• Title/Summary/Keyword: 질량평형

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The Photocatalytic Decomposition of Isopropylalcohol(IPA) Using Plastic Optical Fiber(POE) Coated Photocatalyst (광촉매가 코팅된 플라스틱 광섬유를 이용한 Isopropylalcohol 광분해 반응)

  • 홍지녀;하진욱;주현규
    • Proceedings of the KAIS Fall Conference
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    • 2003.06a
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    • pp.343-346
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    • 2003
  • 본 연구에서는 IPA(isopropyl alcohol)를 분해물질로 선정하여 플라스틱 광섬유(Pastic Optical Fiber, POF)에 TiO₂를 코팅하여 오염물질을 분해하였다. P-25가 코팅된 POF의 표면은 유기계, 무기계, 유ㆍ무기 바인더를 사용한 것 모두 깨끗하였고, 무기계 바인더를 사용하여 코팅한 POF는 부착력이 현저히 떨어졌다. IPA 분해 결과, 무기계 바인더를 사용한 경우, 다른 종류의 바인더와는 다르게 IPA의 초기농도 값이 매우 작게나왔는데 이러한 결과는 반응기에 주입된 IPA가 평형이 될 때까지 기다리는 동안 흡착이 일어났기 때문으로 생각된다. 유기계 바인더를 사용하여 코팅한 POF는 IPA 분해 효율이 매우 저조하였고 유ㆍ무기 바인더를 사용하여 코팅한 POF의 IPA 분해 효율은 우수하였다. P-25와 IPA의 분해 효율이 우수한 유ㆍ무기 바인더의 비율을 10 : 10 : 8, 10 : 6, 10 : 4, 10 : 2로 바꾸어 IPA를 분해한 결과, P-25와 유ㆍ무기 바인더의 비율이 10 : 2일 때 IPA 분해 효율이 가장 우수하였다. 또한 P-25와 코팅액 제조 시 회석제로 사용되는 에탄올의 질량비를 1 : 7, 1 : 11, 1 : 15로 바꾸어 IPA를 분해한 결과, P-25와 에탄올의 비율이 1 : 15 일 때 IPA 분해 효율이 가장 우수하였다.

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$^{230}$ Th/$^{234}$ U disequilibrium dating of fracture-filling carbonate veins from the Ipsil and Janghangri fault zones, Gyeongju, Korea by multiple collector inductively coupled plasma mass spectrometry (다검출기 유도결합 플라즈마 질량분석기를 이용한 경주 입실, 장항리 단층 파쇄대 충진 탄산염암 맥의 $^{230}Th/^{234}U$ 비평형 연대측정)

  • 정창식;최만식;김현철;임상복
    • The Journal of the Petrological Society of Korea
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    • v.10 no.3
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    • pp.148-156
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    • 2001
  • We report $^{230}Th/^{234}U$ disequilibrium ages of fracture-filling carbonate veins from the Ipsil and Janghangri fault zones, Gyeongju, Korea by multiple collector inductively coupled plasma mass spectrometry. The U and Th fraction was extracted from totally dissolved samples by rapid and convenient coprecipitation and ion exchange chemistry. The recovery was around 80% for Th and 70% for U. The $^{234}U/^{238}U,\;^{230}Th/^{232}Th$ ratios were analysed for this preconcentrated fraction and the U/Th ratio was directly analysed for untreated sample solution. The $^{234}U-^{230}Th$ system is in secular equilibrium for the Ipsil carbonate samples, supporting previously reported ESR ages. The detrital-corrected $^{230}Th/^{234}U$ age of the Janghangri carbonate samples is $48\pm$41 ka, which constrains the minimum age of the fracture zone.

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Study on the Steam Line Break Accident for Kori Unit-1 (고리 1호기에 대한 증기배관 파열사고 연구)

  • Tae Woon Kim;Jung In Choi;Un Chul Lee;Ki In Han
    • Nuclear Engineering and Technology
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    • v.14 no.4
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    • pp.186-195
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    • 1982
  • The steam line break accident for Kori Unit 1 is analyzed by a code SYSRAN which calculates nuclear power and heat flux using the point kinetics equation and the lumped-parameter model and calculates system transient using the mass and energy balance equation with the assumption of uniform reactor coolant system pressure. The 1.4 f $t^2$ steam line break accident is analyzed at EOL (End of Life), hot shutdown condition in which case the accident would be most severe. The steam discharge rate is assumed to follow the Moody critical flow model. The results reveal the peak heat flux of 38% of nominal full power value at 60 second after the accident initiates, which is higher than the FSAR result of 26%. Trends for the transient are in good agreement with FSAR results. A sensitivity study shows that this accident is most sensitive to the moderator density coefficient and the lower plenum mixing factor. The DNBR calculation under the assumption of $F_{{\Delta}H}$=3.66, which is used in the FSAR with all the control and the shutdown assemblies inserted except one B bank assembly and of Fz=1.55 shows that minimum DNBR reaches 1.62 at 60 second, indicating that the fuel failure is not anticipated to occur. The point kinetics equation, the lumped-parameter model and the system transient model which uses the mass and energy balance equation are verified to be effective to follow the system transient phenomena of the nuclear power plants.lear power plants.

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Thermodynamic Modelling of Blast Furnace Slag Blended Cement Composites (고로슬래그가 치환된 시멘트복합체의 열역학적 모델링)

  • Yang, Young-Tak;Cha, Soo-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.488-495
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    • 2017
  • In this study, we conducted the kinetic hydration modeling of OPC and the final product according to the substitution ratio of GGBS by using the geochemical code, GEMS, in order to calculate the thermodynamic equilibrium. The thermodynamic data was used by GEMS's 3rd party database, Cemdata18, and the cement hydration model, the Parrot & Killoh model was applied to simulate the hydration process. In OPC modeling, ion concentration of pore solution and hydration products by mass and volume were observed according to time. In the GGBS modeling, as the substitution rate increases, the amount of C-S-H, which contributes the long-term strength, increases, but the amount of Portlandite decreases, which leads to carbonation and steel corrosion. Therefore, it is necessary to establish prevention of some deterioration.

Modeling on the Condensation of a Stable Steam Jet Discharging into a Quenching Tank (응축탱크로 방출되는 안정된 증기제트 응축모델)

  • 김환열;하광순;배윤영;박종균;최상민
    • Journal of Energy Engineering
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    • v.10 no.4
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    • pp.349-356
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    • 2001
  • Phenomenon of direct contact condensation (DCC) heat transfer between steam and water is characterized by the transport of heat and mass through a moving steam/water interface. Since the DCC heat transfer provides some advantageous features in the viewpoint of enhanced heat transfer, it is widely applied to the diversified industries. This study proposes a simple condensation model on the stable steam jets discharging into a quenching tank with subcooled water from a single horizontal pipe for the prediction of the steam jet shapes. The model was derived from the mass, momentum and energy equations as well as thermal balance equation with condensing characteristics at the steam/water interface for the axi-symmetric coordinates. The extremely large heat transfer rate at the steam/water interface was reflected in the effective thermal conductivity estimated from the previous experimental results. The results were compared with the experimental ones. The predicted steam jet shape(i. e. radius and length) by the model was increasing as the steam mass flux and the pool temperature were increasing, which was similar to the trend observed in the experiment.

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Analysis of the Degradation Products of Turmeric using GC-MS (GC-MS법을 이용한 울금의 퇴화물 분석)

  • Ahn, Cheun-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.6 s.165
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    • pp.859-868
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    • 2007
  • Degradation products of the dye extracted from turmeric and the turmeric dyed textiles were examined by using GC-MS after 100 oven (OV) and $H_2O_2/UV/O_2$(PER) treatments for up to 28 days. Throughout the OV degradation times, 2-propenoic acid, 3-(2-hydroxyphenyl)- was found consistently, while isovanillin, and vanillic acid were newly detected. In 28 day PER degradation sample, feruloylmethane, 2-propenoic acid, 3-(2-hydroxyphenyl)-, benzoic acid, and vanillic acid were detected as well as isovanillin. Feruloylrnethane, and 2-propenoic acid, 3-(2-hydroxyphenyl)- were detected from the degraded fabric samples. With the absence of curcuminoids in the GC-MS result, the decreasing pattern of 2-propenoic acid, 3-(2-hydrokyphenyl)- reflect the degradation of curcuminoids in turmeric extraction with the progression of OV degradation times. It is suggested that isovanillin, feruloylmethane, 2-propenoic acid,3-(2-hydroxyphenyl)-, and vanillic acid are the probable fingerprint products for determining the turmeric dye from the badly faded archaeological textiles.

Equilibrium Growth of Allanite and Zircon during Amphibolite-facies Metamorphism (각섬암상 변성작용 중 갈렴석과 저어콘의 평형 성장)

  • Kim, Yoonsup
    • The Journal of the Petrological Society of Korea
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    • v.27 no.2
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    • pp.97-104
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    • 2018
  • The U-Pb isotopic and rare earth element compositions of zircon were measured using a SHRIMP from a tonalitic gneiss sample DE43 in Daeijak Island, central Korea. Zircon crystals, up to ${\sim}300{\mu}m$ in diameter, rarely contain thin overgrowth rims. In contrast to Paleoproterozoic cores, the $^{206}Pb/^{238}U$ ages of $256{\pm}23Ma(1{\sigma})$, and $221{\pm}7Ma(1{\sigma})$ were yielded from two spot analyses on the overgrowth rims of zircon. The rims are geochemically characterized by low Th/U ratios (<0.01) and strongly depleted light rare earth elements. The Permian-Triassic apparent ages of zircon are consistent with the $^{208}Pb/^{232}Th$ ages dated from allanite ($227{\pm}7Ma(t{\sigma})$) in the same sample within uncertainties, indicating an equilibrium growth of allanite and zircon at ~227 Ma. On the other hand, the younger $^{208}Pb/^{232}Th$ and $^{206}Pb/^{238}U$ ages ($213{\pm}4Ma(t{\sigma})$ and $186{\pm}9Ma(t{\sigma})$, respectively) of allanite may result from Pb loss due to the infiltration of alkali fluids from Late Triassic and Jurassic granitoids nearby.

The Study on the Biomechanical Body Segment Parameters of Korean Adults with References to Sasang Constitutional Medicine (한국인 신체분절에 관한 사상의학적 연구)

  • Lee, Eui-ju;Lee, Jae-koo;Kim, Jeong-yun;Song, Jeong-mo
    • Journal of Sasang Constitutional Medicine
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    • v.10 no.1
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    • pp.143-160
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    • 1998
  • PURPOSE This studied the biomechanical body segment parameters of Korean adults with reference to Sasang Constitutional Medicine(SCM). We anlyzed the characteristics of Sasang constitution through Body Measurement, Immersion Method, and Reaction Board Method. SUBJECT Subjects were 72 persons. There were made 49 and Female 23. Mean age was . And There were Taeumin 30, Soyangin 17, and Soeumin 25. METHOD The items of Body Measurement were 51. Limbs were measured right side. Volume was gained with Immersion Method and Weight was calculated with the density equation for limbs from Drills and Contini. Center of Mass was gained with Reaction Board Method. RESULT 1. In Body Measurement there were the significant differences with each constitution of man's circumference. 2. In Volume there were the significant differences between Taeumin and Soeumin in mand. And the volume rate of head and neck, hand, and foot was the lowest in Taeumin, but the highest in Soeumin. 3. In center of mass Soyangin was higher than others.

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Applications of the Fast Grain Boundary Model to Cosmochemistry (빠른 입계 확산 수치 모델의 우주화학에의 적용)

  • Changkun Park
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.3
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    • pp.199-212
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    • 2023
  • Diffusion is a powerful tool to understand geological processes recorded in terrestrial rocks as well as extraterrestrial materials. Since the diffusive exchange of elements or isotopes may have occurred differently in the solar nebula (high temperature and rapid cooling) and on the parent bodies (fluid-assisted thermal metamorphism at relatively low temperature), it is particularly important to model elemental or isotopic diffusion profiles within the mineral grains to better understand the evolution of the early solar system. A numerical model with the finite difference method for the fast grain boundary diffusion was established for the exchange of elements or isotopes between constituent minerals in a closed system. The fast grain boundary diffusion numerical model was applied to 1) 26Mg variation in plagioclase of an amoeboid olivine aggregate (AOA) from a CH chondrite and 2) Fe-Mg interdiffusion between chondrules, AOA, and matrix minerals in a CO chondrite. Equilibrium isotopic fractionation and equilibrium partitioning were also included in the numerical model, based on the assumption that equilibrium can be reached at the interfaces of mineral crystals. The numerical model showed that diffusion profiles observed in chondrite samples likely resulted from the diffusive exchange of elements or isotopes between the constituent minerals. This study also showed that the closure temperature is determined not only by the mineral with the slowest diffusivity in the system, but also strongly depends on the constituent mineral abundances.

Use of a Solution-Adaptive Grid (SAG) Method for the Solution of the Unsaturated Flow Equation (불포화 유동 방정식의 해를 위한 해적응격자법의 이용 연구)

  • Koo, Min-Ho
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.1
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    • pp.23-32
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    • 1999
  • A new numerical method using solution-adaptive grids (SAG) is developed to solve the Richards' equation (RE) for unsaturated flow in porous media. Using a grid generation technique, the SAG method automatically redistributes a fixed number of grid points during the flow process, so that more grid points are clustered in regions of large solution gradients. The method uses the coordinate transformation technique to employ a new transformed RE, which is solved with the standard finite difference method. The movement of grid points is incorporated into the transformed RE, and therefore all computation is performed on fixed grid points of the transformed domain without using any interpolation techniques. Thus, numerical difficulties arising from the movement of the wetting front during the infiltration process have been substantially overcome by the new method. Numerical experiments for an one-dimensional infiltration problem are presented to compare the SAG method to the modified Picard method using a fixed grid. Results show that accuracy of a SAG solution using 41 nodes is comparable with the solution of the fixed grid method using 201 nodes, while it requires only 50% of the CPU time. The global mass balance and the convergence of SAG solutions are strongly affected by the time step size (Δt) and the weighting parameter (${\gamma}$) used for generating solution-adaptive grids. Thus, the method requires automated readjustment of Δt and ${\gamma}$ to yield mass-conservative and convergent solutions, although it may increase computational costs. The method can be effective especially for simulating unsaturated flow and other transport problems involving the propagation of a sharp-front.

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