• Title/Summary/Keyword: 촉매대

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Experimental Study of Decomposition Characteristics of Catalyst for Hydrazine Monopropellant Thruster (하이드라진 단일 액체추력기용 촉매의 분해거동 특성 연구)

  • Kim, Jung-Hun;Lee, Jae-Won;Kim, In-Tae;Yu, Myoung-Jong;Lee, Kyun-Ho;Kim, Su-Kyum
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.151-154
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    • 2007
  • The purpose of this study is to identify the basic concept of thruster design through the visualization firing test on a hydrazine thruster. We designed the visual catalyst bed on the basis of the 1lbf hydrazine thruster for a low earth orbit satellite and observed visually the internal catalyst bed reaction.

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Optimization of Thruster Catalyst Beds using Catalytic Decomposition Modeling of Hydrogen Peroxide (과산화수소 촉매분해 모델링을 이용한 추력기 촉매대 최적설계)

  • Jung, Sangwoo;Choi, Sukmin;Kwon, Sejin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.746-752
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    • 2017
  • High test hydrogen peroxide has been widely developed as green propellant for thrusters. Hydrogen peroxide is decomposed in the catalyst bed to produce the thrust. Catalyst bed design optimization is considered through existing model for catalyst beds. To verify the model, static firing tests were conducted under various conditions using a 100 N scale $H_2O_2$ monopropellant thruster. Temperature and pressure estimations from the model were well correlated to the experimental data. The model is used to obtain optimal design parameters by analyzing the catalyst capacity and pressure drop data for various simulated conditions. Catalyst beds can be optimized from the analysis of the catalyst capacity and pressure drop correlation through catalyst bed modeling.

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연구실 탐방 - 서울대 분자촉매연구센터

  • Korean Federation of Science and Technology Societies
    • The Science & Technology
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    • v.30 no.3 s.334
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    • pp.86-87
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    • 1997
  • 95년 5월 서울대 내에 설립된 분자촉매연구센터는 인체 내에서 가공할만한 힘을 발휘하는 촉매제인 "효소"와 가장 흡사한 생체와 생체모방촉매 개발을 중점과제로 삼고 있다. 3백여명의 연구진이 포진한 이 연구소는 피혁회사에서 사용되는 모피를 부드럽게 하는 인공촉매제 개발에도 성공한 바 있다.

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Investigation on the Change of Ammonia Dissociation for Satellite Thruster According to the Catalyst Loss (위성추력기에서 촉매유실에 따른 암모니아 해리도 변화에 대한 연구)

  • Hwang, Chang-Hwan;Lee, Sung-Nam;Baek, Seung-Wook;Kim, Su-Kyum;Yu, Myoung-Jong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.218-222
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    • 2011
  • During the development of the iridium catalyst for domestic production, the catalyst failure, loss, sintering phenomena are observed by high pressure and temperature. By these abnormal failure of catalyst bed, the performance of thruster is degraded. To figure out the detail phenomena on the damaged catalyst bed, a numerical analysis code is developed by assuming the catalyst bed as an one dimensional porous media. The numerical analysis code is validated with experiment data. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure. Through these numerical analyses we figure out the effect of the catalyst loss on the decomposition of hydrazine and ammonia.

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Design of Hydrogen Peroxide/Kerosene Ignitor and Ignition Characteristic according to Operation Condition (친환경 추진제를 사용하는 액체로켓엔진 점화기의 설계 및 운용 조건이 점화 특성에 미치는 영향)

  • Hwang, Oh-Sik;Kim, Tae-Woan;Jeon, Jun-Su;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.74-77
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    • 2009
  • Ignition performance tests were performed to develop a catalytic ignitor which used hydrogen peroxide and kerosene. Ignition characteristics were investigated by exit area of the catalytic bed, shape of kerosene injector and lead time of purge gas. The results showed that exit area of catalytic bed must be enough for non chocking condition and kerosene must be sprayed with swirl in the middle of catalytic bed. Also in case without preheating of catalytic bed, hydrogen peroxide must be leaded by 3sec, and purge gas must be supplied simultaneously or lately with kerosene.

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An Approach to the Optimization of Catalyst-bed L/D Configuration in 70 N-class Hydrazine Thruster (70 N급 하이드라진 추력기의 촉매대 형상(L/D) 최적화 연구)

  • Jung, Hun;Kim, Jong Hyun;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.6
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    • pp.30-37
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    • 2013
  • A ground hot-firing test was conducted to take out the optimal design configurations for the catalyst bed of liquid-monopropellant hydrazine thruster which could be used for primary engine or attitude control thruster of space vehicles. Performance characteristics with the variation of thrust-chamber length are investigated in terms of thrust, specific impulse, chamber pressure, characteristic velocity, and hydrazine decomposition rate. Additionally, the correlations between propellant-supply pressure and performance parameters are given. As results, increase of catalyst-bed length leads to performance degradation in this test condition, and also decreases propellant consumption efficiency with the supply pressure variation.

Effects of Catalyst Granule Failure in Monopropellant Satellite Thruster (단일추진제 위성추력기에서 촉매 파손에 의한 영향)

  • Hwang, Chang-Hwan;Lee, Sung-Nam;Baek, Seung-Wook;Kim, Su-Kyum;Yu, Myoung-Jong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.6
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    • pp.7-14
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    • 2011
  • Various sizes of hydrazine monopropellant thruster have been used on satellite and space launcher vehicle. The test and handling procedure of hydrazine monopropellant thruster are usually difficult because of the toxicity of hydrazine and its decomposition product gases. Therefore, the numerical analysis can help understand the effects of various design parameters and can reduce the time as well as expenses. In this study, the numerical analysis is performed by modelling the catalyst bed as one dimensional porous medium. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure.

Preparation of Carbon Nanotubes and Carbon Nanowires from Methane Pyrolysis over Pd/SPK Catalyst (Pd/SPK 촉매상에서 메탄의 열분해 반응으로부터 탄소 나노튜브 및 탄소 나노선의 제조)

  • Seo, Ho Joon;Kwon, Oh Yun
    • Applied Chemistry for Engineering
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    • v.18 no.1
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    • pp.94-97
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    • 2007
  • Carbon nanotubes and nanowires were prepared by methane pyrolysis over Pd(5)/SPK catalyst by changing oxygen molar ratio in a fixed bed flow reactor under atmospheric condition and also analyzed by SEM and TEM. When the $CH_4/O_2$ molar ratio was 1, carbons were not almost deposited on the catalyst bed support, but when it was 2, carbons were deposited as much as plugging reactor. TEM and SEM images for the deposited carbons showed a number of single-walled carbon nanotubes and carbon nanowires. The growth mechanism of carbon nanotubes produced on the catalyst surface was the tip growth mode. It should be played an important role in carbon nanotubes and nanowires produced on the catalyst bed support to formate the carbon growth velocity vectors and nuclei of ring structure of carbon nanowires. SPK carrier was $N_2$ isotherm of IV type with mesopores, and excellent in the thermal stability.

Characteristics of the Pressure Instability in a Hydrazine Thruster with Various Length-to-Diameter Ratio of Catalyst-bed (하이드라진 추력기의 촉매대 길이직경비에 따른 압력 불안정 특성)

  • Jung, Hun;Kim, Jong Hyun;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.6
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    • pp.19-26
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    • 2014
  • A ground hot-firing test (HFT) was carried out to make a close examination into the pressure instability for the 70 N-class hydrazine thruster under development. Monopropellant grade hydrazine was adopted as a propellant for the HFT, and catalyst-bed was filled with $Ir/Al_2O_3$ catalyst. In order to investigate the effects of thrust-chamber diameter on combustion stability, evaluation tests for the development models were performed on three kinds of lower thrust chambers having the length-to-diameter ratio (L/D) of 1.03, 1.13, and 1.26. As results, it was found that low frequency instability (~ 50 Hz) was inherent in the models, and in addition, increase of the L/D and decrease of the operating pressure led to an amplification of pressure oscillation in the test condition specified.

Performance improvement of lunar lander thruster (달 착륙선 지상시험용 추력기 성능개선)

  • Lee, Jong-Lyul;Choi, Ji-Yong;Jun, Hyoung-Yoll;Han, Cho-Young;Kim, Su-Kyum;Won, Su-Hee
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.42-45
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    • 2012
  • As a basic research for the development of Korean lunar lander, propulsion system development for ground test is in progress. Design target is 220 N in ground thrust at 130 g/s flow rate, 200 psi chamber pressure. For the performance improvement, two type injector and catalyst bed was designed. For ground test, thrust measurement system using LM guide was developed and test was performed. The result shows 214.1 N thrust in atmosphere condition at 126.6 g/s flow rate.

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