• Proceedings of the Korean Society for Food Science of Animal Resources Conference
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• 2004.10a
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• pp.227-230
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• 2004

본 연구에서는 신선육 및 원료육의 미생물 저감화 및 안전성 확보를 위해 식육에 초임계 이산화탄소 처리를 실시하였다. 이산화탄소의 초임계점인 78 atm, $38^{\circ}C$에서 10분 처리한 시료에서 병원성 미생물의 저감화가 나타나기 시작했으며, 압력을 100 atm 이상으로 증가시켰을 때 5 log 이상의 억제 효과가 나타나 신선육 및 원료육의 미생물학적 안전성이 검증되었다. 하지만 초임계 이산화탄소의 압력을 증가시킬수록 안정성은 확보되는 반면 시료의 구조${\cdot}$물성 변이가 심화되어 원료육의 가공적성도는 떨어지는 것으로 판단된다. 따라서 신선육 및 원료육의 품질을 고려한 미생물적 안전성을 확보하려면, 이산화탄소의 초임계점수준의 처리가 요구되며, 향후 초임계 이산화탄소 처리에 따른 육질변이 및 가공적성도에 대한 다각적이고 심도 있는 연구가 요구된다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.1 s.256
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• pp.40-50
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• 2007

The present contribution describes the application of elliptic-blending second moment closure to predict the gas cooling process of turbulent super-critical carbon dioxide flow in a square cross-sectioned duct. The gas cooling process under super-critical state experiences a drastic change in thermodynamic and transport properties. Redistributive terms in the Reynolds stress and turbulent heat flux equations are modeled by an elliptic-blending second moment closure in order to represent strongly non-homogeneous effects produced by the presence of walls. The main feature of Durbin's elliptic relaxation second moment closure that accounts for the nonlocal character of pressure-velocity gradient correlation and the near-wall inhomogeneity guaranteed by the elliptic blending second moment closure.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.2
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• pp.158-165
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• 2008

The carbon dioxide properties change sharply near the critical or pseudo-critical point in the heat transfer processes. The reduction in turbulent, convective heat transfer parameters observed in some supercritical data and in experiments with common gases can be due to property variation, acceleration, buoyancy or combinations of these phenomena, depending on the conditions of the applications. In this study, the measurement for the secondary flow driven by buoyancy was carried out on the supercritical carbon dioxide turbulent flows in the different boundary condition with the constant mass flow rate. The available measuring techniques were used to clarify the behaviour of any supercritical fluid. Laser Doppler Velocimeter (LDV) and a special device was used to measure the secondary velocity and turbulent characteristics of the supercritical flows.

• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.189-193
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• 2008

In this study, the effect of reaction conditions on the transesterification of soybean oil and methanol was investigated in a high-pressure-fixed-bed-reactor-system with zinc aluminate catalysts. Without catalysts, high-pressure-reaction at $300^{\circ}C$ and 1,200 psi brought 19% yields of methyl esters, which was caused by the approach of reaction condition to supercritical point of methanol. However, except the specific reaction condition, the yields in the reaction with no catalyst were very low below 4.5%. The zinc aluminate was prepared as catalyst by coprecipitation and characterized with $N_2$ gas adsorption/desorption and X-ray diffraction. With catalyst, the effect of the reaction parameters such as temperature, pressure, and molar ratio of reactants on biodiesel production was demonstrated. The higher temperature, pressure, and methanol molar ratio to soybean oil, the more yields of methyl esters. It was proved that among the reaction parameters, the reaction temperature be the most influential variable on methyl ester yields.