• Title/Summary/Keyword: 촉진 염화물 확산계수

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Evaluation of Chloride Diffusion Characteristics in Concrete with Fly Ash Cured for 2 Years (2년 양생된 Fly Ash 콘크리트의 염화물 확산 특성 평가)

  • Yoon, Yong-Sik;Hwang, Sang-Hyeon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.8-15
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    • 2019
  • When RC(Reinforced Concrete) structures are exposed to harsh environment, deterioration phenomenon occurs, and the corrosion in rebar due to chloride intrusion is known as representative deterioration, so called chloride attack. In this paper, chloride resistance performance of 2 years aged concrete is evaluated considering 3 levels of water to binder ratio(0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash(0% and 30%). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests referred to KS F 2405 are performed. With adaptation of the previous test results and the results from this study, time-dependent chloride diffusion characteristics are analyzed for each concrete. The FA(Fly Ash) concrete has higher chloride resistance performance than OPC(Ordinary Portland Cement) concrete. According to the evaluation standard of ASTM C 1202, the FA concrete has "Moderate" grade after 49 days while OPC concrete does "Moderate" grade after 365 days. As the results of time-parameter for chloride diffusion, OPC concrete and FA concrete show the decreasing behavior of time-parameters with increasing water to binder ratio. Also, FA concrete has 1.57~2.74 times of time-parameter than OPC concrete. That's cause is thought that the time-parameter indicates the gradient of decreasing of diffusion coefficient. FA concrete has higher time-parameters than OPC concrete by pozzolanic reaction of FA.

Effect of Latex on Corrosion Resistance of Steel Rebar in Concrete (콘크리트 내에서 보강철근의 부식저항성에 미치는 라텍스의 효과)

  • Park, Sung-Ki;Won, Jong-Pil;Sung, Sang-Kyung;Park, Chan-Gi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.409-412
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    • 2008
  • This study were evaluated the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC). Accelerated testing was accomplished to the evalate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC are effected on the mix proportion factor including latex content, and water-cement ratio.

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Chloride Diffusion Coefficient Evaluation in 1 Year-Cured OPC Concrete under Loading Conditions and Cold Joint (하중조건과 콜드조인트를 고려한 1년 양생된 OPC 콘크리트의 염화물 확산계수 평가)

  • Oh, Kyeong-Seok;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.21-29
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    • 2017
  • Cold joint caused by construction delay is vulnerable to shear stress and it allows more rapid chloride penetration and diffusion. In the paper, investigation of chloride diffusion coefficient is performed for 1-year cured concrete considering compressive and tensile loading level and cold joint. The results are compared with the previous results in 91-day cured concrete. In the 1-year cured concrete without loading, 10.7% and 10.5% of diffusion reduction are evaluated for those in 91-day cured concrete, respectively. The reduction ratios are almost similar however the result in cold joint concrete shows much higher values. The results in 1-year cured concrete under 30% and 60% of compressive loading show reduction of chloride diffusion by 10.9% and 5.8% compared with 91-day cured results, which is caused by steady hydration of cement particles, so called, time effect. In the case of tensile loading, the differences in results are not significant regardless of time effect and cold joint since micro cracks which is weak point of concrete is much dominant despite of long term curing.

Corrosion Prediction of a Cement Mortar-Grouted Rockbolt by Measuring Its Chloride Diffusion Coefficient (시멘트 모르타르계 록볼트 충전재의 염화물 확산계수 측정을 통한 록볼트 부식 예측)

  • Bae, Gyu-Jin;Chang, Soo-Ho;Kim, Dong-Gyou;Park, Hae-Geun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.8 no.3
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    • pp.259-271
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    • 2006
  • This paper aims to predict the corrosion of a fully cement-grouted rockbolt induced by chloride diffusion in a cement mortar grout. From the viewpoint of the long-term durability, a rockbolt may be deteriorated by chemical components, such as sulphate and chloride, in groundwater. Especially, the steel rod of a rockbolt is corroded mainly by chloride. The rockbolt corrosion results in the volume expansion of a rod and then the cracking of a cement grout. In this study, the chloride diffusion coefficient of a cement mortar grout was used to evaluate the possibility of rockbolt corrosion by chloride, and to predict the long-term durability of a rockbolt. The electric acceleration test method was adopted to measure the chloride diffusion coefficient. In addition, a simple pullout testing system was newly proposed to measure the pullout capacity of a rockbolt more easily in a laboratory condition. From the experiments, it was showed that the chloride could diffuse in the cement grout more easily than in ordinary concrete materials. As a result, it was considered that a rockbolt might be easily corroded in a short term by the diffusion of chemical components with high concentration, although it was fully grouted.

Development of Maintenance Simulation System and Prediction of Chloride Ion Permeation for Marine Concrete Structures (해양콘크리트 구조물의 염해 예측 및 유지보수 시뮬레이션시스템 개발)

  • Lee, Chang Su;Kim, Meyong Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.1
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    • pp.64-75
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    • 2013
  • As both laboratory accelerated experiment and field exposure experiment were performed, at recent, the fifth field test at five year exposures was proceeded according to long period experimental plan. Field experiment, for the adoption of the developed evaluation model, which is consisted of the analysis of chloride penetration profile at gate bridges of sea-dike completed 30 years ago was carried out during upgrading the basic evaluation model with analyzing the annual field test data. The surface concentration of chlorides was replaced to the concentration of chloride of inner concrete near the surface chlorides among his research results at basic model. Maage's suggestion function was accepted too as a diffusion coefficient of chloride after verifying the change of diffusion coefficient by analysis of annual field test data. The comparison of field data with model predictions and the estimation of remaining life time demonstrates that the proposed updated model and maintenance simulation system can be used to predict the chloride penetration profile in the marine tidal zone and appropriate repair period and cost.

Crack and Time Effect on Chloride Diffusion Coefficient in Nuclear Power Plant Concrete with 1 Year Curing Period (1년 양생된 고강도 원전 콘크리트의 염화물 확산에 대한 균열 및 시간효과)

  • Chun, Ju-Hyun;Ryu, Hwa-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.83-90
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    • 2017
  • Concrete structure for nuclear power plant is mass concrete structure with large wall depth and easily permits cracking in early age due to hydration heat and drying shrinkage. It always needs cooling water so that usually located near to sea shore. The crack on concrete surface permits rapid chloride intrusion and also causes more rapid corrosion in the steel. In the study, the effect of age and crack width on chloride diffusion is evaluated for the concrete for nuclear power plant with 6000 psi strength. For the work, various crack widths with 0.0~1.4 mm are induced and accelerated diffusion test is performed for concrete with 56 days, 180days, and 365 days. With increasing crack width over 1.0mm, diffusion coefficient is enlarged to 2.7~3.1 times and significant reduction of diffusion is evaluated due to age effect. Furthermore, apparent diffusion coefficient and surface chloride content are evaluated for the concrete with various crack width exposed to atmospheric zone with salt spraying at the age of 180 days. The results are also analyzed with those from accelerated diffusion test.

Evaluation of Durability Performance of Fly Ash Blended Concrete due to Fly Ash Replacement with Tire Derived Fuel Ash (타이어 고무 애쉬 치환에 따른 플라이애쉬 혼입 콘크리트의 내구성능 성능 평가)

  • Kwon, Seung-Jun;Yoon, Yong-Sik;Park, Sang-Min;Kim, Hyeok-Jung
    • Journal of the Korea Concrete Institute
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    • v.28 no.6
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    • pp.647-653
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    • 2016
  • In the paper, durability performance in FA (Fly Ash) blended concrete is evaluated considering replacement of FA with TDFA (Tire Derived Fuel Ash) from 3.0% to 12%. TDFA is a byproduct from combustion process in thermal power plant, where chopped rubber is mixed for boiling efficiency. This is the 1st study on application of TDFA to concrete as mineral admixture. For the work, concrete samples containing 0.5 of w/b (water to binder) ratio and 20% replacement ratio of FA are prepared. With replacing FA with TDFA to 12%, durability performance is evaluated regarding compressive strength, carbonation, chloride diffusion, and porosity. The results of compressive strength, carbonation, and porosity tests show reasonable improvement in durability performance to 12% replacement of TDFA. In particular, clear decreasing diffusion coefficient is observed with increasing TDFA replacement due to its packing effect. Concrete containing TDFA can be effective for durability improvement when workability is satisfied in mixing stage.

Characteristics of Chloride Diffusion and Compressive Strength in the Mortar containing C12A7 based Binder and Anhydrite (C12A7계 바인더와 무수석고를 혼입한 모르타르의 염화물 확산 및 압축강도 특성)

  • Byeong-Cheol, Lho;Yong-Sik, Yoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.450-456
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    • 2022
  • In this study, as the preliminary research on the development of heating concrete members, compressive strength and accelerated chloride diffusion behavior in the mortar specimens containing C12A7 based binder and anhydrite was evaluated. Also, the effect of the mixing ratio of the citric acid based retarder was quantitatively evaluated by considering 4 levels of mixing cases. The compressive strength tests of the mortar specimen were performed referred to KS L ISO 679, and the accelerated chloride diffusion tests were performed according to NT BUILD 492 and ASTM C 1202. In the mortar with 0.3 % of retarder, the highest compressive strength was evaluated, which showed the strength development ratio of 127.6 % compared to the control case. It was considered that engineering performance was improved by effectively securing setting and curing time with 0.3 % of citric acid based retarder. As the result of the evaluation of the passed charge and the accelerated chloride diffusion coefficient, the evaluation results had similar behavior with the results of compressive strength. According to the previous study, the strength behavior and the chloride diffusion behavior had a linear relationship. The mixture showing the highest strength performance had the highest durability performance for chloride ingress, and the heating concrete development from this study will be performed in the future.

A Study on Performance Evaluation of Early-age Concrete with EOS Fine Aggregate and GGBFS (EOS 잔골재 및 GGBFS를 혼입한 초기재령 콘크리트의 성능 평가에 관한 연구)

  • Kwon, Seung Jun;Cho, Sung Jun;Lim, Hee Seob
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.113-119
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    • 2019
  • Many researches on alternative materials as construction materials is continuing by recycling industrial byproducts due to shortage of sitereclamation and natural aggregates. In this paper, engineering properties in early-aged OPC (Ordinary Portland Cement) and GGBFS (Ground Granulated Blast Furnace Slag) concrete are evaluated with EOS aggregate replacement. The related experiments were carried out with 0.6 of water to binder ratio, three levels of EOS replacement ratios (0%, 30% and 50%) for fine aggregate, and two levels of cement replacement with GGBFS (0% and 40%). Several tests such as slump air content, and unit mass measurement are performed for fresh concrete, and compressive strength and diffusion coefficient referred to NT BUILD 492 method are measured for hardened concrete. Through the tests, it was evaluated that the compressive strength in concrete with EOS aggregate increased to 3 days and 7 days but slightly decreased at the age of 28 days. In the accelerated chloride penetration test, GGBFS concrete showed reduced diffusion coefficients by 60 - 67% compared with OPC concrete. The lowest chloride diffusion coefficient was evaluated in the 50% replacement with EOS aggregate, which showed an applicability of EOS aggregate to concrete production.

Evaluation of Relationship between Strength and Resistance to Chloride in Concrete Containing Fly Ash with Ages (Fly Ash를 혼입한 콘크리트의 재령에 따른 강도와 염화물 저항능력간의 상관관계 평가)

  • Yoon, Yong-Sik;Park, Jae-Sung;Hwang, Chul-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.53-60
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    • 2017
  • Fly ash(FA) which is a byproduct in the coal combustion in thermal power plant contributes to pore structure densification due to pozzolanic reaction, and this leads to long-term strength development and excellent resistance to chloride penetration. In the work, compressive strength and chloride resistance in OPC(Ordinary Portland Cement) and FA-based concrete are evaluated, and the relationships are investigated considering ages. For the work, 3 different W/B (Water to Binder) ratios of 37%, 42%, and 47% are prepared, and 3 substitution ratio of fly ash(0%, 30%, and 50%) are considered as well. At the age of 28 days and 180 days, test results of compressive strength, diffusion coefficients based on Tang's method, and passed charges referred to ASTM C 1202 and KS F 2711 are obtained. With increasing replacement ratio of FA and decreasing W/B, the resistances to chlorides(diffusion coefficient and passed charge) are improved, and the results at the age of 180 days decrease to only 15% level at the age of 28 days due to pozzolanic reaction in FA 50 mixture, which shows that resistance to chloride is much dependent on age effect than strength development. After 180 days, more clear linear relationships are observed between strength and resistance to chloride.