• Title/Summary/Keyword: 충방전

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Effect of Preparation Conditions of PAN-based Carbon Fibers on Electrochemical Characteristics of Rechargeable Lithium ion Battery Anode (PAN계 탄소섬유 제조조건에 따른 리튬이온 이차전지 음극의 전기화학적 특성)

  • An K. W.;Lee J. K.;Lee S. W.;Kim Y. D.;Cho W. I.;Ju J. B.;Cho B. W.;Park D. G.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.81-87
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    • 1999
  • Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

Electrochemical Characteristics of EDLC with various Organic Electrolytes (유기전해질에 따른 EDLC의 전기화학적 특성)

  • Yang Chun-Mo;Lee J.K.;Cho W.I.;Cho B.W.;Rim Byung-O
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.113-117
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    • 2001
  • Specific capacitance and charge-discharge rate of EDLC using activated carbon electrode were affected by the compositions of electrolytes, the conditions of charge-discharge and physical properties of activated carbon materials. The activated carbon electrode was prepared by dip coating method. Charge-discharge test and electrochemical experiments were carried out for various kinds of organic electrolytes. Effects of charge and discharge current density on the specific capacitance were studied. Characteristics of leakage current, self-discharge and time-voltage curves in optimum conditions of organic electrolytes were compared with conventional $1M-Et_4NBF_4/PC$ electrolyte. The EDLC using MSP-20(specific surface area: $2000m^2/g$) electrode and $1M-LiPF_6/PC-DEC(1:1)$ was exhibited th highest specific capacitance of 130F/g and low polarization resistances. The EDLC using MSP-20 electrode at $1M-LiPF_6/PC-DEC(1:1)$ was small leak current of 0.0004A for 15min, long voltage retention of 0.8V after 100h and linear time-voltage curves with small IR-drop.

Electrochemical Characteristics of Ru Added Li4Ti5O12 as an Anode Material (Ru를 첨가한 음극활물질 Li4Ti5O12의 전기화학적 특성)

  • Cho, Woo-Ram;Na, Byung-Ki
    • Clean Technology
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    • v.20 no.4
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    • pp.433-438
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    • 2014
  • There is an increasing interest in the development of rechargeable batteries suitable for use in both hybrid electric vehicles and energy storage systems that require higher charge & discharge rates, bigger battery sizes and increased safety of the batteries. Spinel-type lithium titanium oxide ($Li_4Ti_5O_{12}$) as a potential anode for lithium ion batteries has many advantages. It is a zero-strain materials and it experiences no structural change during the charge/discharge precess. Thus, it has long cycle life due to its structural integrity. It also offers a stable operation voltage of approximately 1.55 V versus $Li^+/Li$, above the reduction potential of most organic electrolyte. In this study, Ru added $Li_4Ti_5O_{12}$ composites were synthesized by solid state process. The characteristics of active material were investigated with TGA-DTA, XRD, SEM and charge/discharge test. The capacity was reduced when Ru was added, however, the polarization decreased. The capacity rate of $Li_4Ti_5O_{12}$ with Ru (3%, 4%) addition was reduced during the charge/discharge precess with 10 C-rate as a high current density.