• Polymer(Korea)
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• v.25 no.6
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• pp.803-810
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• 2001

A nonlinear optical hyperbranched polyester (PE-Azo/Hyper) was synthesized from 4-[N,N-bis(hydroxyethyl)amino-4'-formyl] azobenzene and cyanoacetic acid by a Knoevenagel polycondensation using 4-(dimethylamino) pyridine as a base. The resulting polymer was soluble in polar aprotic solvents such as N,N-dimethylformamide and 1-methyl-2-pyrrolidinone and could be processed into optical quality films by spin coating. The molecular weight was determined to be $M_w$=61,800 ($M_W/M_n{=1.86}$) by gel permeation chromatography using polystyrene as a standard. No melting point was detected by differential scanning Calorimeter, indicating that this polymer presents an amorphous state. It shows a glass transition temperature of $121^{\circ}C$. The second-order nonlinear optical coefficient $d_{33}$ of the poled polymer determined by the second harmonic generation at 1064 nm was 25.4 pm/V.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2015.05a
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• pp.622-624
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• 2015

Tumor hypoxia caused by the unique characteristics of solid tumor sites such as lowered vascular density, irregular vasculature, longitudinal oxygen gradient, and unbalanced oxygen consumption has decreased therapeutic efficacy in several clinical trials such as radiation, chemotherapy, and surgery. Hence, tumor oxygenation studies at microvascular levels are important to provide better understanding of the complexity of microvasculature oxygen transport and exchange with tissue. However, polarographic microelectodes, was employed to measure $pO_2$ at the microvasculature level, but it is difficult to perform and does not provide significant spatial and temporal information of oxygen delivery. In this research, we introduce the hyperspectral imaging system able to provide a wide range of vascular characteristics by spatial maps on hemoglobin saturation information for better understanding of the relationship between blood oxygen delivery, hypervascularity, aberrant angiogenesis at microvasculature levels during tumor growth.

• Journal of the Korea Society of Computer and Information
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• v.20 no.4
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• pp.69-76
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• 2015

We present microscopy based hyperspectral imaging system that successively shows high spatial (micrometer) and temporal resolutions (milisecond), and acquired pseudocolor hemoglobin saturation map a result of various image processing techniques can provide additional information such as oxygen transport, abnormal vascularity and therapeutic effects besides structural and physiological measurements in various diseases. To increase understanding of vascular defects several optical methods of imaging for preclinical/clinical assessment have been developed so far. However, they have some limitations for outcoming resolution and user satisfaction level compared to its cost. A hyperspectral imaging system has shown a wide range of vascular characteristics associated with hypervascularity, aberrant angiogenesis or abnormal vascular remodeling in many diseases. This vascular characteristic is considered as a key component to diagnose and detect a type of disease as evidenced by them.

• Korean Journal of Remote Sensing
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• v.32 no.5
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• pp.403-412
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• 2016

Compact Reconnaissance Imaging Spectrometer for Mars(CRISM) is 489-band hyperspectral camera of Mars Reconnaissance Orbiter(MRO) that provided data used on many mineral researches over Martian surface. For the detection of minerals in planet, mineral index using a few spectral bands have been used. In this study, we applied Matched Filter and Adaptive Cosine Estimator(ACE) target detection algorithm on CRISM data over Gusev Crater: landing site of Spirit(Mars Exploration Rover A) to investigate its mineral distribution. As a result, olivine, pyroxene, magnetite, etc. is detected at Gusev Crater's Columbia Hills. These results are corresponding to the Spirit rover's field survey result. It is expected that hyperspectral target detection algorithms can be used as effective and easy to use method for the detection and mapping of surface minerals in planet.

• The Korean Journal of Applied Statistics
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• v.29 no.5
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• pp.859-872
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• 2016

Land cover classification is an important tool for preventing natural disasters, collecting environmental information, and monitoring natural resources. Hyperspectral imaging is widely used for this task thanks to sufficient spectral information. However, the curse of dimensionality, spatiotemporal variability, and lack of labeled data make it difficult to classify the land cover correctly. We propose a novel classification framework for land cover classification of hyperspectral data based on convolutional neural networks. The proposed framework naturally incorporates full spectral features with the information from neighboring pixels and has advantages over existing methods that require additional feature extraction or pre-processing steps. Empirical evaluation results show that the proposed framework provides good generalization power with classification accuracies better than (or comparable to) the most advanced existing classifiers.

• Journal of the Korean Chemical Society
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• v.51 no.6
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• pp.526-535
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• 2007

Ru(II)-terpyridine complexes (8, 9, 11) linked with adamantyl or β-cyclodextrin moieties were synthesized and characterized based on their 1H and 13C NMR spectra as well as MS spectra. Ru(II)-terpyridine complexes (8, 11) linked with adamantyl moiety were readily dissolved in aqueous solution via encapsulation by β-cyclodextrin when they were mixed with an equimolar amount of β-cyclodextrin. In the similar way, the adamantane guest of the Ru(II)-terpyridine complexes (8, 11) were encapsulated by β-cyclodextrin moiety of the ruthenium complex 9 to afford supramolecular assemblies in aqueous environment. Formation of assemblies was corroborated by 1H NMR spectroscopy.

• Journal of the Korean Chemical Society
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• v.55 no.2
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• pp.199-203
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• 2011

The title one-dimensional hydrogen-bonded coordination compound $[Cu^{II}(C_{13}H_{17}N_3OBr)(C_8H_5O_4)]{\cdot}2H_2O.CH_3OH$ has been synthesized and characterized by single crystal X-ray diffraction study. The monomeric unit contains a square-planar $Cu^{II}$ centre. The four coordination sites are occupied by a tridentate anionic Schiff base ligand (4-bromo-2-[(2-piperazin-1-yl-ethylimino)-methyl]-phenol) which furnishes an $N_2O$-donor set, with the fourth position being occupied by the oxygen atom of an adjacent terephthalate unit. Two adjacent neutral molecules are linked through intermolecular N-H---O and O-H---N hydrogen bonds and generate a dimeric pair. Each dimeric pair is connected with each other via discrete water and methanol molecules by hydrogen bonding to form a one-dimensional supramolecular network.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.36 no.4
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• pp.205-211
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• 2018

Remote estimation of water quality via radiometric instruments provides a convenient means for monitoring environmental changes in water bodies in wide areas. Combined with platforms such as satellite, manned/unmanned vehicles, it reduces the measurement cost and time for acquiring water quality information on the interested target areas. To develop accurate retrieval algorithms, however, acquisition of in-situ measurements from various optical environment is critical. In this study, hyperspectral radiometric measurements, the coincident water quality variables, and its optical properties were obtained to analyze the optical environment of the study area. Field data collected around the Tongyeong area showed that the area has optically complex environment, with occasional outbreak of red tide in summer seasons. Effect of water constituents on the optical variables (remote sensing reflectance and absorption coefficients) were qualitatively analyzed.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.76-76
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• 2019

최근 기후변화로 인해 퇴적 및 세굴이 심화되었고, 4대강 사업으로 인해 급격한 하천 지형 변화가 발생하였다. 특히, 4대강 사업 이후 하상변동 모니터링에 대한 지속적인 수요가 증가하고 있다. 이에 따라 개정된 하천법에 따르면 하상변동조사를 기본 10년 주기로 정기적으로 실시하되, 퇴적 및 세굴 발생 구간에 대해서는 기본 2년을 기준으로 하상변동이 큰 곳에 대해서는 1년 주기로, 하상변동이 작은 곳에 대해서는 5년 주기로 실시해야 한다. 하지만 기술 및 예산의 한계로 인해 하상변동조사의 경우 현장 유사량 및 하상토 입도 측정과 유량-총유사량 관계식을 활용하여 모델링을 통해 하상변동을 예측하고 있는 실정이다. 하상변동은 기본적으로 하천 수심을 기본으로 하고 있으며, 사람이 직접 투입하여 임의의 지점에 대한 수심 계측을 실시하고 있다. 하지만 직접 수심 계측의 경우 낮은 자료의 밀도로 인해 많은 인력과 예산, 시간이 소요되며 무엇보다도 관측 대상인 물이라는 작업환경에서는 인명피해가 발생할 수 있는 문제점을 가지고 있다. 최근에는 이러한 한계를 극복하기 위해 초음파 센서가 탑재된 이동식 보트를 활용하여 경로형 수심 계측을 실시하고 있으나, 초음파 센서가 가지는 기기적 한계로 인해 약 50cm 이하에 대한 수심은 측정이 어려운 실정이다. 특히, 국내 하천의 경우는 홍수기를 제외하면 수심이 얕기 때문에 얕은 수심에 대한 자료 확보가 어려워 공간적 정밀도 확보가 어려운 실정이다. 따라서 기존의 하천계측의 패러다임을 지점, 선형 계측이 아닌 면 측량을 실시를 통해 높은 밀도의 자료를 확보해야 한다. 이러한 측량이 가능한 기술로 하천원격탐사가 대안으로 제시되고 있다. 하천원격탐사는 직접 접촉하지 않고, 대상체의 광학적 특성을 통해 물리적 특성을 파악하는 기술로서 적은 시간에 높은 밀도의 자료의 확보와 저예산의 고효율 방법으로 알려져 있다. 본 연구에서는 기존의 하천원격탐사에서 활용한 고비용, 저해상도의 시공간 스케일에 해당하는 위성 및 유인항공기가 아닌 하천의 흐름방향으로 비행이 가능하고 상대적으로 저비용, 고해상도의 시공간 스케일의 측정이 가능한 드론을 활용하여 하천원격탐사를 수행하는 방법에 대해 논하고자 한다. 특히, 기술적 한계가 존재하는 청색, 녹색, 적색에 해당하는 RGB 영상을 활용한 하천원격탐사를 극복하기 위한 대안으로 초분광 영상을 수집하고 활용하는 방법을 제시하고자 한다.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.21 no.5
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• pp.141-147
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• 2021

In this paper, in order to improve the utilization of hyperspectral large-capacity data feature information by reducing complex computations by dimension reduction of neural network inputs in embedded systems, the band selection algorithm is applied in each subset. Among feature extraction and feature selection techniques, the feature selection aim to improve the optimal number of bands suitable for datasets, regardless of wavelength range, and the time and performance, more than others algorithms. Through this experiment, although the time required was reduced by 1/3 to 1/9 times compared to the others band selection technique, meaningful results were improved by more than 4% in terms of performance through the K-neighbor classifier. Although it is difficult to utilize real-time hyperspectral data analysis now, it has confirmed the possibility of improvement.