• Title/Summary/Keyword: 최대흡수파장

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A study of faraday rotation for $Cd_{1-x}Mn_{x}Te$ single crystals ($Cd_{1-x}Mn_{x}Te$단결정의 Faraday 회전에 관한 연구)

  • 박효열
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.4
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    • pp.286-291
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    • 2000
  • $Cd_{1-x}Mn_{x}Te$ singe crystals were grown by the vertical Bridgman method and the Faraday rotations were measured as a function of wavelength and magnetic field. The Verdet constants were evaluated using the result of Faraday rotation. The Verdet constants were maximum at nearly absorption edge and increased for $0\leq x \leq 0.38 $ but decreased for x>0.40. We found that large Faraday rotation occur in $Cd_{0.62}Mn_{0.38}Te$ at nearly absorption edge wavelength was more useful for a magnetic field sensor than any other crystals, and $Cd_{0.60}Mn_{0.40}Te$ crystal was useful in this application when wavelength is He-Ne laser wavelength.

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Storage Stability of Anthocyanin Pigment Isolated from a Wasted Grape Peels (거봉(Black Olympia) 포도과피로부터 분리된 Anthocyanin색소지 저장안정성)

  • Hong, Joo-Heon;Chung, Hun-Sik;U, Hong;Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.9 no.3
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    • pp.327-331
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    • 2002
  • To develop the use of natural pigment for food, anthocyanins were isolated from grape peels which were wasted much in korea, and their characteristics were as fellows. pH has a marked influences on the color of the grape peels anthocyanin solution(GPAS). At low pH the color of GPAS was more stable than high pH. With increasing pH the color gradually fades as colorless pseudobases are formed. It showed characteristic bathnochromic shift as the solution increased. Among the sugars tested, glucose showed the most protective effect on the color of GPAS to raise the color stability, while fructose showed an adverse effect. Orgarnic acid such as citric acid prevented the degradation of anthocyanin, but ascorbic acid lowered stability of color considerably. The effect of light on GPAS was found to be very deleterious. The pigment degradation can be minimized by shielding the light from the pigment solution.

지르코니아 박막의 광학적 특성에 미치는 산소 효과에 관한 연구

  • Bang, Gi-Su;Yun, Hoe-Jin;Jo, Deok-Ho;Lee, Seung-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.360.2-360.2
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    • 2014
  • 박막 태양전지의 변환효율을 높이기 위해 전면에는 반사방지막을, 후면에는 고반사막을 적용한다. 태양전지 구조에서 고반사막을 대신하여 선택적 투과막을 적용할 경우 가시광선은 투과하고 적외선은 광 흡수층으로 재반사되기 때문에 변환효율을 향상 시킬 수 있고 동시에 투명 태양전지를 얻을 수 있다. 선택적 투과 특성을 보이는 지르코니아 박막의 광학적 특성이 이미 보고된 바 있으며, 본 연구에서는 반응성 스퍼터링 방식을 이용하여 지르코니아 박막을 증착하고 산소 유량에 따른 광학적 특성을 관찰한 후 이를 통해 선택적 투과막 성장에 적합한 산소 유량 조건을 얻고자 하였다. 산소 유량에 따라 지르코니아 박막의 투과율은 400 nm 이상의 파장에서 약 10%에서 약 85%의 범위에서 변화하였고 반사율은 적외선 영역에서 최소 약 30%에서 최대 약 60%의 수치를 나타내었다. 이러한 결과로부터 반응성 스퍼터링 시 산소 유량이 지르코니아 박막의 광학적 특성 변화에 큰 영향을 미치는 인자임을 확인하였다.

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Studies on Antifungal Substances Produced by a 2,4-dinitrophenol Resistant Soil Streptomyces spp.

  • Lee, Young-Nam;Yun, Yeo-Pyo;Lee, Do-Hoon;Hwang, Yoo-Sung;Lee, Hyeong-Kyu;Jang, Seung-Jae;Lee, Se-Chang
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1995.04a
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    • pp.68-68
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    • 1995
  • 청주 근처 토양에서 분리한 에너지 대사 저해제인 2,4-dinitrophenol (DNP)에 내성을 보이는 Streptomyces CM 001 균주가 생산하는 항진균성 물질(CUA)을 순수하게 분리 정제하고 화학분석을 통한 구조의 규명, 항진균활성 연구 및 유전적 변이원성(mutagenicity)등을 살펴보았다. CM 001 균주를 베네트 배지와 같이 영양성이 좋은 배지에서 배양시 항진균 활성이 동반 생성되는 색소와 비례적으로 증가했다. 배양 상등액 속의 항진균성 물질들을 염산처리, 유기용매처리 후 Amberlite XAD-4 column chromatography, silica gel adsorption-Sephadex LH-20 chromatography 과정을 통해 색소가 제거된 부분 정제 백색분말로 얻었다 이로부터 Prep. HPLC과정을 통하여 8종의 화합물을 각기 분리하였는데 이 화합물들은 동일한 UV spectrum과 216, 260nm에서 최대 흡수파장을 보였다.

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Properties of the Extracellular Protein Produced by Bacillus sp. $T_2-3$ (Bacillus sp. $T_2-3$가 생산한 균체외 단백질의 성질)

  • Lee, Jae-Sook;Kim, Chan-Jo;Lee, Jong-Soo
    • Applied Biological Chemistry
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    • v.31 no.4
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    • pp.382-386
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    • 1988
  • Extracellular protein produced by Bacillus sp. $T_2-3$ was characterized for its patterns of sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE) and sephadex G-100 filtration, spectrum of maximum absorption, composition of amino acid and solubility to solvents. The extracellular protein was composed of two kinds of protein which was little difference in molecular weight about 49,000. Maximum absorbance of the extracellular protein was showed at 230nm and main amino acids of the extracellular protein were aspartic acid, glutamic acid and alanine. Solubility of the extracellular protein was 55.8% in $H_2O$ and 28.4% in 0.4% NaOH.

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A study on the chemical and dyeing properties of Petasites japonicus leaf extract (머위잎 추출액의 염색성)

  • 김애순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.3_4
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    • pp.444-451
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    • 2004
  • This study was carried out to investigate the chemical and dyeing properties of Petasites japonicus leaf extract under the various extracting and dyeing conditions such as temperature, time, the ratio of water and pH, repetition of dyeing in silk and cotton fabrics with Petasites japonicus leaf. The results were as follows: 1. It was found that λ$_{\max}$ of color solution extracted by Petasites japonicus leaf has two peaks at 290nm and 323nm. 2. The optimum extracting conditions were studied at 10$0^{\circ}C$, 40min., pH 7 and 1 : 20(the ratio of water and Petasites japonicus leaf), the optimum dyeing temperature, dyeing time, dyeing pH and repetition of dyeing were 10$0^{\circ}C$, 60min., pH 7, repetitions of three times, respectively. 3. Silk and cotton fabrics dyed with Petasites japonicus leaf extract were colored yellowish orange. The colory Petasites japonicus leaf extract in silk and cotton fabrics were deeped by same-mordanting with aluminum potassium sufate and cupric sulfate. 4. Washing fastness of silk fabrics was 4∼5 grade, but cotton fabrics was 3∼4 grade, so washing fastness of silk fabrics washed with neutral detergent was excellent.

A Study on the Dyeing Properties of Yellow and Red Natural Dyes(1) (황색 및 적색계 천연염료의 염색성에 관한 연구(1))

  • Shin, Young-Joon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.17 no.2
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    • pp.45-61
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    • 2015
  • In order to analysis on color difference of natural dyes, I have dyed Hanji, cotton, silk fabric and exposed them to carbon arc light. The results of experiment have been analysed by wavelength of maximum absorption, amounts of dye uptake, color difference, Hunter's value and Munsell's value. Gardenia Jasminoides is monogenetic dye, but it gained darker color by pre-mordanting method used Al mordant agent and greenish yellow color by Fe mordant agent. whereas Curcuma, an Amur cork, and bud of pagoda tree are shown as greenish yellow color, and A barberry root, Betel nut, and Rhubarb are shown as reddish yellow color. these gained khaki colored dyed fabric by Fe mordanting. In addition, Sappan wood showed great result in pre-mordanting. Especially, it gained dark red color by Al pre-mordanting. The pink color was shown by post-mordanting. and Logwood showed great dyeing result in Hanji and cotton better than silk. Specially pre-mordanting was effective. Hanji and cotton showed greenish blue color by Al pre-mordanting, and silk showed brown color.

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Dyeing properties of rayon and cotton fabrics with Scutellaria baicalensis Georgi (Rayon직물과 면직물에서의 황금 염색성)

  • Bai, Sang-Kyoung
    • Journal of Fashion Business
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    • v.14 no.4
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    • pp.174-184
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    • 2010
  • This research was carried out to find the dyeing properties of Scutellaria baicalensis Georgi on the rayon and cotton fabrics. The best proper dyeing conditions were examined by changing dye concentrations, dyeing temperature, dyeing time, and dyeing repitition. Also dyeability and surface color changes were evaluated by various mordanting methods and agents. The maximum absorption of Scutellaria baicalensis Georgi were at 275nm and 362nm. The optimum dyeing conditions on the cotton were 80%, $80^{\circ}C$, 40minutes, 4 repitition, and those on the rayon were 80%, $80^{\circ}C$, 60minutes, 5 repitition. The K/S values of rayon and cotton fabrics were higher in pre-mordant than post-mordant. The K/S values on the rayons were lower than no mordant fabric except pre-Fe mordant, these on the cotton fabrics were higher than no mordant fabric except post-Al mordant. The value of ${\Delta}E$ was the highest in Fe mordanted fabrics, and higher on the cotton fabric than rayon. The surface colors of all mordanted fabrics were yellow.

Synthesis of Bis(dithiobenzil) Metal Complex and Its Photostability (Bis(dithiobenzil) 금속 화합물의 합성 및 광안정성)

  • Lee, Gun-Dae;Park, Na Yi;Jeon, Seung Yup;Heo, Jin;Son, Dae Hee;Hwang, Tae Kyung;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.433-437
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    • 2007
  • Bis(dithiobenzil) metal complex, used as functional NIR absorbing dye and photostabilizer, was synthesized using bezoin and anisoin as intermediate compounds. And squarylium, a charge generation material, was synthesized to find its photostability effect. The structure of the product was determined by $^1H-NMR$ and FT-IR and the thermal property was analyzed by DSC and TGA. Optical property and photostability were determined by UV-Vis-NIR spectroscopy. High absorbance was obtained in the NIR range and maximum absorbing wavelength was shifted depending on the nature and position of substituent in the bis(dithiobenzil) metal complex. The photofading effect of squarylium decreased by the addition of bis(dithiobenzil) metal complex.

Dyeing Properties of Silk Fabrics with Pteridium aquilinum Extract (고사리잎 추출액을 이용한 견직물 염색성)

  • 정진순;설정화;장정대
    • Journal of the Korean Society of Clothing and Textiles
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    • v.27 no.3_4
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    • pp.364-372
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    • 2003
  • In this study, the characteristics of catechol tannin and pyrogallol tannin contained in Pteridium aquilinum were analysed by It spectrum. Silk fabrics were dyed with Pteridium aquilinum extracts using various mordants, and their dyeing properties were discussed. Additionally the fastness the water digestion, perspiration liquid digestion and light irradiation were investigated. IR spectrum of catechol tannin showed bands of O-H at $3417cm^{-1}$, C-H at $2930cm^{-1}$, C=0 at $1722cm^{-1}$, C=C at $1644cm^{-1},\;CH_2\;at\;1402cm^{-1}$. And IR spectrum of pyrogallol tannin showed bands of O-H at $3409cm^{-1}$, C-H at $3003cm^{-1}\;and\;2933cm^{-11}$, C=0 at $1701cm^{-1}$, C=C at $1582cm^{-11},\;CH_2\;at\;1410cm^{-1}$, CO at carboxylic acid and carboxylic acid ester at $1287cm^{-1}\;and\;1135cm^{-1}$. The maximum absorption wavelength of the extracts appeared at 270.0nm and 311.5nm. The optimum conditions for dyeing silk fabric with Pteridium aquilinum extracts were $80^{\circ}C$, 60min. Surface color of the silk fabric dyed with Pteridium aquilinum extracts was 2.7Y Surface color of the pre-mordanted fabrics with Al, Cu and Fe were 4.3Y, 2.5Y and 4.7Y, respectively. And Surface color of the post-mordanted fabrics with Al, Cu and Fe were 3.7Y, 2.8Y and 0.2GY. The water fastness and the alkaline perspiration fastness were improved in the Al-mordanted silk fabrics. By acidic and alkaline perspiration treatment, ${\Delta}E of the unmordanted fabrics was lower than hat of pre- and post- mordanted fabrics. Also after 40hour irradiation, ${\Delta}E of the unmordanted fabrics was lower than that of pre- and post- mordanted fabrics.