• Title/Summary/Keyword: 질산염 제거

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해수 순환여과 탈질시스템에서 질소 제거 능력

  • 손맹현;전임기;조기채
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2000.05a
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    • pp.296-297
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    • 2000
  • 순환여과 시스템에서 사육어가 먹이를 섭취한 후 사육수 중에 배설하는 암모니아는 생물 여과조에서 질산화과정에 의해 독성이 적은 질산염으로 축적되는데, 이러한 질산염도 고농도로 축적되면 어류의 성장에 영향을 미치게 된다. 이 실험에서는 생물여과조에 탈질 시스템을 장치하여 효과적인 질산염 제거(Arbia and van Rijn, 1995; Whitson et al., 1993)를 위한 탈질 조건별 사육수질변화 및 이에 따른 실험어인 조피볼락, Sebastes schlegeli 및 큰민어, Nibea japonica의 성장에 미치는 영향을 조사하였다. (중략)

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Adsorption of Nitrate and Phosphate onto the Dredged Sediment from a Coastal Fishery (연안어장 준설퇴적물에 대한 질산염과 인산염의 흡착)

  • Sun, Young-Chul;Kim, Myoung-Jin;Song, Young-Chae
    • Journal of Navigation and Port Research
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    • v.36 no.6
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    • pp.459-463
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    • 2012
  • In the present study, experiments have been performed to investigate the effects of the type of adsorbent, pH, and ionic strength on the adsorption of nutrients (nitrate and phosphate in artificial solution) onto the dredged sediment from a coastal fishery. In addition, this study aims to evaluate the possibility of removing the nutrients from the water using the dredged sediment. In the adsorption experiments of the nutrients, the reactions were completed within 10 minutes using ${NO_3}^-$-N($100{\mu}M$, 10mM) and ${PO_4}^{3-}$-P($100{\mu}M$, 10mM). In the steady state, 61% and 77% of the initial amounts were removed respectively for $100{\mu}M$ ${NO_3}^-$-N and $100{\mu}M$ ${PO_4}^{3-}$-P. The thermal treatment of the dredged sediment at $900^{\circ}C$ was not helpful to increase the removal efficiencies of the nutrients. Additives such as CaO and MgO dropped the removal efficiency of ${NO_3}^-$ to 0%, but increased that of ${PO_4}^{3-}$ up to 98%. Adsorption isotherms of ${NO_3}^-$ and ${PO_4}^{3-}$ could be explained by the Freundlich equation ($R^2$>0.99). The adsorption reaction was little influenced by the pH and ionic strength. Based on the results showing short reaction time and considerably high removal efficiencies of the nutrients, it is proposed to apply the dredged sediment from a coastal fishery to removing nutrients such as nitrate and phosphate in the water.

Sequential Anoxic/Aerobic Biofilm Reactors and MF Membrane System for the Removal of Perchlorate and Nitrate (무산소/호기생물막반응조와 MF막의 연속처리에 의한 퍼클로레이트와 질산염 제거)

  • Choi, Hyeoksun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.5
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    • pp.301-306
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    • 2013
  • This research was conducted to investigate whether sequential anoxic/aerobic biofilm reactors and microfilteration (MF) membrane system can be used as a direct treatment for the removal of perchlorate and nitrate in groundwater. The biofilm process consisted of an anoxic first stage to remove perchlorate and nitrate and aerobic second stage to remove remaining acetate used as a carbon source for dissimilatory reduction of perchlorate and nitrate. In final stage, hollow fiber MF membrane was used to remove turbidity. In this research, perchlorate was reduced from the influent concentration of 102 ${\mu}/L$ to below the IC detection level (5 ${\mu}/L$) and nitrate was reduced from 61.8 mg/L (14 mg/L $NO_3$-N) to 4.4 mg/L (1 mg/L $NO_3$-N). Acetate used as a carbon source was consumed from 179 mg/L $CH_3COO-$ to 117 and 11 mg/L $CH_3COO^-$ in effluents from anoxic and aerobic biofilm reactors, respectively. Turbidity was reduced from 3.0 NTU to 1.5, 0.3, and 0.2 NTU in effluents from anoxic/aerobic biofilm reactors and MF membrane, respectively. It is expected that the sequential anoxic/aerobic biofilm reactors and MF membrane system can efficiently remove perchlorate and nitrate in surface water or groundwater.

Nitrate Removal and Recycling Technique (질산 제거 및 재이용 기술)

  • Lee, Kyoung Hee;Sim, Sang Jun;Choi, Guang Jin;Kim, Young Dae;Woo, Kyoung ja;Cho, Young Sang;Choi, Eui-So
    • Clean Technology
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    • v.3 no.2
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    • pp.87-93
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    • 1997
  • A new process has been developed for nitrate and other salts removals from polluted waters. Alumina cement and calcium oxide served as precipitating agents to remove nitrate with stirring at basic pH. Low content of alumina in the commercialized alumina cements resulted in a increasing in nitrate removal yield. It is found that the compositions of aluminium and calcium are the most important factors in successful nitrate insolubilization. In order to remove high concentration of nitrate in polluted water, multi-stage precipitation was found to be very effective. Sulfate, chloride, and phosphate ions as well as nitrate were also removed by the precipitated reaction. After precipitation, post-treatments including Na2CO3 addition and neutralization with acid alleviated the level of aluminium and calcium in the treated water.

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U 포함 질산염 용액의 안정화에 미치는 $Al_2O_3$의 영향

  • 오종혁;황두성;김연구;이규일;최윤동;황성태;박진호
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.232-232
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    • 2004
  • 우라늄 변환시설 내의 라군 슬러지의 처리를 위해 슬러지의 물 첨가 용해를 실시하고, 여과후 발생한 질산염의 안정적 처리를 위한 열분해를 실시하였다. 라군 슬러지의 질산염 및 우라늄 제거공정은 후속처리공정에서의 부담을 최소화 할 수 있도록 1.5배의 물을 첨가 용해하였으며, 두 개의 라군에 저장된 슬러지 처리방법의 효율성 평가를 위하여 각 라군의 개별적, 혹은 혼합하여 실험을 실시하였다.(중략)

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Separation Technologies for the Removal of Nitrate-Nitrogen from Aqueous Solution (수용액으로부터 질산성질소 제거를 위한 기술)

  • Seo, Yang Gon;Jung, Se Yeong
    • Clean Technology
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    • v.23 no.1
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    • pp.1-14
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    • 2017
  • At high nitrate concentrations, water must be treated to meet regulated concentrations because it results in threat to human health and eutrophication of natural water. However, it is almost impossible to remove nitrate by conventional water treatment methods such as coagulation, filtration and precipitation, due to its high water solubility. Therefore, other technologies including adsorption, ion exchange, reverse osmosis, denitrification, and electrodialysis are required to effectively remove nitrate. Each of these technologies has their own strengths and drawbacks and their feasibility is weighted against factors such as cost, water quality improvement, residuals handling, and pre-treatment requirements. An adsorption technique is the most popular and common process because of its cost effectiveness, ease of operation, and simplicity of design. Surface modifications of adsorbents have been enhanced their adsorption of nitrate. The nitrate-selective membrane process of electrodialysis reversal and reverse osmosis have proven over time and at many locations to be highly effective in removing nitrate contaminating problems in aqueous solutions. Both electrodiaysis and reverse osmosis methods generate highly concentrated wastes and need careful consideration with respect to disposal.

Reduction of Perchlorate and Nitrate by Citrobacter Amalonaticus Strain JB101 : Kinetics and the Applicability of MBR (Citrobacter Amalonaticus Strain JB101에 의한 과염소산염과 질산염의 환원 : Kinetics 및 MBR을 이용한 처리 가능성)

  • Hong, Jae-Wha;Jang, Myung-Su;Lee, Il-Su;Bae, Jae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1298-1304
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    • 2005
  • This study was performed to evaluate the characteristics of the competition between two electron acceptors, perchlorate and nitrate, with Citrobacter Amalonaticus strain JB101. In addition, the applicability of membrane bioreactor(MBR) for perchlorate removal was evaluated. The maximum growth rate of strain JB101 on perchlorate and nitrate are 0.27 and 0.58 $hr^{-1}$, and maximum substrate utilization rates were 35.1 mg $ClO_4^-/g$ protein-day and 45.6 mg $NO_3^-/g$ protein-day, respectively. Nitrate was a competitive inhibitor for perchlorate, and strain JB101 prefer nitrate to perchlorate as electron acceptor. Complete removal of perchlorate could be achieved up to the surface leading rate of 4.6 g $ClO_4^-/m^2-day$ with the MBR fed with 20 mg $ClO_4^-/L$(HCMBR). When 5 mg/L of nitrate was added to the same influent, perchlorate removal efficiency decreased to 96.5%, while nitrate was completely removed. For the MBR fed with 0.7 mg/L of perchlorate (LCMBR), the maximum perchlorate removal efficiency was 100% up to the loading rate of 0.23 g $ClO_4^-/m^2-day$. Membrane fouling was found to be a problem at high leading rate for both MBRs. The acetate consumption ratio per perchlorate was $13.7{\sim}51.7\;e^-eq./e^-eq.$ in LCMBR, while the value was $2.5{\sim}3.6\;e^-eq./e^-eq.$ in HCMBR. This difference could be related to the acetate consumption with oxygen as electron acceptor. Therefore, the amount of acetate addition must be determined considering the concentrations of other electron acceptors in the influent.

Nutrient Removal using the Denitrifying Phosphate Accumulating Organisms (dPAOs) and Microbial Community Analysis in Anaerobic-Anoxic Sequencing Batch Reactor (Denitrifying Phosphate Accumulating Organisms (dPAOs)을 이용한 영양소제거 및 반응조내 미생물 분포 조사)

  • 박용근;이진우;이한웅;이수연;최의소
    • Korean Journal of Microbiology
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    • v.38 no.2
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    • pp.113-118
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    • 2002
  • Laboratory experiments were aimed to evaluate the effect of nitrate as a electron acceptor during the biological phosphorus uptake and to investigate the microbial community. Anaerobic-anoxic sequencing batch reactor (SBR) compared the removal behaviour to anaerobic-oxic SBR, both SBRs maintained lower effluent quality with 1.0 mgp/1. Anaerobic-anoxic SBR was able to remove additional 5.0 to 7.0 mg (P+N)/ι than other biological nutrient removal (BM) system. Therefore, it was proposed that the anaerobic-anoxic SBR was more effective at weak sewage. From the results of the maicrobial community analysis, it can be inferred that denitrifying bacteria and polyphosphate accumulating bacteria coexist in anaerobic-anoxic SBR during stable condition for removing the nitrogen and phosphorus. Particularly, it was suggested that the Zoogloea ramigera in the $\beta$-subclass of proteobacteria and the Alcaligenes defragrans of the Rhodocyclus group in the $\beta$-subclass of proteobacteria played a major role for removing the nitrogen and phosphorus as dPAOs (denitrifying phosphate accumulating organisms).

Simultaneous Removal of Ammonium and Nitrate by Natural Zeolite and Bacteria (천연 zeolite와 미생물을 이용한 NH4+ 및 NO3-의 동시 제거)

  • Lee, Seon-hee;Lee, Ji-Hye;Kim, Duk gyum;Lee, Chang-Soo;Kang, Kyung Suk;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.971-976
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    • 2008
  • Water pollution by ammonium ion and nitrate is a common and growing problem in the ecosystem. Process of biological removal consists of nitrification and denitrification by bacteria. Ammonium is oxidized generally to nitrate by nitrification and nitrate is reduced to dinitrogen gas in the subsequent denitrification process. Although natural zeolite is well known for its ability to preferentially remove ammonium, it is not sufficiently removing ammonium ion and nitrate by adsorption. In order to overcome this problem, a method of biological removal with zeolite is used for simultaneous removal of ammonium and nitrate. As a result, in case of shaking culture with 1% seed and passing through zeolite column, the process revealed that ammonium ion could be removed completely after 14 hours. The removal of nitrate using columns with naturally adsorbed bacteria onto zeolite reached approximately 100% after 4 hours.