• 대한기계학회논문집B
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• 제31권4호
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• pp.376-383
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• 2007

This research represents the catalytic converter for application in the motorcycle. We have to consider about catalytic converter for reducing exhaust gas strength regarding the displacement volume enlargement. The catalytic converter has been widely used to satisfy the regulations of pollutant emissions from automobiles. Recently, all catalytic converter researches are about automobile. Study about motorcycle catalytic converter has not been conducted yet. In this study, flow uniformity and pressure distribution were simulated in the monolithic inlet of catalytic converter for motorcycle. Exhaust pulsation pressure was set as transient condition about. It was found that flow uniformity shown in base model (0.85) was lower than megaphone model (0.98).

• 대한기계학회:학술대회논문집
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• 대한기계학회 2005년도 창립60주년 기념 추계 학술대회
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• pp.89.1-89.1
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• 2005

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.945-949
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• 2001

This study is an experimental study on the characteristics of emission by changing catalytic converter position for cold-start. The measurements are done a changing of the distance between exhaust manifold and catalytic converter. It measured temperature of exhaust manifold, before and after catalytic converter at each position of experimental condition. and measured the characteristics of emission which is HC, CO, $CO_{2}$ and lambda at each position of experimental condition. The results show a few advantage about reduction of HC and CO as catalytic converter's temperature is raised quickly as closed exhaust manifold. but $CO_{2}$ has not the same trend of HC and CO. From measurement value of lambda, reduction effects of $NO_{x}$ are known a few advantage as increase of the distance between exhaust manifold and catalytic converter.

• 한국자동차공학회논문집
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• 제14권6호
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• pp.137-142
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• 2006

This research represents the catalytic converter for application in the motorcycle. Present research model type is monolithic catalytic converter and this type have been widely used for satisfaction on and the regulations of pollutant emissions in automobiles. The flow characteristics in a single monolith automotive catalytic converter were investigated by using a computational simulation method without chemical reaction. So we limit the discussion to the effect of flow uniformity in the catalytic converter. Simulation result shows that the flow uniformity of megaphone type catalytic converter is higher than that of a base type. Therefore, the megaphone type is more suitable to motorcycle.

• 한국자동차공학회논문집
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• 제15권5호
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• pp.63-71
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• 2007

The conversion efficiency, durability and pressure drop of the automotive exhaust catalysts are dependent on the flow distribution within the substrate. Conventional porous medium approaches assuming monolith resistance based on the one-dimensional laminar flow for simulating the flow through the automotive exhaust catalysts over-predict the flow uniformity in the monolith. In this study, additional pressure loss is also considered by accounting for entrance effects due to the oblique flow incident on the front face of monolith as a consequence of flow separation and recirculation within the diffuser. The incorporation of an additional pressure loss improves the predictions for the maximum flow velocity within the substrate. An numerical study has also been conducted for the three-dimensional unsteady incompressible non-reacting flow inside various dual-monolith catalytic converters for the rapid acceleration/deceleration driving.

• 한국자동차공학회논문집
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• 제6권4호
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• pp.108-120
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• 1998

A theoretical study of three-dimensional unsteady compressible non-reacting flow inside double flow of monolith catalytic converter system attached to 6-cylinder engine was performed for the achievement of performance improvement, reduction of light-off time, and longer service life by improving the flow distribution of pulsating exhaust gases. The differences between unsteady and steady-state flow were evaluated through the numerical computations. To obtains the boundary conditions to a numerical analysis, one dimensional non-steady gas dynamic calculation was also performed by using the method of characteristics in intake and exhaust system. Studies indicate that unsteady representation is necessary because pulsation of gas velocity may affect gas flow uniformity within the monolith. The simulation results also show that the level of flow maldistribution in the monolith heavily depends on curvature and angles of separation streamline of mixing pipe that homogenizes the exhaust gas from individual cylinders. It is also found that on dual flow converter systems, there is severe interactions of each pulsating exhaust gas flow and the length of mixing pipe and junction geometry influence greatly on the degree of flow distribution.

• 대한기계학회논문집B
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• 제23권7호
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• pp.841-855
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• 1999

In the present work, the effect of a flow maldistribution on the thermal and conversion response of 8 monolith catalytic converter is Investigated. To achieve this goal, a combined chemical reaction and multi-dimensional fluid dynamic mathematical model has been developed. The present results show that flow uniformity within the monolith brick has 8 great impact on light-off performance of the catalytic converter. In the case of lower flow uniformity, large portions of the monolith remain cold due to locally concentrated high velocities and CO, HC are unconverted during warm-up period, which loads to retardation of light-off. It has been also found that the heat-up pattern of the monolith ill similar to the flow distribution profile, In the early stage of the reaction. It may be concluded that flow maldistribution can cause a significant retardation of the light-off and hence can eventually worsen tho conversion efficiency of automotive catalytic converter.

• 한국자동차공학회논문집
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• 제7권7호
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• pp.187-194
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• 1999

In the design of catalytic converter, velocity distribution is more important than pressure drop because monolith pressure drop is about 80% of overall pressure drop. For the catalytic converter with single diffuser, pressure drop is decreased as the angle of diffuser decrease, but when the angle is below 18$^{\circ}$, the effect is almost negligible . For the catalytic converter with double diffuser, variation of the angle of the first diffuser shows the same trend as the pressure drop while the shape of diffuser gives little influence on that The outlet shape gives negligible effect on the pressure drop and velocity . distribution . Results show that recirculation region of commercial model is aoubt 30% of the total area in the front of monolith. For the catalytic converter with Model 11 that was presented in the study, recirculation region was not detected more uniform velocity distribution was obtained, and pressure drop was also decreased.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.77.2-77.2
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• 2010

일산화탄소를 수소로 변환하는 수성가스전환반응(WGSR)은 수소 생산, 연료개질 시스템뿐만 아니라 암모니아 제조, 제철소 제련과정등 일선 산업현장에서 널리 활용되고 있다. 상용공정에서의 WGS반응은 두 단계의 반응기(HTS/LTS)에서 각각 Fe/Cr, Cu/Zn기반 촉매를 사용하여 이루어진다. 하지만 이러한 촉매들은 공기중 자연발화성이 있고 사용전 환원과정이 필요하다. 또한 최근에 많은 연구가 진행되고 있는 귀금속 담지 촉매는 기존 촉매의 단점을 극복하고 활성이 높은 장점이 있다. 이에 본 연구에서 제시한 페로브스카이트 촉매는 상용 촉매, 귀금속 담지촉매 시스템과의 비교를 위하여 제작된 촉매를 사용한 반응시스템과 기존 상용촉매를 사용한 반응시스템을 비교하여 개발 촉매의 성능 수준을 검토하였다. 이러한 결과 페로브스카이트 구조 촉매는 상용촉매의 공정상의 단점과 귀금속 담지촉매의 가격적인 측면에서의 단점을 동시에 극복한 촉매로서 성능 및 메탄화반응 억제 측면에서 우수성을 보유하고 있다는 것을 증명하였다. 이러한 페로브스카이트 구조 촉매의 반응특성을 규명하기 위해 문헌조사해본 결과 기존 수성가스전환반응에서 쓰이는 촉매들의 반응매카니즘은 대표적으로 formate와 redox 반응 두가지가 있었다. 페로스브스카이트 구조 촉매는 그 구조와 귀금속 함량, 활성 등 성능측면에서 귀금속 촉매와 상당히 유사한 측면이 있기 때문에 귀금속 담지 촉매의 반응속도식을 기본으로 하여 실험결과와 일치시켜 페로브스카이트구조 촉매에 맞는 반응속도식을 제시하고 이를 통한 반응파라미터 값을 도출하였다.

• 한국자동차공학회논문집
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• 제9권3호
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• pp.76-83
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• 2001

An experimental investigation has been performed on the steady flow in exhaust system. When individual flow coming from exhaust manifold entered UCC, the inlet conditions at entry to the diffuser in UCC were affected by the upstream pipe and manifold works. But those effects of the inlet condition on flow through monolith are negligible because the flows are concentrated on the center of monolith regardless of inlet flow distribution. To improve the flow distribution, we installed the cone type circular ring in diffuser of UCC. This led to increasement of flow uniformity, but there was minor increment of pressure drop.