• 플랜트 저널
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• 제4권2호
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• pp.60-65
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• 2008

As the operating conditions in a supercritical oxidation reactor are set in high temperature with high pressure causing a reactor suffering from the harsh circumstances. It means the reactor adopts itself with Fe-Cr alloy in acidic atmosphere with low pH value and Ni alloy in basic atmosphere with high pH value due to its superior corrosion resistance. The study, whose target waster water is pertinent to the latter part, has selected Ni alloy such as ostenite type stainless steel 304 and 316, superstainless steel AL6XN, Inconel 625, MAT 21, and titanium Gr. 5 in order to measure corrosion resistance against those samples under the same conditions of temperature and pressure applied for a supercritical oxidation reactor. The result shows the identifiable difference in corrosion resistance by observing the surface states through a scanning probe microscope as well as measuring the weight loss through making the samples above deposited in wastewater for two-week and four-week stay. The purpose of this corrosion experiment is to identify the most corrosion-resistant material among sample species pre-selected according to pH concentration of wastewater in pursue of applying for a reactor exposed to the extreme corrosion environment. It is because such a reactor made of a verified material enables to safeguard a stable operation under the supercritical wastewater processing facility.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 춘계학술발표대회
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• pp.57.1-57.1
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• 2009

나노이산화티타늄은 인체에는 화장품, 의약, 식품분야 등에 쓰이고 외부 환경 재료에는 광촉매로서 유독가스 정화제, 옥내 외 항균, 수소발생 가시광 응답형 촉매 및 멤브레인 필터 등과 전자소재용 유전재료, 발광 재료 등 용도가 다양하다. 나노 산화티타늄 화합물의 제조법은 수열합성법, 기상법 등 여러 방법이 있다. 이들에 대한 리뷰의 목적은 2009년도 정부의 투자 계획 중에서 본제목에 관련되는 핵심 산업 재원 원천기술 개발, 태양광, 풍력 등의 신재생 에너지 개발, 록색 기술 개발을 통한 에너지절약형 LED 개발, 차세대 핵심환경 기술 개발, 핵심나노기반기술개발 등의 개발을 위하여 4,363억 원의 예산을 편성하고 연구자와 기술자들이 참여하여 유익한 실적이 창출되기를 원하고 있으므로 본 발표자들은 이 분야에서 연구하는 연구자와 기술자들에게 이 분야에 관련되는 자료를 참고로 제시하는데 있다. 페로브스카이트형 산화물인 유전재료($BaTiO_3$), 발광재료(CaTiO3:Pr3+적색), 박막형 반응기재료($Ca0.8Sr0.2TiO_3$), 등의 여러 가지 산화물은 류통식 급속 승온 수열 합성법, 겔 졸 법, 수열 합성법 등 여러 방법에 의하여 페로브스카이트형 산화물 입자 직경이 약 20nm~100nm 범위까지 합성된다. 태양광을 조사하여 물을분해 해서 수소를 생산하는 산화티타늄계 가시광 응답형 Vis-$TiO_2$ 박막은 기상법으로 제조하는데 한 예로써 RF 스퍼터링법으로 박막을 제조하여 수소와 산소를 회수하였으며, 황도프산화티타늄, 질소 도프 산화티타늄은 유기물 분해에 의한 공해제거, $NO_x$ 제거 등 환경정화에 사용되고, 고온 고압수법/산화티타늄 복합기술에 의해서는 바이오매스 분해 하고, 일종의 수열법인 개량형 HyCOM 법은 가시광 응답성 산화티타늄을 합성하여 NO가스 제거에 사용한다. 이들 여러 방법에 관한 것을 소개하고저 한다.

• Journal of Advanced Marine Engineering and Technology
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• 제28권1호
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• pp.65-74
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• 2004

The heat transfer coefficient and pressure drop of $CO_2$(R-744) during gas cooling Process of carbon dioxide in a horizontal tube were investigated experimentally and theoretically. The experiments were conducted without oil in the refrigerant loop. The main components of the refrigerant loop consist of a receiver. a variable-speed pump. a mass flowmeter, an evaporator. and a gas cooler(test section). The main components of the water loop consist of a variable-speed Pump. an constant temperature bath. and a flowmeter. The gas cooler is a counterflow heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus The test section consists of smooth, horizontal stainless steel tube of 9.53 mm outer diameter and 7.75 mm inner diameter. The length of test section is 6 m. The refrigerant mass fluxes were 200 ~ 300 kg/($m^2{\cdot}s$) and the inlet pressure of the gas cooler varied from 7.5 MPa to 8.5 MPa. The main results were summarized as follows : The predicted correlation can evaluated the R-744 exit temperature from the gas cooler within ${\pm}10%$ for most of the experimental data, given only the inlet conditions. The predicted gas cooley capacity using log mean temperature difference showed relatively food agreement with gas cooler capacity within ${\pm}5%$. The pressure drop predicted by Blasius estimated the pressure drop on the $CO_2$ side within ${\pm}4.3%$. The predicted heat transfer coefficients using Gnielinski's correlation evaluated the heat transfer coefficients on the $CO_2$ side well within the range of experimental error. The predicted heat transfer coefficients using Gao and Honda's correlation estimated the heat transfer coefficients on the coolant side well within ${\pm}10\;%$. Therefore. The predicted equation's usefulness is demonstrated by analyzing data obtained in experiments.

• 설비공학논문집
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• 제17권5호
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• pp.410-417
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• 2005

The cooling performance of a transcritical $CO_{2}$ cycle varies significantly with a variation of refrigerant charge amount. In this study, the performance of the $CO_{2}$ system was measured and analyzed by varying refrigerant charge amount at a standard test condition. Besides, the losses of the major components in the $CO_{2}$ system were estimated by evaluating entropy generation with refrigerant charge amount. The losses in the expansion device and the gascooler show the major portion of the total loss. For undercharging conditions, the expansion loss dominates the overall system performance, while the gascooler loss increases significantly with an increase of refrigerant charge amount.

• 한국자동차공학회논문집
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• 제16권3호
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• pp.159-165
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• 2008

This paper deals with the optimum high pressure control algorithm for a transcritical $CO_2$ mobile air-conditioning system with belt-driven compressor to achieve the maximum COP. The experiments were performed to find out the maximum COP conditions with various operating conditions. The experimental results showed that the COP was increased and then decreased with increase of the refrigerant high pressure for the system. Therefore the value of high pressure which has maximum COP could be selected. Furthermore, the strong (linear) relation between the optimum high pressure and the gas cooler outlet temperature was revealed, which suggests the use of a simple controller with only one parameter for the transcritical $CO_2$ cycle.

• 설비공학논문집
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• 제15권9호
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• pp.768-778
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• 2003

Numerical analysis has been carried out to investigate laminar convective heat transfer in a tube for supercritical water near the thermodynamic critical point. Fluid flow and heat transfer are strongly coupled due to large variations of thermodynamic and transport properties such as density, specific heat, viscosity, and thermal conductivity near the critical point. Heat transfer characteristics in the developing region of the tube show transition behavior between liquid-like and gas-like phases with a peak in heat transfer coefficient distribution near the pseudocritical point. The peak of the heat transfer coefficient depends on pressure and wall heat flux rather than inlet temperature and Reynolds number, Results of the modeling provide convective heat transfer characteristics including velocity vectors, temperature, and the properties as well as the heat transfer coefficient. The effect of proximity to the critical point is considered and a heat transfer correlation is suggested for the peak of Nusselt number in the tube.

• Korean Chemical Engineering Research
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• 제44권6호
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• pp.659-668
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• 2006

실험계획법을 이용하여 nitromethane을 초임계수산화(SCWO)로 분해시키는 공정의 최적화 연구를 진행하였다. Lab scale 반응설비를 이용하여 처리수의 COD와 T-N을 최소화하는 SCWO 공정의 최적 운전조건을 도출하였으며, scale-up 문제점을 파악하기 위해 SCWO pilot plant 실험 결과와 lab scale 최적화 실험 결과를 비교하였다. 처리수의 COD와 T-N을 최적화 목적 변수(KPOV)로 설정하였으며, 예비실험을 통해 반응 온도(temp)와 nitromethane과 암모니아수의 몰 비(NAR)를 주요 운전 변수(KPIV)로 설정하였다. 최적화 실험은 통계적 실험계획법인 중심합성설계법을 사용하였으며, 실험결과의 해석은 반응표면법을 활용하였다. 주 효과 분석결과 처리수의 COD는 Temp 증가에 따라 급격하게 감소하며, NAR 증가에 따라 약간 감소하는 것으로 나타났으며, T-N은 Temp 와 NAR 증가에 따라 감소하였다. Temp가 $420{\sim}430^{\circ}C$로 낮을 때에는 NAR 증가에 따라 T-N이 급격히 감소하였으나, $450^{\circ}C$ 이상으로 높을 때에는 큰 변화가 없었다. 최적화 실험 결과를 회귀분석 하여 처리수의 COD와 T-N 을 예측할 수 있도록 Temp와 NAR이 변수인 2차식으로 회귀식을 도출하였으며, 결정계수($r^2$)와 표준화잔차의 정규성을 분석하여 회귀식이 실험결과를 잘 모사하는 것을 확인하였다. 회귀식을 이용하여 COD < 2 mg/L, T-N<40 mg/L를 동시에 만족시키며 부식 위험이 적은 nitromethane 분해 최적 운전 조건은 Temp $450-460^{\circ}C$, NAR 1.03-1.08로 설정하였다. SCWO pilot plant를 이용하여 nitromethane 분해 최적 조건을 검증하고, SCWO 공정의 scale-up 문제점을 파악하는 연구를 실시하였다. SCWO pilot plant 실험 결과를 lab scale 반응설비에서 도출한 COD와 T-N의 회귀식과 비교한 결과 오차가 증가하지만 회귀식이 pilot plant 실험결과도 잘 나타내는 것을 확인할 수 있었다. Pilot plant 실험결과에 대한 회귀식의 적합성은 실험값과 예측값의 비교도와 표준화잔차의 정규성으로 검증하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제29권5호
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• pp.526-532
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• 2005

The cooling heat transfer coefficient of $CO_2$(R-744) in a horizontal tube was investigated experimentally. The experiments were conducted without oil in a closed refrigerant loop which was driven by a magnetic gear pump. The main components of the refrigerant loop are a receiver, a variable-speed pump. a mass flow meter. a pre-heater and gas cooler(test section). The test section consists of a smooth, horizontal stainless steel tube of 7.75 mm inner diameter. The experiments were conducted at mass flux of 200 to $400\;kg/m^{2}s$ and the inlet cooling pressure of 7.5 MPa to 10.0 MPa. The variation of heat transfer coefficient tends to decrease as cooling pressure of $CO_2$ increases. The heat transfer coefficient with respect to mass flux increases as mass flux increases. The pressure drop of $CO_2$ in the gas cooler shows a relatively good agreement with that predicted by Blasius's correlation. The local heat transfer coefficient of $CO_2$ agrees well with the correlation by Bringer-Smith.

• 한국유체기계학회 논문집
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• 제10권2호
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• pp.16-21
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• 2007

Potential advantages of using vapor injection in a two stage rotary compressor for a $CO_2$ heat pump water heater system were addressed in this paper by numerical simulation. Vapor separated from a flash tank in the middle of the expansion process can be used for injection into the second stage suction plenum of the compressor to improve the system performance. Vapor injection increases the intermediate pressure between the two stages, thus increasing the first stage compressor work and reducing that of the second stage. As a whole, however, the compressor input power increases due to injected mass flow rate for the second stage. Computer simulation showed that increment of the cooling capacity by vapor injection exceeded that of the compressor work, thus improving the system performance. COP improvement by vapor injection was calculated to be about 5-14% for normal operating conditions. With vapor injection, a maximum COP was found when the displacement volume of the second stage becomes 90-95% of that of the first stage of the compressor.

• 한국자동차공학회논문집
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• 제16권2호
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• pp.150-157
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• 2008

The main objective of this paper is to investigate the performance characteristics of a $CO_2$ air conditioning system for fuel cell electric vehicles (FCEV). The present air conditioning system for FCEV uses the electrically driven compressor and electrically controlled expansion valve for $CO_2$ as a working fluid. The experimental work has been done with various operating conditions, which are quite matching the actual vehicle's driving conditions such as different compressor speed and high pressure to identify the characteristics of the system. Experimental results show that the cooling capacity and coefficient of performance (COP) were up to 6.3kW and 2.5, respectively. This paper also deals with the development of optimum high pressure control algorithm for the transcritical $CO_2$ cycle to achieve the maximum COP.