• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.705-710
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• 2003

In this study, to confirm the diffusion coefficient of chloride ion is affected by the concentration of NaCl solution, capacity of voltage, time of an electric current, the diffusion coefficient of chloride ion in concrete was investigated through an electrochemical accelerated test. and the results of these test were compared with the diffusion coefficient of chloride ion by test of sodium chloride solution digestion. As the results of this study, the diffusion coefficient of chloride ion wasn't affected by the concentration of NaCl solution, capacity of voltage, time of an electric current within the range of this study and was similar to the diffusion coefficient of chloride ion by test of sodium chloride solution digestion.

• Journal of Navigation and Port Research
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• v.34 no.10
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• pp.787-792
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• 2010

It is necessary to predict the penetration of chloride ions for designing RC construction in marine environments. However, it takes a long time to obtain chloride migration coefficients. Therefore, the rapid chloride penetration test (RCPT) is generally used to shorten the test time. But there is a difference between chloride migration coefficients determined by rapid chloride penetration tests and those based on exposure in marine environments. In this study, we evaluated the effect on the chloride ion migration coefficient caused by a change in voltage and NaCl concentration. We also compared the relationship between the chloride ion migration coefficient by RCPT and that by exposure in marine environments. As a result of the experiments, we found that there is only a small change in the experimental factors based on changes in voltage and NaCl concentration and since they are so small, we can conclude that they are in the range of experimental error and test results from chloride ion migration coefficients by RCPT and exposure were very different from each other. In the exposure experiments, when the water-cement ratio was increased, the smaller fine air gaps in concrete affected the chloride ion migration coefficient.

• Journal of the Korea Concrete Institute
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• v.16 no.4 s.82
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• pp.485-492
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• 2004

In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.2
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• pp.136-143
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• 2013

In the sewage structures and wastewater facilities, concrete is exposed to hydrogen sulfide ($H_2S$) which acts as an acid material in a solution, and a strongly acidic sulfate ion ($SO{_4}^{-2}$) is generated by a sulfuric bacteria. Hence, a degradation of concrete with biochemical corrosion would be accelerated. Finally, durability of concrete and concrete structures may be greatly reduced. In this study, in order to remove the hydrogen sulfide which is used by the sulfuric bacteria organic-biologically, the antibiotic metal and metallic salt powders were mixed to concrete, and a suppressing performance of the sulfate ion was assessed. For the sulfuric acid bacteria, a comparative evaluation of antimicrobial performance on neutralized concrete specimens were carried out, also by a rapid chloride penetration test, chloride penetration depths and diffusion coefficients were measured for antibiotic concrete in accordance with the amount of metal and metallic salt-based antibacterial agents. Eventually, by an observation of the biochemical state of the surface of concrete specimens exposed outdoors, the performance and applicability of antibiotic concrete were confirmed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.5
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• pp.127-134
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• 2022

In this study, RCPTs (Rapid Chloride Penetration Test) were performed for fly ash concrete with curing age of 4 ~ 6 years. The concrete mixtures were prepared with 3 levels of water to binder ratio (0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash (0 and 30%), and the improved passed charges of chloride ion behavior were quantitatively analyzed. Additionally, the results were trained through the univariate time series models consisted of GRU (Gated Recurrent Unit) algorithm and those from the models were evaluated. As the result of the RCPT, fly ash concrete showed the reduced passed charges with period and an more improved resistance to chloride penetration than OPC concrete. At the final evaluation period (6 years), fly ash concrete showed 'Very low' grade in all W/B (water to binder) ratio, however OPC concrete showed 'Moderate' grade in the condition with the highest W/B ratio (0.47). The adopted algorithm of GRU for this study can analyze time series data and has the advantage like operation efficiency. The deep learning model with 4 hidden layers was designed, and it provided a reasonable prediction results of passed charge. The deep learning model from this study has a limitation of single consideration of a univariate time series characteristic, but it is in the developing process of providing various characteristics of concrete like strength and diffusion coefficient through additional studies.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.7
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• pp.4960-4968
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• 2015

In this study to improve the chloride durability of the shotcrete structure depending on types and contents of mineral admixture chloride resistance was evaluated by NT BUILD 492 of european test standards. It was also evaluated with the mechanical properties such as static strength and chloride penetration resistance. For shotcrete mixed crushed stone aggregate of the maximum size 10mm of coarse aggregates was produced. Based on 28days compression strength the variable mixed with 15% silica fume showed the highest strength in 67.55MPa. As the content of fly ash and blast furnace slag increased, the strength lowered. In the chloride penetration resistance test, OPC showed "high grade" and In the case of admixture, the penetration resistance tended to increase in all variables except the fly ash. In order to evaluate the service life, the accelerated chloride penetration test was conducted by the standards of KCL, ACI, FIB. Test results were obtained with the lowest spreading factor in a variable mixed with silica fume of 15%. At the KCI standards, It was found to have a service life of about 65 years and at the FIB standards, It was found to have a service life of 131 years. Among standards, the service life of KCI standard in all of the variables was evaluated as the lowest.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.520-527
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• 2020

Hwangtoh is the rich resource that accounts for about 15.0% of the domestic soil, and can be used as the admixture of concrete with Pozzolan characteristics if activated by rapidly freezing after burning with high temperature. In this study, the mortar curbs containing active hwangtoh were produced, based on the mixture for the mortar curbs sold on the market. The substitution rate of active hwangtoh were considered 10.0% and 25.0%, and the test items were selected to compressive and flexural strength tests, freezing/thawing resistance tests, accelerated carbonation tests, and accelerated chloride diffusion tests. In the results of the mechanical performance, it was showed that the highest strength was evaluated in OPC mixture, and the increase in strength was small by the increase of age, which was believed to be due to the fact that most of the strength in each mixture was created in three days of steam curing. The results of the freezing/thawing tests for 28 aged days showed the reduction rate of compressive strength was 85.0% or higher for all specimen, meeting the criteria presented. The accelerated carbonation tests were carried out on the specimen at 28 days of age, and the results showed that the mortar with active hwangtoh had lower carbonation resistance performance than mortar with OPC. The passed charge of each mixture was assessed in accordance with ASTM C 1202 on 28 and 91 aged days. The OPC mixture had "Low" rate and the mortar with active hwangtoh had "Moderate" rate. So it was thought that the mortar with active hwangtoh had appropriate resistance performance for chloride attack.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.311-320
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• 2011

Fly ash (FA), byproduct from power plant has been actively used as mineral admixture for concrete. However, since bottom ash (BA) is usually used for land reclaim or subbase material, more active reuse plan is needed. Pond ash (PA) obtained from reclaimed land is mixed with both FA and BA. In this study, 6 PA from different domestic power plant are prepared and 5 different replacement ratios (10%, 20%, 30%, 50%, and 70%) for fine aggregate substitutes are considered to evaluate engineering properties of PA as fine aggregate and durability performance of PA concrete. Tests for fine aggregate of PA for fineness modulus, density and absorption, soundness, chloride and toxicity content, and alkali aggregate reaction are performed. For PA concrete, durability tests for compressive strength, drying shrinkage, chloride penetration/diffusion, accelerated carbonation, and freezing/thawing are performed. Also, basic tests for fresh concrete like slump and air content are performed. Although PA has lower density and higher absorption, its potential as a replacement material for fine aggregate is promising. PA concrete shows a reasonable durability performance with higher strength with higher replacement ratio. Finally, best PA among 6 samples is selected through quantitative classification, and limitation of PA concrete application is understood based on the test results. Various tests for engineering properties of PA and PA concrete are discussed in this paper to evaluate its application to concrete structure.

• Journal of the Korea Concrete Institute
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• v.22 no.3
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• pp.305-311
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• 2010

The industrial by-product market has increased at a geometric rate worldwide with the rapid economic growth. At present time, conventional disposal methods of industrial by-products in Korea including landfill, incineration and storage already have reached their limits. In this study, the industrial by-products such as fly ash and silicafume were used as mineral admixtures, which are commonly added to concrete mix to inhance the economic efficiency, long-term strength and durability of concrete, to determine the optimized mix proportion of high performance shotcrete. Through the series of tests (compressive strength test, accelerated chloride ion penetration test, measurement of chloride diffusion coefficient). The results of the study showed that the proposed mix proportions satisfied the requirements of domestic as well as international guidelines for shotcrete, with a higher durability than the existing shotcrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.4
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• pp.96-102
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• 2019

When GGBFS(Ground Granulated Blast Furnace Slag) with high blaine is incorporated in concrete, compressive strength in the initial period is improved, but several engineering problems arise such as heat of hydration and quality control. In this paper, compressive strength and durability performance of concrete with 3,000 Grade-low fineness slag are evaluated. Three conditions of concrete mixtures are considered considering workability, and the related durability tests are performed. Although the strength of concrete with 3,000 Grade slag is slightly lower than the OPC(Ordinary Portland Cement) concrete at the age of 28 days, but insignificant difference is observed in long-term compressive strength due to latent hydration activity. The durability performances in concrete with low fineness slag show that the resistances to carbonation and freezing/thawing action are slightly higher than those of concrete with high fineness slag, since reduced unit water content is considered in 3,000 Grade slag mixture. For the long-term age, the chloride diffusion coefficient of the 3000-grade slag mixture is reduced to 20% compared to the OPC mixture, and the excellent chloride resistance are evaluated. Compared with concrete with OPC and high fineness GGBFS, concrete with lower fineness GGBFS can keep reasonable workability and durability performance with reduced water content.