• Title/Summary/Keyword: 철 광화작용

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Petrochemical Study of the Gadaeri Granite in Ulsan Area, Kyeongsang Province (경상남도 울산지역 가대리화강암에 대한 암석화학적 연구)

  • Choi, Seon-Gyu;Wee, Soo-Meen
    • Economic and Environmental Geology
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    • v.27 no.5
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    • pp.459-467
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    • 1994
  • The Gadaeri granite near Ulsan mine is an oval-shape isolated granitic body, and is genetically related to the iron-tungsten mineralization. The Gadaeri granite exhibits calc-alkaline and I-type characteristics, and generally shows the micrographic texture which indicates the shallow depth of emplacement. Consideration of the stratigraphic thickness of Ulsan formation and minimum-melt compositions suggests that the bulk magma crystallized at pressure of 0.5~2.0 kbar under water saturated condition. The evolutionary trend observed in the studied rocks represents that feldspar fractional crystallization has been a major magmatic process at the Gadaeri granite pluton. Different chemical characteristics between the Gadaeri and the Masan-Kimhae granites cannot be explained by fractional crystallization or different degrees of partial melting, and it reflects that the magma source for Gadaeri granite was different from that of the Masan and Kimhae granites.

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A Comparative Analysis between 3D Geological Modeling and Magnetic Data of Fe-Mn Ore in Ugii Nuur, Mongolia (몽골 우기누르 철-망간 부존 지역의 3차원 지질모델과 자력탐사 결과의 비교분석)

  • Lee, Jeong-a;Yu, Jaehyung;Park, Gyesoon;Lee, Bum han;Kim, In-Joon;Heo, Chul-Ho
    • Economic and Environmental Geology
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    • v.48 no.4
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    • pp.313-324
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    • 2015
  • This study constructed a 3D geological model for Uggi Nuur Fe-Mn mineralization zone in Mongolia, and the 3D geological distribution is cross-analyzed with magnetic anomaly distribution to figure out relationship between ore zone and subsurface geology. As a result of 4 step 3D modeling procedures including geological cross section, surface modeling, foliation modeling and solid modeling, the geology of the both study area is bordered by faults in NW direction with Munguntessj formation being located in the west side of the fault while Yashill formation is located on the other side of the fault. Moreover, the strike direction of foliation in the both formation shows same directional pattern with the NW faults. The magnetic anomaly distribution reveals that higher anomaly values are concentrated to near the ground surface. The analyses of 3 dimensional distribution between subsurface geology and magnetic anomaly indicates that higher anomaly is mainly distributed over the Munguntessj formation as a elongated lens bodies whereas the magnetic anomaly is evenly found in the both of Munguntessj formation and Yashill formation in the study area 2. It infers that volcanic activities associated mineralization occurred during silurian period, and the mineralized zone is thought to be realigned along the geological structures caused by later stage tectonic activities.

Occurrence and Mineral Characteristics of Au-Ag-Cu-Bi Bearing Quartz Veins in the Estancia de la Virgen area, Guatemala (과테말라 Estancia de la Virgen 지역 금-은-동-비스무스 광화대의 산상과 광물특성)

  • Shin, Eui-Cheol;Kim, Soo-Young;Hong, Sei-Sun;Kim, In-Joon
    • Economic and Environmental Geology
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    • v.31 no.6
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    • pp.463-472
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    • 1998
  • The survey was carried out in order to delineate the occurrence of ore deposits and the mineralized characteristics in the Estancia de la Virgen area through the 1:2,000 scaled geological mapping and topographic measuring surveys. Gold-silver mineralization is in the fault block developed between the San Agustin Fault and Cabanas Fault. It is associated with ore bearing quartz veins controlled by the fault structure. The contents of Au and Ag range from traces up to 72 g/t and 180 g/t respectively. According to traversing the outcrops, the quartz veins are traced by 0.5 Km trended to north and south. In those extended part, they continue for 1,000 m intermittently. Gold-silver mineralization could be divided into three stages. In the first stage, pyrite, galena, sphalerite, and chalcopyrite were formed with the primary silver and gold associated with galena and copper sulfides respectively. In the second stage, Cu-Bi-Au-Ag bearing sulfides such as chalcocite, covellite, and linarite are formed and usually deposited on the cataclastic fractures of galena and/or chalcopyrite. In the third stage, both the carbonation of galena and sphalerite and the sulphatization of galena, took place in the surface environment. And then primary silver was carried away off and was deposited on galena and/or copper sulfides during oxidation near the water table. Low partitionings of Fe in sphalerite assist that the minerals were formed at the relatively low temperature, which is coincided with previously reported homogenization temperature of fluid inclusions.

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Geology and Mineralization of the Iscaycruz Pb-Zn-Cu Project, Central Peru (페루 중부 이스카이크루즈 연-아연-동 프로젝트의 지질 및 광화작용)

  • Heo, Chul-Ho;Nam, Hyeong-Tae
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.1
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    • pp.57-67
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    • 2021
  • The geology of the Iskaycruz project are mainly composed of sedimentary rocks within Cretaceous basin. The basal part is composed up of dark-gray shale, gray sandstone, and clastic rock of Oyon formation interbedded with coal measures. In the folded zone in the eastern part of the survey area, there is Chimu formation that has medium-grained massive and white quarztite. In terms of geological structure, the Iskaykruz region is located in the folded and overthrust zones of the central part of the Occidental Mountains. Ore body was formed by hydrothermal replacement process and consists of zinc, lead, silver, and copper. Stratabound-type deposits are hosted in limestone of Santa formation. It extends 12 kilometers discontinuously from northern Canaypata to southern Antapampa. Irregular iron oxide and sulfide minerals hosted in Santa and Parihuanca formations are observed. The mineralization observed on the surface consist of primary sulfides consisting of sphalerite with galena and chalcopyrite, and iron and manganese oxide produced from oxidation of primary sulfides. Skarn minerals are accompanied by tremolite, garnet, epidote and quartz.

Mineralogical and Fluid Inclusion Study on Seafloor Hydrothermal Vents at TA25 Subsea Caldera in Tongan Waters (통가 TA25 해저산 칼데라 해저열수 분출구의 광석광물 산상 및 유체포유물 연구)

  • Choi, Sun Ki;Lee, Kyeong-Yong;Pak, Sang Joon;Choi, Sang-Hoon;Lee, In-Kyeong
    • Economic and Environmental Geology
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    • v.48 no.4
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    • pp.273-285
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    • 2015
  • The extensive hydrothermal deposits have been found, for the first time, on the western TA25 seamount caldera in the Tonga arc. The seafloor hydrothermal vents are active and immature, emitting the transparent fluids of which temperatures range from $150^{\circ}C$ to $242^{\circ}C$ (average=$203^{\circ}C$). The recovered hydrothermal sulfides are mainly composed of sphalerite, pyrite, marcasite, galena, chalcopyrite, covellite, tennantite, enargite and sulfates such as barite, gypsum/anhydrite. Predominant sphalerite categorize it into Zn-rich hydrothermal ore body. Zn-rich sulfide ores have minor enargite, indicating that mineralization occurred in high sulfidation environment. The proportion and FeS content of sphalerite increase from outside to inside of the hydrothermal ores, respectively. In particular, sphalerite has a great silver content (up to ~10 wt.%). Chalcopyrite is more frequently observed in mound than in the chimney, implying mineralization temperature in the mound is higher than in the chimney. Homogenization temperatures and salinities from fluid inclusions in barite at the mound range from $148^{\circ}C$ to $341^{\circ}C$ (average=$213^{\circ}C$) and 0.4 to 3.6 equiv. wt.% NaCl, respectively. Homogenization temperatures suggest that sulfides in the mound mineralized at a higher temperature (${\geq}200^{\circ}C$) than in the chimney.

Spectral Induced Polarization Response Charaterization of Pb-Zn Ore Bodies at the Gagok mine (가곡광산 연-아연 광체의 광대역유도분극 반응 특성)

  • Shin, Seungwook;Park, Samgyu;Shin, Dongbok
    • Geophysics and Geophysical Exploration
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    • v.17 no.4
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    • pp.247-252
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    • 2014
  • Gagok Mine, which is skarn deposits, includes sulfide minerals such as sphalerite, galena, chalcopyrite, and pyrrhotite. To explore these minerals, spectral induced polarization (SIP) is relatively effective compared to other geophysical exploration methods because there is a strong IP effect caused by electrode polarization. In the SIP, the chargeability related to sulfide mineral contents and the time constant related to the grain size of the minerals are obtained. For this reason, we aim to compare difference in the mineralized characteristics between two orebodies in the Gagok Mine by using the chargeability and the time constant. For this study, we sampled ores from the south of Wolgok orebody and the north of Sungok orebody. In order to recognize the mineralization characteristics, the metal content of the samples was measured by a potable XRF and the SIP data of the samples were acquired by using a laboratory SIP measurement system. As a result, the metals in the samples such as Pb, Zn, Cu, and Fe were detected by the portable XRF measurement. In particular, the Fe and Zn contents were far higher than the other metals. The Fe and the Zn were caused by the sphalerite and the pyrrhotite through microscopy. The Wolgok orebody had higher sulfide mineral contents than the Sungok orebody and the result corresponded with the chargeability result. However, we considered that the Sungok orebody had a larger sulfide mineral grain size than the Wolgok orebody because the time constant of the Sungok orebody was larger.

Photochemical Degradation of Polymers (고분자 물질의 광화학적 분해)

  • Sang Chul Shim;Hong Lim
    • Journal of the Korean Chemical Society
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    • v.19 no.6
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    • pp.454-462
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    • 1975
  • The photodegradation of polystyrene and polyethylene was studied utilizing several additives to promote photooxidation. Polymer films with small amount of additives were irradiated with ultraviolet lamps in Rayonet Photochemical Reactor. The progress of photodegradation was followed by measuring the intensities of carbonyl and hydroxyl stretching bands in infrared spectra as well as the viscosity changes. It was found that the increase of carbonyl or hydroxyl peaks was proportional to the decrease of the molecular weight of polymers under study. Iron(II, III) complexes of dithiocarbamate and their analogs showed good results.

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Characteristics of W-Mo Mineralization in Dulaankhaikhan area, Mongolia (몽골 중부 둘란하이한 지역의 W-Mo 부존 특성)

  • Lee, Bum Han;Kim, In Joon;Heo, Chul-Ho
    • Mineral and Industry
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    • v.26
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    • pp.22-31
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    • 2013
  • KIGAM and MRAM (Mineral Resources Authority of Mongolia) performed joint researches on geological survey of Dulaankhaikhan W-Mo occurrences areas in southeastern part of Khangai region. XRD results of tungsten containing quartz vein sample show that tungsten minerals are wolframite, hubnerite and ferberiteore. $WO_3$ grade of samples obtained in Silurian Khotont formation is 0.11-4.43% and that of samples obtained in Permian Delgerkhan complex is 137-3844 ppm. Average total $R_2O_3$ of samples obtained in survey area is 473 ppm which is 2.5 times larger than that of Earth's crust. The highest total $R_2O_3$ is 1326 ppm. Factor analysis results show that two areas of high tungsten contents have similar correlations with tungsten, and therefore we conclude that these two areas have the similar origin of mineralization.

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Mode of Occurrences and Depositional Conditions of Arsenopyrite from the Yeonhwa 1 Mine, Korea (연화 제1광산에서의 유비철석의 산상과 배태 조건)

  • Lee, Young-Up;Chung, Jae-Il
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.1-17
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    • 2003
  • The chemical composition of the arsenopyrite Ib adjoining“triple mutual contact”arsenopyrite + pyrite + hexagonal pyrrhotite may serve as a useful geothermometer in Stage II. In this study it corresponds to temperature T=33$0^{\circ}C$ and f( $S_2$)=10$^{-9.5}$ atm. And the pyrite-hexagonal pyrrhotite buffer curve indicates the probable range of the two variables; T= 315∼345$^{\circ}C$, and f( $S_2$)=10$^{-1}$0.5/∼10$^{-9}$ atm. The present antimony-bearing arsenopyrite (arsenopyrite Ic) is characterized by relatively high content of antimony, ranging from 4.95 to 8.91 percent Sb by weight and excess of iron and deficiency of anions are evident. Such a high antimonian arsenopyrite has never been known within single grain. But being the high content of antimony as in the arsenopyrite Ic, it does not serve as a geothermometer. The results of microprobe analyses for four pairs of asenopyrite and sphalerite in Stage III indicate the temperature range from 310 to 34$0^{\circ}C$, and sulphur fugacity range from 10$^{-10}$ ∼10$^{-9}$ atm. These values seem to correspond with those inferred from the Fe-As-S system.m..

Gold Mineralization of the Youngbogari Mine, Youngdong Area (영동지역 영보가리 광산의 금광화 작용)

  • Heo, Chul-Ho;Chi, Se-Jung
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.115-124
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    • 2007
  • Electrum-sulfide mineralization of the Youngbogari mine area occurred in two stages of massive quartz veins that fill the fractures along the fault/shear zones in the Precambrian gneiss. Ore mineralogy is simple, consisting of arsenopyrite $(31.4{\sim}33.4atom.%As)$, pyrite, sphalerite $(4.1{\sim}17.6mole%FeS)$, galena, chalcopyrite, argentite, and electrum. Electrum $(60.3{\sim}87.6atom.%Ag)$ is associated with galena, chalcopyrite and late sphalerite infilling the fractures in quartz and sulfides. Fluid inclusion data show that ore mineralization was formed from $H_2O-CO_2-CH_4-NaCl$ fluids $(X_{CO2+CH4}=0.0\;to\;0.2)$ with low salinities (0 to 10wt.% eq. NaCl) at temperatures between $200^{\circ}\;and\;370^{\circ}C$. Gold-silver mineralization occurred later than the base-metal sulfide deposition, at temperatures near $250^{\circ}C$ and was probably a result of cooling and decreasing sulfur fugacity caused by sulfide precipitation and/or $H_2S$ loss through fluid unmixing.