• Title/Summary/Keyword: 추출제

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Solvent Extraction of Zr(IV) and Hf(IV) from Sulfuric Acid Solutions by Acidic Extractants and Their Mixtures with TBP (황산용액에서 양이온계 추출제 및 TBP와의 혼합추출제에 의한 지르코늄(IV)과 하프늄(IV)의 용매추출)

  • Wang, Ling Yun;Lee, Man Seung
    • Resources Recycling
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    • v.25 no.2
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    • pp.3-9
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    • 2016
  • Separation of Zr(IV) and Hf(IV) from sulfuric acid solutions was investigated by extraction with several acidic extractants such as Versatic acid, LIX 63, and Cyanex 301. From strong sulfuric acid solutions, the separation of Zr(IV) and Hf(IV) by Versatic acid and LIX 63 was not possible, while selective extraction of Hf(IV) over Zr(IV) was obtained with Cyanex 301. However, the extraction percentage of the two metals was much lower compared to that by D2EHPA. Mixing of TBP with Cyanex 301 and D2EHPA led to negative effect on the extraction and separation of the two metal ions. The difference in the extraction reaction and separation selectivity between HCl, $HNO_3$ and $H_2SO_4$ media with each extractant was discussed.

The quality and sensory characteristics of tofu with various levels of black garlic extract (흑마늘 추출물 첨가 두부의 품질특성)

  • Sim, Hye-Jin;Hwang, Cho-Rong;Kang, Min-Jung;Kim, Gyeong-Min;Shin, Jung-Hye
    • Food Science and Preservation
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    • v.21 no.5
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    • pp.688-693
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    • 2014
  • The quality and sensory characteristics of tofu were investigated with various levels of black garlic extract (BE) added to it in 0, 1, 3, 5 and 7%-weight soymilk, before it was coagulated with $MgCl_2$ (MC, BEM-A, BEM-B, BEM-C and BEM-D) and concentrated to $8^{\circ}Brix$ deep ground sea-like water (SC, BES-A, BES-B, BES-C and BES-D). The overall acceptability of the tofu samples was higher (SC > BES-A > BEM-A) than that of the other samples. The addition of BE was influenced by the color, flavor and taste of the tofu, and the more BE was added, the tougher the tofu became. The tofu yield with various amounts of black garlic extract did not significantly differ among the samples. The pH range was 5.61~6.15 and decreased as more BE was added, whereas the turbidity increased. Also, the L value of the tofu decreased as more BE was added. The a value showed a tendency opposite that of the L value. The b value did not significantly differ among the samples. The texture profile analysis of the tofus showed that the hardness, chewiness, and gumminess significantly increased as more BE was added. In conclusion, it was found that the addition of 1% BE will improve the quality and sensory characteristics of tofu.

Separation of Iron and Nickel from Heavily Concentrated Aqueous Ferric Chloride Solution by Liquid-liquid Extraction (염화 제2철 농축 수용액으로부터의 액-액 추출에 의한 철과 니켈의 분리)

  • Park, Moo-Ryong;Kim, Young-Wook;Park, Jae-Ho;Park, Chin-Ho
    • Clean Technology
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    • v.13 no.4
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    • pp.274-280
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    • 2007
  • A liquid-liquid solvent extraction process was developed in this study to recover Fe and Ni from heavily concentrated aqueous ferric chloride solution, in an effort to substitute the conventional iron reduction method. Solvent composition and extraction conditions were first developed from the laboratory experiments, and the pilot system was designed and built for commercialization. Stage numbers for extraction and stripping were determined from pilot plant runs, and other operation data were obtained for mass production.

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수종 점막 추출액중 메치오닌엔케팔린 및 유사체의 분해 억제

  • 전인구;이치호;신영희
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1993.04a
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    • pp.178-178
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    • 1993
  • 생리활성 펩타이드류의 경점막 수송을 검토하기 위하여 토끼의 비강, 직장, 질 또는 눈 점막 구출액에서의 메치오닌엔케팔린 (Met-Enk) 및 그 합성 유사체인 [D-알라$^2$]-메치오닌엔케팔린아미드 (YAGFM)의 효소적 분해를 억제하고자 수종 효소억제제를 검토하였다. 방법: 토끼의 질, 직장 및 비강 점막을 차례로 적출하여 신속히 Valia-Chien투과셀에 마운팅하고, 눈의 각막은 절취하여 따로 각막 투과셀에 마운팅한 다음 등장 인산염 완충액 3.5ml씩으로 8시간씩 3회 추출하여 점막측 및 장막측 추출액을 제조하였다. 추출 완료 직후 이들 추출액에 Met-Enk 또는 YAGFM 50$\mu\textrm{g}$/ml의 농도로 첨가하고 여러 효소억제제를 단독 또는 혼합하여 첨가한 조건에서 37$^{\circ}C$에서 60 rpm으로 24시간 동안 흔들면서 경시적으로 시료를 취하여 잔존 펩타이드의 양을 HPLC법으로 정량하여 속도론적으로 비교 검토하였다. 이 연구에 사용한 효소억제제로는 아미노펩티다제의 억제제인 amastatin (AM), bestatin (BS). 엔케팔리나제 A의 억제제로 알려진 thiophan (TP), 엔케팔리나제 B의 억제작용이 있는 것으로 밝혀진 thimerosal (TM), metalloenzyme의 억제제인 에데트산나트륨 (EDTA) 등을 검토하였고 또 $\beta$-시클로덱스트린 유도체인 디메칠-$\beta$-시클로덱스트린과 2-히드록시프로필-$\beta$-시클로덱스트린이 펩타이드의 분해억제효과도 함께 검토하였다.

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A Study on the Segmentation of Kidney from the Non-Enhanced CT Image (조영제를 사용하지 않은 복보 CT영상에서 신장의 추출에 대한 연구)

  • 김선주;유승화;김종철;노승무;박종원
    • Proceedings of the Korean Information Science Society Conference
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    • 2000.04b
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    • pp.514-516
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    • 2000
  • 본 논문은 조영제를 사용하지 않은 정상인의 신장의 추출에 관한 연구로서 복구 CT 영상의 특성을 파악하고 신장부분을 분석함으로서 신장의 자동적인 추출을 시행하였다. 처리과정에서 기준값에 의한 이진영상에서 각 장기의 서로 다른 화소분포의 특징을 이용하여 장기추출을 시행하였고 템플리트를 이용한 서브트랙션과 채우기 과정을 거쳐 단일 슬라이스에서 신장을 추출한 후 추출된 신장영상의 슬라이스들을 겹친 영상을 생성하여 단일 슬라이스 내에서 제거되지 못한 노이즈들을 제거하였다.

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Separation of Copper & Cobalt by Solvent Extraction in Organic Acid Leaching Solution (유기산 침출용액에서 용매추출법에 의한 구리 및 코발트 분리)

  • Kim, Tae-Young;Ryu, Seong-Hyung;Ahn, Jae-Woo
    • Resources Recycling
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    • v.24 no.3
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    • pp.3-10
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    • 2015
  • A study has been made on the recovery & separation of cobalt and copper from organic acid leaching solution by solvent extraction. The experimental parameters such as the equilibrium pH, concentration of extractant and phase ratio were observed. Copper was extracted using LIX 84 and Cobalt was extracted using cyanex 272 and versatic acid 10. Experimental results showed that extraction percent of copper was 99% at above eq. pH 2.0 and then more than 90% of cobalt were extracted by cyanex 272 in eq. pH 6.0 and versatic acid 10 in eq. pH 7.5. Stripping of copper and cobalt from the loaded organic phases can be accomplished by sulfuric acid as a stripping reagent and 120 ~ 150 g/L of $H_2SO_4$ was effective for the stripping of copper and cobalt respectively. Finially, the basic optimal process for recovery of copper and cobalt from the bio-leaching solution was proposed.

Solvent Extraction of Lithium Ion in Aqueous Solution Using TTA and TOPO (TTA와 TOPO를 이용한 수용액 중의 리튬이온 용매추출)

  • Lee, Jeon-Kyu;Jeong, Sang-Gu;Koo, Su-Jin;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.53-57
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    • 2013
  • For the purpose of development of the extraction process of lithium ion from concentrated water eliminated from desalination process, an experimental research on the solvent extraction of lithium ion from aqueous solutions was performed. The effects of operating parameters, such as concentration of extractant, ratio of extracting solution/aqueous solution, pH of aqueous solution, were examined. The effect of sodium chloride, the major component of sea water, was also examined. Lithium ion in aqueous solutions of pH=10.2~10.6 adjusted by ammonia solution was most effectively extracted by extracting solution composed of 0.02 M TTA and 0.04 M TOPO in kerosine. The addition of sodium chloride in lithium aqueous solution significantly interfered the extraction of lithium ion.

Extraction and Separation of Protein-bound Polysaccharide by Lentinus edodes (표고버섯 배양액으로부터 단백다당류의 추출 및 정제 방법)

  • 박경숙;이별나
    • The Korean Journal of Food And Nutrition
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    • v.10 no.4
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    • pp.503-508
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    • 1997
  • The extraction and separation methods of protein-bound polysaccharides from the mycelium and culture broth of L. edodes were investigated. The use 2% solution of surface active agent, Triton X-100 was effective for extraction of the protein-bound polysaccharide from the mycelium. The extraction of the protein-bound polysaccharides from mycelium with hot water was achieved by 4 hours extraction at 10$0^{\circ}C$. For the separation and partial purification of the protein bound polysaccharides the column chromatography using DEAE-Cellulose, DEAE-Sephadex and Sephadex proved to be effective.

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Solvent Extraction of Hydrochloric Acid Using Commercial Extractants and Synthesized Ionic Liquids (상용화 추출제 및 이온성액체에 의한 염산의 용매추출)

  • Nguyen, Viet Nhan Hoa;Lee, Man Seung
    • Resources Recycling
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    • v.29 no.6
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    • pp.79-87
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    • 2020
  • The extraction and stripping of HCl from aqueous solutions by commercial extractants like LIX 63 and its mixture with TEHA/ Cyanex 923/ Aliquat 336 and ionic liquids like ALi-SCN, ALi-PC in kerosene was investigated. Among these extractants, ALi-PC showed the best extraction effectivity (above 80%), but it was difficult to strip HCl from the loaded phase. Although the extraction percentage of HCl by LIX 63 was not high, the stripping performance was above 81%. The addition of octanol to the organic phase led to negative effect on the extraction performance of HCl. The addition of C2H5OH into aqueous solutions significantly increased the extraction and stripping percentage of HCl by LIX 63, ALi-PC and ALi-SCN.

Reactive Extraction of Organic Acid with Amine Extractant, I. (A Study on the Effects of Extractant and Solvent on the Degree of Extraction in Reactive Extraction of Organic Acid) (아민 추출제에 의한 유기산의 반응추출(I) (유기산의 반응추출시 추출도에 미치는 추출제 및 용매의 영향에 관한 연구))

  • Ryu, Oon-Hyung;Lee, Han-Seob;Yoo, Chul-Hwi;Kim, Yong-Yeul;Kang, An-Soo
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.203-213
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    • 1996
  • In physical and reactive extraction system using equilibrium extraction equipment, the effects of extractants, concentration of extractant, and solvent on the degree of extraction were investigated. The organic acids used were acrylic acid and metacrylic acid. Extractants were n-octylamine(OA), di-n-octylamine(DOA), tri-n-octylamine(TOA) and tri-octylmetyl ammonium chloride(TOMAC ; Aliquat 336). We found that the degree of extraction for reactive extraction was 2~9 times than that for physical extraction and that effect of extractants on the degree of extraction of organic acid was the order of OA

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