• Title/Summary/Keyword: 체가름

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Preparation of Low Density Ceramic Supporter from Fly Ash with Borax and Glass Powder (붕사 및 유리분말을 첨가한 석탄회로부터 저밀도 세라믹 담체의 제조)

  • Hwang, Yeon;Lee, Hyo-Sook;Lee, Woo-Chul;Bae, Kwang-Hyun;Jeong, Yong-Dae;Lee, Won-Kwon
    • Resources Recycling
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    • v.9 no.2
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    • pp.40-45
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    • 2000
  • Low density ceramic supporter was prepared by using fly ash as a starting mterial with borax or glass powders. Also the wheat powders were used by 30 wt% to increase the initial porosity of the supporter. The density of the supporter decreased as the amount of borax increased. The bulk density of $0.79g/\textrm{cm}^3$ and the apparent density of $1.10g/\textrm{cm}^3$ were obtained when the fly ash with 15% of borax was sintered at $1160^{\circ}C$ for 15 minutes. The density also decreased as the plate glass powders past through $212\mu\textrm{m}$ size were mixed. When the fly ash with 12% of glass powder was sintered at $1280^{\circ}C$ for 10 minutes, the bulk and apparent density were $0.90g/\textrm{cm}^3$ and $1.00g/\textrm{cm}^3$, respectively.

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Effect of Attrition Scrubbing on the Recovery of Platinum Group Metals from Spent Automobile Catalytic Converters (자동차(自動車) 폐촉매(廢觸媒)로부터 백금족(白金族) 회수(回收)를 위한 어트리션 스크러빙의 효과(效果))

  • Kim, Wan-Tae;Kim, Hyung-Seok;Cho, Sung-Baek;Lee, Jae-Chun;Kim, Sang-Bae
    • Resources Recycling
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    • v.17 no.5
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    • pp.28-36
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    • 2008
  • The effect of attrition scrubbing on the recovery of platinum group metals (PGMs) from automobile catalytic converters has been investigated. Catalytic converters were first crushed into particles less than 2 mm and attrition scrubbed in the range of 60 min, and then they were sieved with several screens. The catalyst layer, $\gamma$-alumina, was dislodged from the surface of the supporting matrix into fine particles less than $45{\mu}m$ by attrition scrubbing. The fraction of fine particles less than $45{\mu}m$ increased as the residence time for attrition scrubbing increased. The composition of the fine fraction obtained at a residence time of 40 min was $CeO_2$ 19.3%, $ZrO_2$ 1.9% and PGMs 419 ppm. In the fine fraction, the recovery of y-alumina increased proportionally to the residence time. Simultaneously, the recovery rates of $CeO_2$, $ZrO_2$ and PGMs increased to 82.9%, 78.7% and 78.9%, respectively. The production of the fine fraction less than $45{\mu}m$ and the recovery of $\gamma$-alumina increased when the solid concentration and initial feed size increased. Therefore, the attrition scrubbing as the comminution and separation process was concerned to be effective for the recovery of catalyst layer from ceramic supporting matrix by physical impact and shearing action between particles in the scrubbing vessel.

Study on Recycling of Incombustion Materials from MSWI Fluidized Bed Incinerator Ash (생활쓰레기 유동상(流動床) 소각로(燒却爐) 불연물(不燃物)의 재활용에 관한 연구(硏究))

  • Choi, Woo-Zin;Park, Eun-Kyu;Kang, Seung-Kyun
    • Resources Recycling
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    • v.17 no.4
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    • pp.3-9
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    • 2008
  • The total amount of fluidized bed incinerator ash, i.e. incombustion materials generated from the municipal solid waste incineration(MSWI) in Korea was approximately 14,000 tons in 2006. Most of the ash after ferrous metal separation is finally discard to the landfill sites. In the present work, possibility for recycling of the ash is studied to utilize the ash as raw materials for ceramic products. Incombustion materials obtained from the two different incinerators were used to recover the raw materials by applying the magnetic separation and screening process to remove metallic particles. The raw materials show relatively low heavy metals content obtained from the KSLP leaching tests. The ceramic products were prepared by mixing the clay with the various amounts of the raw material. The physical properties, i.e. shrinkage rate, absorbancy and compressive strength of the ceramic products sintered at $1,000^{\circ}C$ and $1,050^{\circ}C$, respectively were improved by increasing the addition amounts of the incinerator ash. Based on the leaching tests the ceramic products also be satisfied with the standard limits on the leachability of heavy metals because most of the metallic materials are effectively removed from the incombustion materials by appling the separation processes.

Fine Aggregates Size Effect on Rheological Behavior of Mortar (잔골재 입자 크기에 따른 모르타르의 레올로지 거동 특성)

  • Lee, Jin Hyun;Kim, Jae Hong;Kim, Myeong Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.8
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    • pp.5636-5645
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    • 2015
  • Physical characteristics of aggregates affect the workability and strength of mortar and concrete, which include their fineness ratio, particle size distribution and water absorption. The workability of construction materials decreases if the incorporated fine aggregates show improper size distribution of their particles. This study shows the particle size effect on the rheological behavior of mortar and provides basic information for evaluating its workability. A mini-slump flow test was adopted to evaluate the workability of mortar. In addition, its plastic viscosity and yield stress were measured using a rheometer for building materials. The sand samples were prepared by sieving river sand and sorting out with their particle sizes. As a result, it was observed that the fines less than 0.7 mm increases the yield stress and plastic viscosity of the mortar samples. If the fines are less than 0.34 mm, the water absorption of the fines dominates change on the workability.

Gradation Curve of Coarse Aggregate by Digital Image Analysis (디지털 이미지 처리 기법을 이용한 굵은골재의 입도분포곡선)

  • Lee, Kwan-Ho;Kim, Young-Jin;Hwang, Tak-Jin;Cho, Jae-Yoon
    • Land and Housing Review
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    • v.2 no.1
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    • pp.69-78
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    • 2011
  • The purpose of this research is particle shape evaluation of aggregate using Digital Image Process(DIP). DIP is very useful to measure the roughness and particle shape of aggregates. Couple of aggregates, like standard sand, two different crushed stones, and two different marine aggregates, have been employed. Shape factors of two different marine aggregates are ranged 0.35 to 0.54. Crushed stone I is 0.74 which is highly flat, but standard sand is elongated shape. Especially, two marine aggregate showed a big difference of width and length which meaned a long shape. There is any significant difference of elongation ratio and flatness for each aggregate with different measuring system, like direct measurement of vernier calipers and DIP method. Shape conversion coefficient and equivalent diameter for changing 2D image to 3D image by the Digital Image Process(DIP) have been suggested and modified particle size distribution curve has been showed. The measured flatness ratios of each aggregate were 0.30, 0.36, 0.47 and 0.83, respectively. Also, the conversion shape coefficients of each aggregate were determinded as 0.77, 0.78, 0.84 and 0.92. The size of aggregate has been modified by multiplying the shape conversion coefficient and the aggregate size from DIP. The modified gradation curve with modified volume and weight of aggregate has been suggested. Within the limited test results, DIP is one of useful to get the particle shape of aggregate with limitation of measuring errors and to apply the particle distribution curve.

Characterization of artificial aggregates of coal bottom ash-red clay system (석탄바닥재-적점토계 인공골재의 특성평가)

  • Kim, Kangduk;Kang, Seunggu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.6
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    • pp.305-311
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    • 2012
  • In order to recycle the coal bottom ashes (denoted as BA) produced from a thermal power plant, the artificial aggregates (denoted as AAs) containing BA and red clay were manufactured, and the physical properties of AAs were studied as a function of particle size of BA and batch compositions. As-received BA had 38 wt% coarse particles of above 2 mm and many unburned carbon mass and porous slag particles were co-existed. So the two particle sizes of BA, the fine (< 100 ${\mu}m$) and coarse (< 2 mm), were prepared by milling and screening process. The AAs containing fine BA sintered at $1100{\sim}1200^{\circ}C$ had the higher bulk density and lower water absorption compared to the specimen made of coarse BA. The inside core of AAs manufactured by using coarse BA showed nonuniform and porous microstructure, while the AAs made of fine BA had a uniform and dense microstructure. In this research, the AAs containing BA and red clay with various bulk density (1.2~1.7) and water absorption (13~21 %) could be manufactured by controlling the particle size of BA and batch compositions, so the AAs of various physical properties could be applied to the wide fields such as construction/building materials in near future.

A Study on the Beneficiation of Illite by Selective Grinding and Air Classification (선택분쇄 및 공기분급에 의한 일라이트의 정제기술 연구)

  • Kim Sang-Bae;Cho Sung-Baek;Kim Wan-Tae;Yoon Sung-Dae
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.1
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    • pp.19-31
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    • 2005
  • A study on the beneficiation of illite occurring in Youngdong province is performed with applying selective grinding and air classification techniques. Quartz and illite are occurred as major components, and sulfide minerals such as pyrite, chalcopyrite are associated as minor components. The result of sieving test shows that contents of Al₂O₃, K₂O and ignition loss are increased, whereas SiO₂ is decreased with particle size decrease. Fe₂O₃ content is almost same in all the particle size range but slightly lower at coarse particles. The yield of fine particles is increased with increasing rotor speed in both grinding stage and air classification stage. When the selective grinding and air classification are carried out at optimal condition, yield of the concentrate is 76.16 wt.%. The chemical compositions of the concentrate are SiO₂70.13%, Al₂O₃ 19.40%, Fe₂O₃ 1.62%, K₂O 5.20%, and ignition loss 2.77%. The beneficiation process developed in the current study is very effective method which purification and particle size control can be achieved simultaneously.

Beneficiation of Low Grade Sericite Using Attrition Scrubbing and Sedimentation (해쇄 및 침강분리에 의한 저품위 견운모의 품위향상 특성)

  • Chae, Sungki;Kim, Hyunsoo;Kim, Sangbae;Kim, Wantae
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.4
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    • pp.137-147
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    • 2017
  • Sericite is a clay mineral that has a wide applications in the industry, depending on its purity. To maintain sericite's purity as high as possible it is necessary to remove its gangue minerals or control their contents prior to use for high value-added products and applications. In this study, the wet beneficiation of sericite by applying selective grinding and sedimentation techniques, were investigated. The ore mineral was composed mainly of sericite, quartz and calcite. Analysis showed that the content of sericite increased along with the particle size decrease, but the contents of impurity minerals as quartz and calcite were tended to decrease relatively with particle size decrease. The results of liberation tests using an attrition scrubber showed that the increase in residence time and slurry density have increased the generation of fine particles in -325 mesh size range. It was observed, however, that the contents of impurities such as quartz and calcite in such fine particles also increased during prolonged scrubbing. In the dispersed form without breaking, the yield of the recovered concentrate was 15.4 wt% and the $K_2O$ content was 9.84 wt%, after the dispersed slurry was allowed to settle for 20 minutes. On the other hand, the concentrate yield was increased to 23.4 wt% after 10 minute attrition scrubbing and 40 minute sedimentation, while its $K_2O$ content was decreased to 9.71 wt%. Most of final products were observed as platelet-shaped particles containing Si, Al and K which are main component of sericite.

A Study on the Development Lightweight Aggregate using Clink Ash for Reduction in Freezing Ground (지반의 동결저감 대책기술을 수립하기 위한 클링커애쉬 인공경량골재 개발에 관한 연구)

  • Moon, Jong-Wook
    • Fire Science and Engineering
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    • v.23 no.6
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    • pp.116-125
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    • 2009
  • This study is progressed function ratio, it's trued taste by an experiment to present data for human work light weight aggregate development that use clink ash progressed liquid limit, small success limit, wear loss in quantity, sand equivalent, sieve cutting examination. 80 : 20's match of function rain examination is 1.4, and that use rubble Goljae as ckink ash lightweight aggregate's capacity ratio increases by 1.0 increase of function rain many. Also, examination multiplied delicate flavor gradually according to increase of the mixing rate, and absorption coefficient increased. This is judged by phenomenon that appear by special quality upper clink ash of polystyrene bid and porosity's increase between lightweight aggregate. It is case that use aggregate of wear loss in quantity is 13.5 in sand equivalent and a wear loss in quantity experiment and although case that mix 20% increases by 14.4, this phenomenon by weak tissue of lightweight aggergate be judge. When it's as a these experiment, the statue prevention floor of a street improvement specifications is prescribing so that satisfy by sand equivalent 20, CBR 10. This is showed result that this satisfies in quality standard all in match experiment ago that see.

Enhanced Thermoelectric Properties in n-Type Bi2Te3 using Control of Grain Size (Grain 크기 조절을 통한 n-Type Bi2Te3 열전 소재 특성 향상)

  • Lee, Nayoung;Ye, Sungwook;Jamil Ur, Rahman;Tak, Jang-Yeul;Cho, Jung Young;Seo, Won Seon;Shin, Weon Ho;Nam, Woo Hyun;Roh, Jong Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.4
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    • pp.91-96
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    • 2021
  • The enhancement of thermoelectric figure of merit was achieved by the simple processes of sieving and high energy ball milling, respectively, which are enable to reduce the grain size of n-type Bi2Te3 thermoelectric materials. By optimizing the grain size, the electrical conductivities and thermal conductivities were controlled. In this study, spark plasma sintering was employed for hindering the grain growth during the sintering process. The thermoelectric figure of merit was measured to be 0.78 in the samples with 30 min high energy ball milling process. Notably, this value was 40 % higher than that of pristine Bi2Te3 sample. This result shows the properties of thermoelectric materials can be readily controlled by optimization of grain size via simple ball milling process.