하기 위해 주로 사용하고 있는 층간변형각은 구조형식 및 설계방법에 따라 편차가 크게 나타나고 있으므로 손상한계치의 층간변형각을 임의로 설정하는 것은 매우 어려우며 향후 이에 대한 해석적, 실험적 검증이 필요할 것으로 판단되었다.

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Development of Ventilation Silencer for Noise Reduction of Apartments (공동주택 층간소음 저감을 위한 환기장치용 소음기 개발)

  • Oh, J.W.;Lee, J.S.;Lee, J.H.;Lee, S.C.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.1247-1251
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    • 2006
  • 공동주택의 보급 증가에 따라 화장실과 같이 환기용 덕트를 통한 층간 소음전달 문제가 예상되어 환기용 덕트에 간단히 설치하여 층간 소음 전달을 차단할 수 있는 환기장치용 소음기를 개발하였다. 본 개발품은 소음 차단 기능이 확실하고, 구조가 간단하며 분해조립이 가능하여 설치 및 유지보수가 용이한 제품이다. 또한 습기에 의한 부식이 없고, 먼지와 습기를 쉽게 제거할 수 있는 특징이 있다. 성능시험 결과 환기용 덕트를 통한 소음의 전달을 10dB 이상 저감시킬 수 있고, 삽입에 의한 압력손실 2mmAq 이하가 됨을 확인하였다.

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Floor Noise Isolation System of the Residential Buildings Using Waste Rubbers (폐고무를 이용한 공공주택 층간소음차단 시스템)

  • Oh, Jeong Seok;Suh, Jaechan;Kim, Jin Kuk
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.427-431
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    • 2017
  • Recently, complaints of floor noise have been growing up with the rapid increase of the residential buildings. This demands the effective floor noise isolation system. Since the construction of high-rise the residential buildings will be increased even more in future, the noise isolation is a more important technology in the market. In this study, a new floor noise isolation panel (FNIP) was designed and manufactured using waste rubbers. The noise isolation was investigated at both laboratory and field conditions. Light and heavy weight shock wave showed 52 dB and 48 dB in the field test, respectively. The new system could reduce the total floor thickness by 22~42 mm.

Homogenization Analysis of Problems related to Quartz Dissolution and Hydroxide Diffusion (석영광물의 용해 및 수산화 이온의 확산에 관한 균질화해석)

  • Choi, Jung-Hae;Ichikawa, Yasuaki
    • The Journal of Engineering Geology
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    • v.20 no.3
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    • pp.271-279
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    • 2010
  • Time-dependent behavior similar to secondary deformation related to mineral dissolution is easily observed when performing a laboratory pressure experiment. In this research, to observe the dissolution of quartz found in bentonite used as buffer material for the geological disposal of high-level waste (HLW) under conditions of high pH, we calculated the diffusion of $OH^-$ ions and the behavior of quartz dissolution using the homogenization analysis method. The results reveal that the rate of quartz dissolution is proportional to the temperature and interlayer water thickness. In particular, in a high-pH environment, the reacted area (and therefore the dissolution rate) increases with decreasing interlayer water thickness.

Effect of Temperature on Interlaminar Fracture Toughness of Filament-Wound Carbon/Epoxy Composites (필라멘트 와인딩된 카본/에폭시 복합재의 층간파괴인성에 미치는 온도 영향)

  • Im, JaeMoon;Shin, KwangBok;Hwang, Taekyung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.5
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    • pp.491-497
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    • 2015
  • This paper reports an experimental study for evaluating the effect of temperature on the mode I, mode II and mixed-mode interlaminar fracture toughness of adhesive joints with a curved cross-section of filament-wound dome-separated composite pressure vessel. Mode I and mixed-mode interlaminar fracture toughness were evaluated using DCB specimens, while mode II interlaminar fracture toughness was determined using ENF specimens. $[{\pm}10^{\circ}]_6$, $[{\pm}27^{\circ}]_6$ and ($[{\pm}10^{\circ}]_3/FM73/[{\pm}27^{\circ}]_3$) winding specimens with the curved cross-section were considered. In-situ temperature environments were simulated with a range of $-30^{\circ}C-60^{\circ}C$ using an environmental chamber and furnace. Experimental results on the effect of temperature indicate that interlaminar fracture toughness tends to be high at low temperature and is degraded with increase in temperature. For specimen types, it was found that interlaminar fracture toughness of $[{\pm}10^{\circ}]_3/FM73/[{\pm}27^{\circ}]_3$ winding specimens considered as adhesive joints of dome and helical part was higher than other specimens.