• Title/Summary/Keyword: 질산칼륨

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질산칼륨을 첨가한 인산암모늄 방염제의 연소특성

  • Gwon, Gyeong-Ok;Kim, Yeong-Geun
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.04a
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    • pp.158-159
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    • 2013
  • 방염제인 인산암모늄에 질산칼륨을 첨가하여 질산칼륨이 인산암모늄의 방염성능에 미치는 영향을 DSC와 실체현미경으로 분석하였다. 활성화에너지는 키싱거방법을 도입하여 분석하였다. 방염성능 실험으로서 셀룰로스를 연료로 사용하였다. 질산칼륨이 일정량 첨가된 방염제를 사용하는 경우 인산암모늄의 활성화에너지를 높이고 탄화면적을 감소시켜 연소확대를 억제하였다. 방염제인 질산칼륨이 첨가된 인산염을 방염제로 사용하는 경우 질산칼륨의 강한 산화력으로 화염발생 온도를 낮추고 탄화형성을 억제하여 화재진행 속도를 낮추는 것으로 나타났다. 적정량 이하의 질산칼륨이 포함된 방염제의 처리는 연소속도를 높이고 탄화물형성을 감소시킬 수 있음을 제시하였다.

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ROLE OF POTASSIUM AND MALIC ACID FOR NITRATE TRANSLOCATION AND REDUCTION IN TOBACCO LEAF (담배잎에서 칼륨과 능금산이 질산태질소의 이동 및 환원에 미치는 영향)

  • 이윤환
    • Journal of the Korean Society of Tobacco Science
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    • v.7 no.2
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    • pp.141-149
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    • 1985
  • 뿌리에서 흡수된 질소는 대부분이 질산태이온으로 잎의 엽맥까지 도달하나 엽육에서 급격히 환원되어 유기태질소로 동화한다. 잎의 주맥을 통과하여 세맥까지 질산태질소로 이동되며 전질소의 1/2이상의 양까지 다다르나 엽육에서는 전질소함량이 엽맥의 5배까지 증가되어도 질산태질소는 $10^{-2}$ 정도로 급격히 환원되었다. 칼륨은 엽맥까지 질소와 동반 이동하나 엽육에서의 질산태질소환원에 의하여 이동이 차단되는 현상을 보였다. 엽육에 축적된 칼륨은 능금산의 축전을 촉진하였고 질산환원효소의 활성이 왕성하게 일어나는 하위엽에 높은 농도로 축적되었다.

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Conversion of Potassium Chloride to Potassium Nitrate by the Reaction of Nitrogen Dioxide (Potassium Chloride로부터 Nitrogen Dioxide 반응에 의한 Potassium Nitrate로의 전환)

  • Yim, Going
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.129-136
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    • 1996
  • The direct conversion of solid potassium chloride to solid potassium nitrate by the reaction of the chloride with gaseous nitrogen dioxide is suggested for the preparation of potassium nitrate. Thermodynamic calculations indicate that the free energy change is favorable at ordinary temperatures and that the reaction is exothermic. Experiments are described in which it was found that the reaction takes place at ordinary temperatures in the presence of a small amount of water with good yield. Nitrosyl chloride is produced simultaneously.

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Study on Manufacturing Process of Potassium Nitrate using the Natural Materials in Joseon Dynasty (천연물을 이용한 조선시대의 염초 제조공정에 관한 연구)

  • Kim, Jun-Soo;Kim, Ji-Hun;Jang, Mi-Kyeng
    • Explosives and Blasting
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    • v.33 no.2
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    • pp.1-14
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    • 2015
  • This study was performed to investigate the manufacturing process of the Yeomcho(potassium nitrate), a necessary raw material for making gunpowder using soils and ashes by our ancestor. 10 types of soils including underfloor soil and 6 kinds of ashes including mugwort ash were collected, referencing the historical record. The ionic components extracted from the soils and ashes were analyzed by ICP(inductively coupled plasma atomic emission spectrometer) and IC(ion chromatograph). Nitrate ions and potassium ions were dominantly contained in soils and ashes, respectively. In particular, nitrate ions were found in the highest lebels in underfloor soil which often has much exposure to human living environments and accumulated fine organic matter. Potassium ions contained in ash was affected significantly by the type of plant and the growth environments and the measured levels were the highest in mugwort ashes. Yeomcho of 68% purity was obtained from the soil and ash mixture of 1:1 and thid purity was improved by about 14% by fractional crystallization method.

Effect of Wallastonite, Potssium chloride and Potassium sulphate on the mineraligation of Urea (규회석 분말, 염화칼륨 및 황산칼륨이 요소질소의 유효화에 미친 영향)

  • Oh, Wang-Keun;Kim, Jea-Yeang
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.4
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    • pp.293-296
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    • 1990
  • The effect of wallastonite, potassium chloride and potassium sulphate on the ammonification and nitrification of urea was studied in a non-planted green house experiment, filling with 500g soil in plastic pot and incubating for 17 days. Potassium sulphate gave superior effect on the neutralizing soil acidity of wallastonite than potassium chloride and raised soil pH which promoted ammonification and subsequent nitrification of urea. Less than 20% $NO_3-N$ against the sum of $NH_4-N$ and $NO_3-N$ was accumulated in soils incubated bellow pH 6.0. It seemed that pH 5.2 to 6.0 was the critical range for the nitrification of ammonium, or raising the concentration of ammonia in soils to the toxic level to the nitrification. It appeared that the nitrification could be occuring in low moisture, air dried, conditions of soil.

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Nutritional Effect of Carbonized Tobacco Leaf Debris Neutralized by Nitric and Phosphoric Acid on Nursery Seedlings (연초가공부산물(煙草加工副産物)의 탄화정도(炭化程度)에 따른 질산중화능력(窒酸中和能力)과 비효(肥效))

  • Lee, Yun-Hwan;Hong, Soon-Dal
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.1
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    • pp.89-93
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    • 1985
  • In order to develop the nutrient material for growing plants, tobacco leaf debris (T.L.D) that is a residual product of cigarette processing was carbonated at about 50% of its weight and neutralized its alkalinity by nitric and phosphoric acid. This material ($T.L.D+3N-HNO_3+1N-H_3PO_4$ (10:1:1), as a consequence, contained 4.1% of nitrogen, 2.1% of phosphte, and 6.6% of potassium in value of about pH 7. It was very effective on seedling growth to apply 1 Kg of nutrient material per 110 1 of bed soil as basic dressing because of containing not only quick-acting nitrate but also slow-releasing organo-nitrogen and sufficient potassium.

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도금공정의 안전성평가

  • 박익철;이광원;박문희;이홍기
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.11a
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    • pp.79-85
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    • 2002
  • 도금이란 금속이나 비금속의 표면을 얇은 금속 막으로 밀착 피복 시켜 마무리하는 공정을 말한다. 이러한 도금은 제품에 내식성과 장식성, 기계적 강도 등을 주기 위한 목적에서 행해진다. 그러나 도금작업에서는 염산, 황산, 질산 등의 산성물질(Acid)과 수산화나트륨, 수산화칼륨 등의 알칼리성 물질 및 시안화칼륨, 시안화나트륨 등의 시안화크롬화합물 이외에도 다수의 유해한 화학물질을 취급하고 있다.(중략)

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Thermal Decomposition of Phase Stabilized Ammonium Nitrate (PSAN) (상안정화 질산암모늄(PSAN)의 열분해)

  • 김준형;임유진
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.4
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    • pp.23-30
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    • 1999
  • The thermal decomposition of phase stabilized ammonium nitrate(PSAN) was studied by means of thermogravimetric analysis(TGA). In this study, potassium nitrate and zinc oxide were used as the phase stabilizers in the range of contents from 0 wt.% to 8 wt.%. The kinetics and mechanism for the decomposition were evaluated using integral methods. It was found that the thermal kinetic parameters such as activation energy(I) and frequency factor(A) increase with the increase of the stabilizer contents, and the mechanism of decomposition also changes.

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Influence of Fertilization Treatment using Organic Amendment based on Soil Testing on Plant Growth and Nutrient use Efficiency in Cabbage (토양검정에 의한 유기자원 시비처방이 양배추의 생육 및 양분이용효율에 미치는 영향)

  • Lim, Jin-Soo;Lee, Bang-Hyun;Kang, Seung-Hee;Lee, Tae-Guen
    • Korean Journal of Environmental Agriculture
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    • v.39 no.2
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    • pp.95-105
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    • 2020
  • BACKGROUND: In this study, in order to verify the effects of supplemented organic amendment fertilizers recommended by the soil testing on cabbages, we used various amounts of organic amendment fertilizers. The amount of organic amendment fertilizers was decided by calculating each ratio of inorganic nitrogen, phosphorus, and potassium based on the recommended fertilizer composition. METHODS AND RESULTS: The cabbages subjected to treatments 1 and 2 showed similar or greater leaf colors (SPAD values), head heights, head widths, head weight, soil organic matter content, nitrate-nitrogen level, and conductivity after harvest, when compared with cabbages treated with chemical fertilizers. The phosphorus and potassium fixation in the soil were higher in the plot where cabbages were treated with chemical fertilizers, and the nutrient use efficiency was greater in the plots with organic amendments and mineral addition. CONCLUSION: The treatments 1 and 2 that were supplemented with 180-200% of nitrogen, 100-130% of phosphorus, and 185-250% of potassium in comparison to chemical fertilizers, applied by the inorganic ratios of nitrogen, phosphorus, and potassium can be used as organic amendment fertilizers for cabbages.

Thermal Decomposition Behavior of Boron-Potassium Nitrate (BKNO3) by TGA (열중량분석법에 의한 Boron-Potassium Nitrate(BKNO3)의 열분해 특성 연구)

  • Go, Cheongah;Kim, Junhyung;Park, Youngchul;Moon, Youngtaek;Seo, Taeseok;Ryu, Byungtae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.104-110
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    • 2019
  • The thermal decomposition characteristics of boron-potassium nitrate ($BKNO_3$) were investigated by non-isothermal thermal gravimetric analysis (TGA). Two steps of mass loss were observed in the temperature range between room temperature and $600^{\circ}C$. Kinetic parameters of the thermal decompositions were evaluated from the measured TGA curves using the AKTS Thermokinetics Software. For the first step of mass loss ($220-360^{\circ}C$) corresponding to the thermal decomposition process of the binder (Laminac/Lupersol), the activation energy is in the range of approximately 120-270 kJ/mol when evaluated by Friedman's iso-conversional method, while the value of activation energy varies in the range of approximately 150-400 kJ/mol during the second step process ($360-550^{\circ}C$).