• Title/Summary/Keyword: 질산성 질소

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Distribution of Inorganic N from Fertigated and Broadcast-applied 15N-Urea along Drip Irrigation Domain (점적관수시 관비와 표면시비된 중질소 표지요소의 행동비교)

  • Yoo, Sun-Ho;Jung, Kang-Ho;Ro, Hee-Myong;Choi, Woo-Jung
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.4
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    • pp.292-301
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    • 2001
  • The objectives of this study were to measure the changes in soil moisture regimes and the distribution patterns of inorganic N derived from the fertigated $^{15}N$-labeled urea, and compare them with the results obtained from broadcast-applied soil under the same drip irrigation domain. In fertigated soil, a $^{15}N$-labeled urea solution of $117mg\;N\;L^{-1}$ was applied by surface drip irrigation for 4 weeks. In broadcast-applied soil, no the other hand, 4 g of $^{15}N$-labeled urea(1.87 g N) mixed thoroughly with 5 kg of soil was placed on the surface of packed soil. Soil water status was controlled by drip irrigation scheduled at soil matric potential of -50 kPa. A calibrated time-domain reflectometry probe was installed in the soil vertically 15 cm apart from a drip emitter to control drip irrigation. About 60% of urea-derived inorganic nitrogen was remained in the top zone between 0 and 10 cm depth of fertigated soil, while, most of the inorganic nitrogen (91%) was accumulated in the top zone of broadcast-applied soil. Of inorganic nitrogen derived from urea, the percentage of $NO_3{^-}$ was much higher for fertigation (99%) than for surface application (62%). The relatively lower recovery of urea-derived inorganic nitrogen of broadcast-applied urea-N (51%) than that of fertigated urea-N (89%) was attributable to enhanced $NH_3$ volatilization.

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The Effect of Soybean and Herbs on Formation of N-nitrosamine during the the Fermentation of Low Salted Anchovy (저염 멸치젓의 숙성 중 두류 및 허브류 첨가각 N-nitrosamine의 생성에 미치는 영향)

  • 신정혜;정미자;김형식;김행자;성낙주
    • The Korean Journal of Food And Nutrition
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    • v.14 no.3
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    • pp.204-210
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    • 2001
  • 전통수산 발효식품인 젓갈은 부패를 억제하기 위하여 20∼25%의 식염을 첨가하므로 짠맛이 강하고 성인병 유발과 유관하다는 단점이 있으므로 저식염 젓갈이 개발되고 있으나 저염 젓갈류는 비린내와 부패취가 강하여 기호도가 떨어질 뿐만 아니라 발암성 N-nitosamine(NA)의 생성 가능성이 높아지게 된다. 본 연구에서는 저염 젓갈의 저장성, 기호성 유지 및 NA생성을 억제코져 두류(대두, 검정콩) 및 허브류(애플민트, 페파민트, 레몬밤 및 스파아민트)의 에탄올 추출물을 각각 첨가한 저염 멸치젓을 제조하여 110일간 숙성시키면서 품질과 관련된 여러 인자 및 NA 생성여부를 실험하였다. 저염 멸치젓 숙성 중 PH, 염도 및 산도는 모든 실험군에서 숙성 110일까지 큰 변화를 보이지 않았다. 휘발성 염기질소는 저장기간에 따라 점차 증가하는 경향을 보였는데 애플민트 추출물 첨가군이 가장 큰 폭으로 증가하였다. DMA 및 TMA 질소도 증가하는 경향을 보였는데 숙성 75일째부터 그 증가폭이 두드러졌다. 질산염 질소는 젓갈 숙성 중 점차 증가하는 경향을 보였으며, 아질산염 질소는 약간 증가하는 경향이었다 NA는 N-nitrosodi-methylamine(NDMA)만이 검출되었으며 대조군에 비하여 전 실험군에 더 낮은 함량이었으며 이때 평균회수율은 63.9∼99.7%였다. 허브 추출물 첨가군에서 대조군에 비하여 월등히 낮은 함량은 NDMA가 검출되었는데, 특히 페파민트 추출물 첨가군에서는 숙성 75일까지 흔적량에 불과하였다.

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Nitrogen Removal Characteristics in DynaFlow Biofilter System Using Sewage Wastewater of Low C/N Ratio (낮은 C/N비에서 운영되는 유로변경식 생물여과 공정의 질소 제거 특성)

  • Kim, Jin-Sik;Kim, Kyu-Ri;Kang, Han-Sol;Won, In-Seop;Kim, Keum-Yong;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.189-194
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    • 2012
  • In this study, a 3-stage biological aerated filter (BAF) system was proposed to enhance nitrogen removal in the treatment of low carbon to nitrogen ratio (C/N ratio) municipal wastewater. Laboratory experiments were conducted to evaluate the effects of dynamic-flow at the HRT of 6 h. Results of the long-term operation of 3-stage BAF systems showed that the dynamic-flow enabled the total nitrogen removal (T-N) removal efficiency of the system to be about 7 % higher than that of non-dynamic-flow system in treating domestic wastewater due to the more efficient use of organic substrates. The overall $NH_4$-N removal performance was stable during the operational period due to the unique system configuration where independent nitrification occurred. It was concluded that the 3-stage BAF system proposed in this study provided excellent performance in the removal of nitrogen by employing dynamic-flow and three columns functioning as sorption, denitrification and nitrification, respectively.

Recycling Water Treatment of Aquaculture by Using Three Phase Fluidized Bed Reactor (삼상유동층 반응기를 이용한 양어장 순환수 처리에 관한 연구)

  • LEE Byung-hun;KIM Jeong-sook;KANG Im-suk
    • Journal of Aquaculture
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    • v.7 no.3
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    • pp.177-187
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    • 1994
  • The objective of the present study were to evaluate nitrification characteristics and determine optimum treatment conditions of three phase fluidized bed reactor for recycling water treatment of aquaculture. When the loading rates were 2.739-0.086kg $COD/m^3/day$ and 1.575-0.128kg $NH_4\;^+-N/m^3/day$, COD and ammonia removal efficiencies were $56.3-94.7\%\;and\; 67.3­92.6\%$, respectively. The maximum removal rates of COD and ammonia were 1200mg/l/day and 488mg/l/day, respectively. Ammonia removal rates were more than $90\%$ beyond 1hr HRT. The ammoniaremoval efficiency was sensitive to the variation of media concentration and air flowrate.

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Removal of Nitrogen Using by SOD Process in the Industrial Wastewater Containing Fluoride and Nitrogen from the Zirconium Aolly Tubing Production Factory of the Nuclear Industry (원자력산업 지르코늄합금 튜브 생산공장에서 배출되는 불소.질소 함유 폐수의 황산화탈질을 이용한 질소처리)

  • Cho, Nam-Chan;Moon, Jong-Han;Ku, Sang-Hyun;Noh, Jae-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.855-859
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    • 2011
  • The main pollutants from zirconium alloy tubing manufacturing process in nuclear industry are nitrate ($NO_3-N$) and fluoride (F-)Nitric acid, and hydrofluoric acid is used for acid pickling. The process for the removal of nitrate and fluoride is composed of 1st chemical coagulation, SOD (Sulfur Oxidation Denitrification) process using sulfur-oxidizing denitrification, and 2nd chemical coagulation. The characteristic of the wastewater treatment is an application of SOD process. The SOD Process is highly received attention because it is significantly different from existing processes for sulfur denitrification. A JSC (JeonTech-Sulfur- Calcium) Pellet is unification of sulfur and alkalinity material. According to result of SOD process in wastewater treatment plant, the removal efficiency of T-N was over 91% and the average concentration of T-N from influent was 147.55 mg T-N/L and that from effluent was 12.72 mg T-N/L. Therefore, SOD process is a useful to remove nitrogen from inorganic industrial wastewater and a new development of microbial activator was shown to be stable for activation of autotrophic bacteria.

Isolation and Physiological Characteristics of Rhizobia with Good Nitrogen Fixation Ability (우량질소고정균(優良窒素固定菌)의 탐색분리(探索分離) 및 생리적(生理的) 특성(特性))

  • Park, Woo-Churl;Lee, Kwang-Hee;Kim, Jin-Ho;Rhee, In-Koo;Jo, Jin-Ki
    • Current Research on Agriculture and Life Sciences
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    • v.5
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    • pp.40-51
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    • 1987
  • This experiment was conducted to search for Rhizobia with good nitrogen fixation abilities and to investigate their physiological characteristics isolated from 12 soybean cultivars and the affinities of root nodule bacteria with soybeans. The results obtained were as follows; Based on colors, Rhizobia grown on YMA medium were divided into 3 groups, i. e., white, translucent and transparent, amounting to 60, 30 and 10%, respectively. In litmus milk reaction, the strains which produced alkali, acid serum, alkaline serum and acid reached to 51, 29, 9 and 11%, respectively. Strains, S022, and S096 were slow-growers and produced alkaili, while strains, S080, S-090, and S118 were fastgrowers and produced acid. The growth of root nodule bacteria on YMA medium was favorable between the initial pHs of 6.0~7.0. Glutamine, asparagine and al1antoin as nitrogen sources enhanced the growth of root nodule bacteria. All the strains tested formed nodules on the soybean roots, and the strains with good symbiotic nitrogen fixation abilities that had white color, small colony, nitrate reduction abilities and no nitrite reduction abilities showed comparatively high nitrogen fixing activities. Some strains varied in nitrogen fixing activities according to soybean cultivars, and a few strains fanned ineffective nodules which showed no nitrogen fixing activity.

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Estimation of Nitrate Sources in Cheju Island Groundwater using $\delta$$^{15}$ N ($\delta$$^{15}$ N을 이용한 제주도 지하수 중의 질산염 오염원 조사)

  • 송영철;고용구;유장걸
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.3
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    • pp.107-110
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    • 1999
  • 18 boreholes with nitrate contaminated were selected. Samples were collected 4 times between both 1995 and 1996. Stable nitrogen isotope ratio for them all was measured and the contribution to contamination from several sources like fertilizer, sewage, cropland. and landfill was analysed. Nitrogen source for 11 sampling sites of T-3, L-1. O-1∼O-4, F-2∼F-5, and G-2 considered to come from chemical fertilizer and its contribution was around 60% or more. T-4. T-5 were located downward the downtown, which were influenced bydomestic sewage and its contribution were 70.7% and 54.7%. Nitrate concentration of G-2 was 17.7 mg/L, among which 60.7% was estimated to come from landfill leachate. T-1 and T-2 were located in the small village, in which 42.2 and 43.4% of nitrogen was to come from domestic sewage but 52.8% and 56.0% were from fertilizer sprayed in the cropland. L-2 was near livestock by which it was estimated to be influenced, in which 59.9% of nitrogen was from cropland. F-1 was in the cropland, by which 50.0% was influenced and 49.5% was estimated from organic matter of animals.

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Establishment of Optimal Management Plans on Agricultural Groundwater Resources of the Yeosu County (여수시 농어촌지역 지하수자원 적정 관리방안)

  • Seo, Hyo Kyoung;Shin, Hyung Jin;Lee, Byung Sun;Lee, Gyu Sang
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.282-282
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    • 2020
  • 본 연구는 여수시 농어촌지역에 대하여 지하수 함양특성, 개발가능량 산정 및 오염부하량 등의 조사를 통해서 체계적인 지하수자원의 보전관리(안)을 수립하기 위해 수행되었다. 연구지역은 여수시 화양면, 소라면 2개 면을 포함하는 농어촌 용수구역(여소지구)으로, 여소지구의 총면적은 130.68 ㎢이며, 이 중 임야면적은 81.57 ㎢, 경지면적은 32.98 ㎢ 이고, 경지면적은 논 15.37 ㎢, 밭 17.42 ㎢, 시설재배 0.19 ㎢로 구성되어 있다. 여소지구의 30년 강수평균은 1,454.08 mm/년이며, 지하수 함양량은 국가지하수관리 기본계획(국토교통부, 2019) 및 전라남도 지하수관리계획(전라남도, 2009) 보고서를 참고하여 평균값인 11.28%로 산정한 결과, 21,279 천㎥/년으로 분석되었다. 또한, 지하수연보(국토교통부, 2018)의 세부용도별 이용량을 활용하여 지하수 이용량을 산정한 결과, 2,638.35 천㎥/년이었으며, 강수량, 함양률 및 면적 값을 고려하여 지하수 개발가능량을 산정한 결과, 16,387.57 천㎥/년, 개발가능량 대비 이용량은 16.11%로 확인되었다. 여소지구의 질산성질소 항목은 총 181개소(경지면적 0.2 ㎢당 1점)에 대해 분석한 결과, 전체 평균값은 6.67 mg/L이었으며, 농업용수 수질기준(20 mg/L)을 초과한 관정은 8개소(6%)로 확인되었다. DRASTIC을 이용한 오염취약성 지수는 평균값이 119.57점으로 나타나 오염취약성이 낮은 것으로 분석되었다. 신고·허가된 축사 시설을 기준으로 점오염원 조사결과, 단위면적당 시설수(오염원밀도)는 3.12 개소/㎢로 조사되었으며, 인구, 가축 및 토지이용 등 인자별을 고려하여 오염부하량을 산출한 결과, 단위면적당 오염부하량은 75.30 kg/day/㎢로 확인되었다. 행정구역별로 7가지 지표를 반영하여 관심, 주의, 경계 및 심각 4단계로 기준을 설정하여 지하수관리 필요지역을 선정하였다. 수량 측면은 개발가능량 대비 이용량, 단위면적당 이용량 및 관정밀 3가지 지표를 적용하였고, 수질 측면은 질산성질소 평균, 오염취약성 지수, 오염원밀도 및 단위면적당 오염부하량 4가지 지표를 적용하여 선정하였다. 지하수관리 필요지역을 분석한 결과, 전체 18개 리 중에서 14개 리에서 수량관리 12개리에서 수질관리 필요지역이 나타났다. 수량관리 필요지역은 지하수 취수량 조정 및 관리 확충 등의 대책방안이 마련되어야 하며, 수질관리 필요지역은 주변 오염원관리 및 수질검사 강화 등의 대책방안이 필요할 것으로 판단된다.

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Changes of Nitrogen Uptake, Growth and Activities of Nitrogen Metabolizing Enzymes by Different Source of Nitrogen in Tobacco (담배에서 질소 형태에 따른 흡수 양상 및 생육과 질소대사 효소의 활성 변화)

  • 이상각;심상인;강병화;배길관
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.5
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    • pp.515-521
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    • 1997
  • Tobacco plant was grown for 40 days hydroponically in nutrient solutions composed of different forms of nitrogen, like NO$_3$$^{[-10]}$ -N, NH$_4$$^{+}$-N, and a mixed formulation of NO$_3$$^{[-10]}$ -N and NH$_4$$^{+}$-N. Uptake response, nitrate reductase, and glutamine synthetase activity at growth stage were investigated to understand the basic knowledge of nitrogen metabolism. The better growth of shoot and root was observed in the mixed nutrient solution than NO$_3$$^{[-10]}$ -N or NH$_4$$^{+}$-N, alone. The plant growth in NH$_4$$^{+}$-N nutrient solution was poor due to ammonium toxicity. The pH of nutrient solution containing NO$_3$$^{[-10]}$ -N increased up to 40 days after transplanting. But the pH of solution containing NO$_3$$^{[-10]}$ -N decreased drastically to 3.42 at 20 days after transplant. The pH in the mixed formulation dropped to pH 3.64 at 30 days after transplant and showed re-increase. It is assumed that nitrogen of NH$_4$$^{+}$-N form was taken up preferentially at early stage and NO$_3$$^{[-10]}$ -N form was taken up preferentially at middle stage in the treatment with the mixed solution. The result indicates that the relative proportion of nitrogen forms affected the uptake patterns at each growth stages. The contents of chlorophyll and soluble protein were high with the mixed solution. Total nitrogen content was the highest in NH$_4$$^{+}$-N solution and the content also increased by the application of the mixed type of nitrogen. The amount of nitrate in leaves was high in NO$_3$$^{[-10]}$ -N treatment and the amount of ammonium was high in NH$_4$$^{+}$-N treatment. The activity of nitrate reductase or glutamine synthetase was highest in the leaves grown in mixed nutrient solution than in those with any other single of nitrogen form.

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Effects of Seeding Rate on Hairy vetch (Vicia villosa) - Rye (Secale cereale) Mixtures for Green Manure Production in Upland Soil (밭토양에서 녹비작물 헤어리베치와 호밀의 혼파비율이 Biomass 생산에 미치는 영향)

  • Jeon, Weon-Tai;Seong, Ki-Yeong;Lee, Jong-Ki;Kim, Min-Tae;Cho, Hyun-Suk
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.3
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    • pp.327-331
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    • 2009
  • Korean government has promoted the policy of chemical fertilizer reduction by 40% reduction from 2003 to 2013. Hairy vetch (Vicia villosa Roth) fixes nitrogen from the atmosphere and rye (Secale cerale L.) accumulates soil nitrogen to reduce potential nitrogen loss. The objective of this research was to identify optimum seeding rates of hairy vetch-rye mixtures in the central regions of Korea. The experiment of mixture rate was carried out for maximum production in 2006 and 2007. The best seeding rate mixture for maximum biomass production was 6.75 kg hairy vetch and 5 kg rye per 10a. Pure hairy vetch and rye were used as control. The nitrogen production of mixture treatments were higher than pure rye. The hairy vetch and rye mixture can scavenge potentially leachable nitrogen, while maintaining soil fertility by adding fixed nitrogen to the cropping system.