• Journal of the Korean Chemical Society
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• v.36 no.3
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• pp.405-411
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• 1992

The substitution reaction and structrue of products obtained from the reaction of Equatorial-Skew-[Co(TRDTRA)($OH_2$)] (TRDTRA = trimethylenediaminetriacetate) with $CN^-, NO^{-}_{2}$ and $NCS^-$ ions have been investigated by means of electronic absorption spectroscopy and theoretical calculation based on the Yamatera's theory. According to kinetic data, the substitution reaction order for the complexes such as $CN^-, NO^{-}_{2}$ and $NCS^-$ was the first order, respectively, and overall reaction order was second order. It has been determined that the structure of products having $CN^{-} and NO^{-}_{2}$ ions was Polar-Chair type complexes which were accompanying with isomerization and having $NCS^-$ ion was Equatorial-Skew type complex which was not accompanying with isomerization.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.12
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• pp.279-286
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• 2018

The grouting method is to reinforce the ground by injecting the chemical solution for the strengthening of the ground. Cement grouting material has usually used portland cement for centuries ago, but the cement particle size is large and the injection effect is limited. This study analyzes the effect of ultrafine cement grouting in rock ground using 3S-1 grouting in rock ground and ordinary Portland cement (OPC). The results of tests were compared and analyzed from the Lugeon test, bore loading test (P.M.T.), and injection (P-Q) test. The use of ultrafine cement (3S-1) had a higher effect (K, 10-6cm/sec) than OPC. The reinforcement effect of 3S-1 was also confirmed. Ultrafine cement (3S-1) was 4~9 times more injectable than OPC. Therefore, it is more advantageous to use ultrafine cement (3S-1) than OPC.

• Journal of the Korean Geosynthetics Society
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• v.22 no.4
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• pp.35-42
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• 2023

This paper described the strength variation characteristics to evaluate the applicability of a reactive material that can absorb organic pollutants as an underground barrier. The Strength was evaluated by unconfined compression test. The test results showed that the strength of the reactive material according to the absorption of each pollutant was in the order of water > TCE > TPH. However, the strength of the reactive material absorbing TPH was greater than that of the case absorbing TCE, when the composition ratio of polynorbornene was 12% or less. The strength of the reaction material in contact with water continued to decrease as the polynorbornene composition ratio decreased. The strength of the reaction material in contact with TCE and TPH increased as the polynorbornene composition ratio decreased from 30% to 21%, and then decreased. In other words, the optimal composition ratio of the reactive material should be applied considering the strength due to contact with pollutants according to the stress conditions occurring in the ground.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.1075-1082
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• 2008

Recently, coal ashes which are increasing annually are buried in ash ponds as industrial wastes. However, buried coal ashes can pollute ground water and ground due to leachate from coal ashes, which are serious environmental problem. Even though a lot of researches on recycling of coal ashes have been conducted, only 15% of coal ashes are recycled up to now. And those recycled coal ashes are not bottom ashes but fly ashes. So in this study, it was proved that Bottom Ash can be used as an alternative material to O.P.C(Ordinary Portland Cement) according to laboratory test results and test field construction. Also bottom ash is more economical and environmentally friendly than O.P.C.

• Korean Journal of Optics and Photonics
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• v.8 no.1
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• pp.73-79
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• 1997

We analyzed the variation of the focus error signal with the effect of land and groove, wavefront error, and optical system parameter variation for the knife-edge and astigmatism methods on the Land/Groove recordable optical disc, using a numerical simulation method. We verified causes of the zero-cross-shift that took place by the effect of land and groove by analyzing the diffraction beam including defocus wavefront errors. We also found that the sensitivty of the focus error signal was reduced by the effect of land and groove in the astigmatism method, as in the analysis of the focus error signal with the each order of the diffraction beam.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2011.04a
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• pp.635-638
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• 2011

유한요소법은 편미분방정식(Partial Differential Equation)의 수치적 근사 해를 구하기 위한 가장 일반적이고 효율적인 방법으로 다양한 공학 분야에서 널리 사용되어지고 있다. 유한요소법의 해석은 연속적인 범위를 가지는 문제를 여러 개의 요소로 나누어 다항식의 형상함수를 만들게 되며 결과적으로 근사 해를 구하게 된다. 이때 해석의 정확성을 높이기 위하여 형상함수의 차수를 높이고 요소의 개수를 늘리게 되면, 이에 따른 수치 계산량의 급격한 증가로 인해 수치해석의 효율성은 떨어지게 된다. 이를 보완하기 위해 유한요소법에 영역분할기법을 적용하여 병렬해석을 수행하면 해의 정확성과 효율성을 동시에 높인다. 병렬해석을 수행하는데 있어서 클러스터의 구조적 특성은 해석의 효율성에 영향을 미치게 된다. 따라서 본 논문에서는 일반적인 모델에 대하여 병렬해석의 수행을 통하여 클러스터의 구조적 특성이 병렬해석의 효율성에 미치는 영향에 대해 확인한다.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.553-556
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• 2006

Chloride penetration is the main reason which causes the deterioration of concrete structures. Chloride penetration of concrete structures due to chemical-physical phenomena can be profitably analyzed by means of model-based simulations. The main purpose of this paper is to analyze chloride penetration considering self-desiccation, convection and admixture(GBFS: granulated blast-furnace slag) effects. Basic governing equations are modified properly to apply these effects to chloride penetration analysis. Temperature and relative humidity data of In-Cheon from Korea Meteorological Administration are used for analyzing chloride penetration.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.219-219
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• 2019

모래저장형댐(sand dam)은 계곡이나 하천을 가로질러 보를 설치하고 확보된 공간을 모래와 같은 공극이 큰 투수성 재료로 채운 후 그 채움재 안에 물을 저장하는 구조물로서 증발량이 큰 건조지역에서 수자원 확보 수단으로 널리 이용되고 있다(Hanson and Nilsson, 1986). 국내에서는 차수 및 저류를 위한 제체를 지하 땅속에 설치한 지하수댐을 운영하거나 사방댐을 소규모 수자원공급시설로 개조하여 활용한 일부 사례가 있으나, 전형적인 모래저장형댐의 설계, 시공, 운영 사례가 전무하다. 본 연구에서는 A지역을 대상으로 모래저장형댐의 저류용량을 설계하고 수자원 확보효과를 분석하기 위해서 유역수문모형 SWAT으로 모의한 장기유출량과 방류구, 위어 등을 고려한 저수지 유출추적을 수행하였다. 모래저장형댐의 형태, 규모, 취수량, 지형조건, 수문학적 조건 등에 따른 댐내 수위, 저류량, 방류량 등의 변화를 분석하여 설치 부지에 대한 적정 설계 인자를 도출하였다. 또한 평시 및 가뭄시 물공급 효과와 유황개선 효과를 정량적으로 분석, 제시하였다.

• Journal of the Korean GEO-environmental Society
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• v.12 no.4
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• pp.17-24
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• 2011

For the purpose of cut off and ground stabilization, water glass chemical grouting method using sodium silicate has problems of weakening durability and ground water pollution because leaching was conducted when the homogel is exposed to the ground water as time elapses. The purpose of this study is to identify the effect of alkali silica sol ground injection materials, it was compared with the sodium silicate ground injection materials using water glasses. For sodium silicate and alkali silica sol by mixing each case is divided into four different specimens were made and tested. The characteristic of alkali silica sol ground injection material was analyzed by unconfined compression test and environmental impact statement of ordinary portland cement and blast furnace slag cement. Alkali silica sol specimens were made mixing A-solution and B-solution in the proportion of one on one. Through this study, alkali silica sol ground injection mixing blast furnace slag cement has excellent strength and environment-friendly.

• Journal of the Korean GEO-environmental Society
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• v.17 no.9
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• pp.37-45
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• 2016

This study analyzes the environmental and durability problems of traditional (LW) grouting method. And the proposed method was compared to the others effects by analyzing the in-situ applicability and effect of performance of the method using the silica sol. This study analyzed the eco-friendly, effects of high strength silica sol through laboratory tests. The effects of the construction process were identified through the field tests. The compressive strength was increased by 1.3 times compared to the LW method and the shrinkage is 3~8 times less than that of LW method with water glass. No toxicity, which could affect soil contamination. In particular, it was confirmed that the Toxicity fish also survived with little pH change in the concentration tank. Also it confirmed the construction effects through field test. Field tests are a standard penetration test, permeability test, LLT, BST. Permeability was reduced to $1{\times}10^{-5{\sim}-6}cm/sec$.