• Title/Summary/Keyword: 질소산화물 저감

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A numerical study of the air fuel ratio effect on the combustion characteristics in a MILD combustor (공연비 변화가 MILD 연소 특성에 미치는 영향에 관한 해석적 연구)

  • Ha, Ji-Soo;Kim, Tae-Kwon;Shim, Sung-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.6
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    • pp.587-592
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    • 2010
  • A numerical analysis of reactive flow in a MILD(Moderate and Intense Low oxygen Dilution) combustor is accomplished to elucidate the characteristics of combustion phenomena in the furnace with the variation of air fuel ratio. For the smaller magnitude of air injection velocity(10 m/s), the air flow could not penetrate toward upper part of furnace. On the other hand, the air flow suppresses the fuel flow for the case of air injection velocity 30 m/s. The air velocity 18 m/s is corresponding to the stoichiometric air flow velocity, and for that case, the air flows to relatively more upper part of the furnace when compared with the case of air injection velocity 10 m/s. The reaction zone is produced with the previous flow pattern, so that the reaction zone of the air injection velocity 10 m/s is biased to the air nozzle side and for the case of air injection velocity 30 m/s, the reaction zone is inclined to the fuel nozzle side. For the cases with the air injection velocities 16, 18, 20 m/s, the reaction zone is nearly located at the center between air nozzle and fuel nozzle. The maximum temperatures and NOx concentrations for the cases of air injection velocity 16, 18, 20 m/s are lower than the cases with air injection velocity 10, 30 m/s. From the present study, the stoichiometric air fuel ratio is considered as the most optimal operating condition for the NOx reduction.

A Study on the Flow Entrainment Characteristics of a Coaxial Nozzle Used in a MILD Combustor with the Change of Nozzle Position and Flow Condition (MILD 연소로에서 노즐의 위치와 유동 조건에 따른 유입량 특성에 관한 연구)

  • Shim, Sung-Hoon;Ha, Ji-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.2
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    • pp.103-108
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    • 2012
  • A MILD (Moderate and Intense Low oxygen Dilution) combustor decreases NOx formation effectively during the combustion process and NOx formation is affected significantly by the exhaust gas entrainment rate toward fuel and air. The present study focused on the new MILD combustor, which has coaxial cylindrical tube. The outside tube of the new MILD combustor corresponds to the exhaust gas passage and the inner side tube is the furnace passage. The connection pipe is set between the outer side and the inner side tubes and coaxial air nozzle is inserted at the center of the connection pipe. A numerical analysis is accomplished to elucidate the characteristics of exhaust gas entrainment toward the inner furnace with the changes of air nozzle exit velocity, nozzle diameter, nozzle exit position and exhaust gas side pressure. The entrainment rate is proportional to the square root of air nozzle exit velocity and negatively proportional to the pressure difference between the exhaust gas side and furnace side pressures. The effect of air nozzle exit position is not considerable on the exhaust gas entrainment.

Conversion of NOx by Plasma-hydrocarbon Selective Catalytic Reduction Process (플라즈마-탄화수소 선택적 촉매환원공정을 이용한 질소산화물 저감 연구)

  • Jo, Jin-Oh;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.103-111
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    • 2018
  • A plasma-catalytic combined process was used as an attempt to improve the conversion efficiency of nitrogen oxides ($NO_x$) over a wide temperature range ($150{\sim}500^{\circ}C$) to cope with the exhaust gas whose temperature varies greatly. Since the catalytic $NO_x$ reduction is effective at high temperatures where the activity of the catalyst itself is high, the $NO_x$ reduction was carried out without plasma generation in the high temperature region. On the other hand, in the low temperature region, the plasma was created in the catalyst bed to make up for the decreased catalytic activity, thereby increasing the $NO_x$ conversion efficiency. Effects of the types of catalysts, the reaction temperature, the concentration of the reducing agent (n-heptane), and the energy density on $NO_x$ conversion efficiency were examined. As a result of comparative analysis of various catalysts, the catalytic $NO_x$ conversion efficiency in the high temperature region was the highest in the case of the $Ag-Zn/{\gamma}-Al_2O_3$ catalyst of more than 90%. In the low temperature region, $NO_x$ was hardly removed by the hydrocarbon selective reduction process, but when the plasma was generated in the catalyst bed, the $NO_x$ conversion sharply increased to about 90%. The $NO_x$ conversion can be maintained high at temperatures of $150{\sim}500^{\circ}C$ by the combination of plasma in accordance with the temperature change of the exhaust gas.

Effect of EGR on power and exhaust emissions in diesel engine (디젤엔진의 출력 및 배기가스에 미치는 EGR의 영향)

  • Song, Kyu-keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.9
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    • pp.870-875
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    • 2015
  • Diesel engines are widely used due to superior power and fuel consumption, however there are many challenges in exhaust gas management. Exhaust gas recirculation (EGR) is the most effective technique for reducing mono-nitrogen oxide (NOx) emissions in a diesel engine, in comparison with other catalytic technologies. In addition, the technology has a number of advantages in terms of economic efficiency and implementation. In this study, the effects on the power and exhaust characteristics of diesel engines equipped with EGR systems were investigated. It was found that as the EGR rate increased, horsepower expressed as IHP and BHP decreased. The net effect of the application of EGR was measured at various engine speeds. EGR technology caused decreases in BHP of around 9% during low engine speed and 3.5% during high engine speed. Additionally, NOx emissions reduced as the EGR rate increased, and increased as engine speed increased. However, smoke emissions increased as the EGR rate increased, and decreased as engine speed increased. The optimum operating conditions and ERG rate to simultaneously achieve minimum NOx and smoke emissions were investigate. It was found that as the EGR rate increased, optimal operating speed for minimal NOx and smoke also increased. Keywords: Diesel engine, Exhaust gas recirculation, Power perfomance, Emission characteristics, NOx, Smoke

Internal Flow Analysis of Urea-SCR System for Passenger Cars Considering Actual Driving Conditions (운전 조건을 고려한 승용차용 요소첨가 선택적 촉매환원장치의 내부 유동 해석에 관한 연구)

  • Moon, Seong Joon;Jo, Nak Won;Oh, Se Doo;Lee, Ho Kil;Park, Kyoung Woo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.3
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    • pp.127-138
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    • 2016
  • Diesel vehicles should be equipped with urea-selective catalytic reduction(SCR) system as a high-performance catalyst, in order to reduce harmful nitrogen oxide emissions. In this study, a three-dimensional Eulerian-Lagrangian CFD analysis was used to numerically predict the multiphase flow characteristics of the urea-SCR system, coupled with the chemical reactions of the system's transport phenomena. Then, the numerical spray structure was modified by comparing the results with the measured values from spray visualization, such as the injection velocity, penentration length, spray radius, and sauter mean diameter. In addition, the analysis results were verified by comparison with the removal efficiency of the nitrogen oxide emissions during engine and chassis tests, resulting in accuracy of the relative error of less than 5%. Finally, a verified CFD analysis was used to calculate the interanl flow of the urea-SCR system, thereby analyzing the characteristics of pressure drop and velocity increase, and predicting the uniformity index and overdistribution positions of ammonia.

Effect of Vane Angle of Swirl Type Mixer on Flow Mixing and Pressure Drop in Marine Selective Catalytic Reduction Systems (선박용 SCR 시스템에서 스월형 혼합기의 날개 각도가 유동혼합 및 압력강하에 미치는 영향)

  • Park, Taewha;Sung, Yonmo;Kim, Taekyoung;Choi, Cheolyong;Kim, Duckjool;Choi, Gyungmin
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.443-448
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    • 2015
  • A swirl type mixer was developed to improve the flow mixing performance of a marine selective catalytic reduction system. In this study, the swirl type mixer and a multi-staged swirl type mixer, in which the angle of the vanes at each stage is controllable were considered to provide the optimal region of angles for the mixers. The effects of the vane angles in both mixers on the uniformity index and pressure drop were investigated using a computational fluid dynamics simulation. In the swirl type mixer, the optimal conditions for the flow mixing performance were observed at vane angles from 30 to 60 degrees when vane angles could be adjusted between 10 to 80 degrees, however, the pressure drop increased continually with increasing vane angle of the mixer. On the other hand, control of the individual staged angles of the multi-staged mixer showed that it is possible to keep enhancing flow mixing performance while reducing the pressure drop.

Real Time Measurement of Exhaust Emissions from Main Engine using Training Ship (실습선을 이용한 주 추진기관의 배기배출물의 실시간 계측)

  • Choi, Jung-Sik;Lee, Sang-Deuk;Lee, Kyoung-Woo;Chun, Kang-Woo;Nam, Youn-Woo;Yoon, Seok-Hun;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.5
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    • pp.531-537
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    • 2013
  • In this study, we conducted real-time measurement at the ship arrivals and departures at the port and at a constant speed of 150 rpm for exhaust emissions from a main engine installed on the training ship, HANBADA, of Korea Maritime University. The result showed that the concentration of nitrogen oxide was measured in the range of 800 ppm to 1,000 ppm at constant speed mode. On the other hand, the concentration of nitrogen oxide during ship arrivals and departures was significantly fluctuated between 210 ppm and 1,230 ppm. And, the concentration of carbon oxide at the arrivals and departures was also larger than that of at constant speed mode. These results show that the ship maneuvering skills to prevent a sudden load change of main engine at the arrivals and departures of ship is needed. Additionally, it means that the difference of exhaust emissions generated between the constant speed mode and the arrival/departure has to be considered when invented many technologies are adopted into the reduction technologies of air pollutants from ships.

Study on Characteristics of Change of Urea and Biuret Content by Temperature Variation in Urea Solution (요소수(Urea solution)의 온도변화에 따른 요소 및 뷰렛함량 변화 특성 연구)

  • Doe, Jin-woo;Park, Tae-sung;Lee, Yu-rim;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1307-1319
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    • 2018
  • As interests in the air pollution increases, many kinds of researches are underway on the reduction of air pollutants. The removal of nitrogen oxides from the emission gas of diesel vehicles using urea solution has shown a great effect. The quality of urea solution is strictly defined by domestic law, but the increase of impurities in urea solution reduces the effect of reducing nitrogen oxides. Therefore, in this study, the change of physical properties of urea solution was analyzed after heating the urea solution for a certain temperature and time. Also, the changes of physical properties of urea solution were analyzed according to kinds of storage container and temperature for storing the urea solution. After heating the urea solution for a certain period of time, the biuret content in urea solution increased and the content of urea decreased. As the urea content decreased, both density and refractive index decreased. In the storage stability test carried out at a constant temperature with iron and PET containers, no change in physical properties was observed.

Effect of fuel injection timing on the combustion and NOx emission characteristics in a single cylinder diesel engine applied with diesel fuel for naval vessel and biodiesel (함정용 디젤 연료와 바이오디젤 연료를 적용한 단기통 디젤엔진에서 연료분사시기가 연소 및 질소산화물 배출특성에 미치는 영향)

  • Lee, Hyungmin
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.681-687
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    • 2014
  • The objective of this work presented here was focused on analysis of in-cylinder combustion characteristic, engine performance, and nitrogen oxides emission characteristic from marine gas oil for propulsion diesel engine of naval vessels and biodiesel with fuel injection timing in a single cylinder diesel engine. In addition, combustion process was analyzed with a high speed camera of marine gas oil and biodiesel fuel. Retarding the fuel injection timing from $BTDC25^{\circ}CA$ to $BTDC5^{\circ}CA$, in cylinder peak combustion pressure was gradually decreased, however, engine torque showed a tendency to increase. The highest nitrogen oxides level was measured at $BTDC15^{\circ}CA$, they were reduced at retarded and advanced condition on the basis of $BTDC15^{\circ}CA$. Comparing with combustion process of marine gas oil and biodiesel fuel at $BTDC5^{\circ}CA$, self-ignition timing of biodiesel fuel included oxygen content was faster than marine gas oil, however, a cautious observation indicates a slightly higher flame intensity for marin gas oil than biodiesel as a diffusion flame is developing.

Calcination Properties of Cement Raw Meal and Limestone with Oxidation/Reduction Condition (산화/환원 소성분위기에서 석회석 및 시멘트 원료물질의 소성거동 특성)

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Jin-Sang;Cho, Kye-Hong
    • Resources Recycling
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    • v.29 no.5
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    • pp.64-72
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    • 2020
  • When the multi-stage combustion process is applied to the cement kiln to reduce nitrogen oxide emissions in the cement industry, oxidation/reduction section that can increase combustion efficiency by reducing NOx to NO and completely burning unburned materials is essential In this study, when applied the oxidation/reduction system of the cement kiln preheater and calciner, the optimal oxidation/reduction calcination crisis that can secure the quality stability of the final product, cement clinker, was to be observed macroscopically, and the mass change of raw materials according to the burning conditions, decarbonation rate, and calcination rate were investigated. The results showed that the thermal decomposition of raw materials tends to be promoted in the oxidation condition rather than in the reduction condition, and that the thermal decomposition of limestone, which has a relatively high CaO content, is carried out later than that of cement raw meal, which is thought to be caused by the CO2 fractionation in the kiln. The thermal decomposition properties of raw materials according to oxidation/reducing burning condition showed a relatively large difference in temperature range lower than normal limestone themal decomposition temperature, which is thought to be expected to improve the thermal efficiency of raw materials according to the formation of oxidation condition in the section 750℃ of burning temperature. However, for this study, lab scale. Because there is a difference from the field process as a scale study, it is deemed necessary to verify the actual test results of the pilot scale.