• Journal of the Korean earth science society
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• v.38 no.7
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• pp.570-580
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• 2017

The purpose of the study was to evaluate the groundwater quality of Sinan-gun, Jeollanam-do, an island located in the southern part of the Korean peninsula where the effect of seawater on the groundwater quality had not been investigated in the past. In order to evaluate its effect, the hydrogeological parameters including groundwater quality and major dissolved components were investigated. The water quality was measured four times in the field, and 74 of 163 samples that showed the high conductivity value of more than $500{\mu}S/cm$ and the influence of seawater on the groundwater were analyzed by $Cl^-/HCO_3{^-}$ molar ratio. The results showed that, 40 samples out of 74 were found to have a value of 2.8 or more, indicating severe and very severe effects. According to the type of groundwater quality, the ratio of samples belonging to Na-Cl type, which is considered to be influenced by the direct seawater, is 35.3% for bedrock groundwater and 52.5% for weathered zone and alluvial groundwater. In the evolution stage of groundwater due to seawater infiltration, the type of Ca-Cl prior to the Na-Cl type is 44.1% in bedrock groundwater and 45% in weathered zone and alluvial groundwater. The effect of sea water on the aquifer is likely to be influenced by distance from the shore, pumped water, and tide.

• Economic and Environmental Geology
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• v.40 no.4
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• pp.403-418
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• 2007

The objective of this research was to characterize the fate and transport of Cr(VI) contaminated groundwater in the Daejeon industrial area. Five subsidiary monitoring wells were newly installed and two existing wells were utilized for the investigation and the reduction process of Cr(VI) contaminated groundwater of the Daejeon(Mun-pyeong) national groundwater monitoring station. The Cr(VI) concentrations at the shallow aquifer well of the station were in the range of 3.2-4.5 mg/L indicating continuous contamination. However, Cr was not detected at the deep bedrock well and the other monitoring wells except MPH-1 and 3. The Cr(VI) concentrations of MPH-1 and MPH-3 were below the drinking water guideline value (0.05 mg/L). Therefore, the plume of the Cr(VI) contaminated groundwater was predicted to be confined within the narrow boundary around the station. The soluble/exchangeable Cr(VI) concentrations were below the detection limit in all core and slime samples taken from the five newly installed wells. Although the exact source of contamination was not directly detected in the study area, the spatial Cr(VI) distribution in groundwater and characteristics of the core samples indicated that the source and the dispersion range were confined within the 100 m area from the monitoring station. The contamination might be induced from the unlined landfill of industrial wastes which was observed during the installation of an subsidiary monitoring well. For the evaluation of the natural attenuation of Cr(VI), available reduction capacities of Cr(VI) with an initial concentration of 5 mg/L were measured in soil and aquifer materials. Dark-gray clay layer samples have high capacities of Cr(VI) reduction ranging from 58 to 64%, which is obviously related to organic carbon contents of the samples. The analysis of reduction capacities implied that the soil and aquifer materials controlled the dispersion of Cr(VI) contamination in this area. However, some possibilities of dispersion by the preferential flow cannot be excluded due to the limited numbers of monitoring wells. We suggest the removal of Cr(VI) contaminated groundwater by periodical pumping, and the continuous groundwater quality monitoring for evaluation of the Cr(VI) dispersion should be followed in the study area.