• Title/Summary/Keyword: 질량성분비

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Measurement of Oxygen Isotope Ratio in Water Vapor by using Tunable Diode Laser Absorption Spectroscopy(TDLAS) - II (다이오드레이저 흡수분광법을 이용한 수증기의 산소 동위원소 성분비 측정 - II)

  • Jung, Do-Young;Park, Sang-Eon;Kim, Jae-Woo;Ko, Kwang-Hoon;Im, Kwon;Jung, Eui-Chang;Kim, Chul-Joong
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.202-203
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    • 2003
  • 여러 가지 원소의 동위원소 성분 분석은 생물학, 화학, 환경학, 연대학, 기후학 연구에 있어서 중요한 정보를 제공하는 유용한 수단이다. 동위원소 성분비를 측정하는 방법으로는 가스 동위원소 질량분석기를 이용한 방법이 사용되어 왔지만, 최근 다이오드 레이저의 발달과 함께 다이오드레이저 흡수분광법(TDLAS)이 개발되어 사용되고 있다. TDLAS 방법의 경우 질량분석기를 이용하는 방법에서는 측정이 불가능한 동일질량 분자의 동위원소 성분비를 측정할 수 있다. (중략)

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GC/MS and its applications for the analysis of cosmetic produtcts (GC/MS와 화장품 분석의 응용)

  • 노경원
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.19 no.1
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    • pp.1-19
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    • 1993
  • Gas chromatography serves to separate the mixtures into its components, and mass spectrometer is used to analyzing of unknown compounds. But there are many problems the identification of horn compounds using by GC only. As this reason GC/MS a very powerful analyzing technique. Mass spectrometer consists of 1) inlet stem 2) ion source 3) Bass filter 4) detectors and 5) data system. There are two analyzing modes in the GC/MS, those are scan and SIM(selected ion mom toping) modes. Scan mode is used when analyzing unknown compounds and SIM mode al lows the mass spectrometer to detect specific compound with very high sensitivity. As GC/MS applications for the analysis of cosmetic products, volatile compounds in lotion, earn foundation and hair color, and carbon distribution of fatty acids in soap were performed. Also as a new sample pre-treatment technique, head space sampler/GC/MS introduced in order to analyze the volatile compounds in a toothpaste.

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Discharge Characteristics of Heavy Metals in Acid mine Drainage from the Abandoned Ilgwang Mine (일광 폐광산 갱내에서 유래된 산성광산배수의 중금속 유출특성)

  • Kang, Dong-Hwan;Kwon, Byung-Hyuk;Yu, Hun-Sun;Kim, Sun-Ok
    • The Journal of Engineering Geology
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    • v.20 no.1
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    • pp.79-87
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    • 2010
  • Field water qualities (temperature, pH, Eh, EC, DO) was monitored by 6 times March to September 2009 on background water (BW) and acid mine drainage (AMD0, AMD1, AMD2 and AMD3 points), and flow rate was measured on AMD0 point. Acid mine drainage flowed out from abandoned Ilgwang mine were high acid waters that lower than pH 3, and Eh component was ranged 400 to 600 mV. EC measured on acid mine drainage were higher over 10 times than background water, DO component was increased by reaction on the air during the water flow from AMD0 point to AMD4 point. Heavy metal concentrations in acid mine drainage were ordered Fe > Cu > Zn > Mn > As > Cd, and Fe concentration was highest for 81.870~474.30 mg/L. Monitoring periods measured maximum concentrations of heavy metals were May for As and Cd, June for Fe, July for Cu, Zn and Mn. The periods measured minimum concentrations were monitored April for Cd and Mn, September for Fe, Cu, Zn and As. Discharge mass of heavy metal components were calculated 53.44 kg for Fe, 6.25 kg for Cu, 5.26 kg for Zn, 2.13 kg for Mn, 0.14 kg for As and 0.04 kg for Cd, respectively. Total discharge mass of heavy metal components were calculated 67.26 kg for 1 day, and Fe component was taken 79% of total mass.

A Study on Mass Fractions of Individual Particles by SEM/EDX in Seoul Subway Stations (SEM/EDX를 이용한 서울시 지하철 역사 내 개별입자의 질량분율에 관한 연구)

  • 한근혁;김동술
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.249-250
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    • 2002
  • 입자상 물질은 호흡에 의해 폐 깊숙이 침착되어 인체에 피해를 줄 수 있다 같은 질량의 거대 및 미세 입자가 있을 경우, 입자의 크기가 작아짐에 따라 비표면적이 급속히 커지기 때문에 입자가 유해 중금속 성분을 함유하고 있을 경우 그 중금속의 농축 정도가 크다. 지하철 역사는 사람들이 가장 많이 생활하는 지하 공간중의 하나이며, 유동인구가 많아 입자상 물질의 발생이 심한 지역으로 외기에 비해 희석, 화산 공간이 크지 않기 때문에 역사 내 유해 환경 오염 물질의 영향과 관리 대책에 대한 연구가 진행되고 있다. (중략)

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Vibration Control of Offshore Platform using Tuned Mass Damper (동조질량감쇠기를 이용한 해양구조물의 진동제어)

  • Kim, Ju Myung;Lee, Gyu Won
    • Journal of Korean Society of Steel Construction
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    • v.16 no.1 s.68
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    • pp.73-79
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    • 2004
  • Tuned Mass Damper (TMD) was applied to control the vibration of an offshore structure due to ocean waves. The errors caused by the linearization of the fluid-structure interaction effect and the phenomena when using the linearized equation of motion in TMD design were analyzed. To determine the performance of TMD in controlling vibration, both regular waves with varying periods and irregular waves with different significant wave heights were used. When the offshore structure received regular waves with a period similar to the first natural period of structure. TMD performed well in terms of response reduction. Such was not the case for the other periods. however, In the case of irregular waves, TMD triggered the reduction of structural response for waves with relatively small significant wave height. For irregular waves with relatively big significant wave height, however, TMD did not show any control effect. Therefore, TMD is useful in reducing offshore structural vibration due to ambient waves, thereby helping secure fatigue life.

Conservation for the Seismic Models of Intake Tower with Nonlinear Behaviors and Fluid Structure Interaction (비선형거동과 구조물유체상호작용을 고려한 취수탑 내진모델의 보수성평가)

  • Lee, Gye-Hee;Lee, Myoung-Kyu;Hong, Kwan-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.17-24
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    • 2020
  • In this study, series of nonlinear seismic analysis were performed on a reinforced concrete intake tower surrounded by water. To consider the fluid effect around the structure, analysis models were composed using an added mass and CEL approach. At this time, the implicit method was used for the added mass model, and the explicit method was used for the fluid structure interaction model. The input motions were scaled to correspond to 500, 1000, and 2400 years return period of the same artificial earthquake. To estimate the counteractivity of the fluid coupled model, models without fluid effect were constructed and used as a reference. The material models of concrete and reinforcement were selected to consider the nonlinear behavior after yielding, and analysis were performed by ABAQUS. As results, in the acceleration response spectrum of the structure, it was found that the influence of the surrounding fluid reducing the peak frequency and magnitude corresponding to the fundamental frequency of the structure. However, the added mass model did not affect the peak value corresponding to the higher mode. The sectional moments were increased significantly in the case of the added mass model than those of the reference model. Especially, this amplification occurred largely for a small-sized earthquake response in which linear behavior is dominant. In the fluid structure interaction model, the sectional moment with a low frequency component amplifies compared to that of the reference model, but the sectional moment with a high requency component was not amplified. Based in these results, it was evaluated that the counteractivity of the additive mass model was greater than that of the fluid structure interaction model.

Characterization of Fragrances from Lilac Blossom by Gas Chromatography-Mass Spectrometry (GC-MS에 의한 라일락 꽃 향기 분석)

  • Kim, Nam-Sun;Lee, Dong-Sun
    • Analytical Science and Technology
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    • v.17 no.1
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    • pp.85-89
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    • 2004
  • Fragrance components of lilac (Syringa vulgaris) blossom have been characterized in this paper. The accurate characterization of fragrances collected from lilac blossom was carried out by solid-phase trapping-solvent extraction and gas chromatography-ion trap mass spectrometry. According to lilac species, the chemical compositions were significantly different. Benzaldehyde, phenylacetaldehyde, and ${\alpha}$-farnesene were found as the predominant component of white lilac blossom whereas benzaldehyde, ${\alpha}$-pinene, and ocimene were those of pale purple lilac. The enantiomeric analysis of ${\alpha}$-pinene in lilac blossom was found in the form of ( ).

A Study on the Characterization of PM$_{2.5}$, PM$_{10}$ Concentration at Asian and Non-Asian Dust in Asan Area (아산지역의 황사/비황사시 PM$_{2.5}$, PM$_{10}$ 농도특성에 관한 연구)

  • Chung, Jin-Do;Hwang, Seung-Min;Choi, Hee-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1111-1115
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    • 2008
  • The characterization of PM$_{2.5}$ and PM$_{10}$ concentration is considered by analysis of ionic and heavy metal component to measured suspended particle at atmosphere in Hoseo university of Asan area. The variation of concentration is studied at the periods of asian dust occured. In asian dust, the PM$_{2.5}$ ratio is decreased from 79.7% to 40.1%, whereas the size-classified mean concentration of suspended particle is increased largely. It is found that the PM$_{2.5}$ ratio is decreased relatively because the coarse particle is increased largely according to the analysis of the mass concentration to divide the fine and coarse particle on 2.1 $\mu$m basis. It is observed that the Ca$^{2+}$ion is about 40 magnifications and Na$^+$, SO$_4{^{2-}}$ ion is increased in sequence in coarse particle, whereas the variation of ionic concentration is slightly increased in the fine particle. Furthermore, Mn, Fe, Zn, and Al are increased in sequence as the result of heavy metal component analysis, and Al is shown the most increased as mass concentration.

Comparative analysis of volatile and non-volatile flavor compounds in rice paste made by α-amylase according to cultivars (α-amylase를 이용하여 제조한 쌀 페이스트의 품종에 따른 휘발성비휘발성 향미성분 비교분석)

  • Son, Eun Young;Kim, Hye Won;Kim, Sun Ah;Lee, Sang Mi;Paek, Se Hee;Kim, Sun Hee;Seo, Yong Ki;Park, Hye-Young;Oh, Sea-Kwan;Kim, Young-Suk
    • Journal of Applied Biological Chemistry
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    • v.60 no.3
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    • pp.283-291
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    • 2017
  • Rice that the half of population in the world eats as a staple food is mostly produced and consumed in Asia. However, its consumption is nowadays decreasing mainly due to diet diversity. Accordingly, some attempts are in demand to enhance the utilization of rice. In this study, profiling of volatile and non-volatile flavor components in rice pastes obtained by ${\alpha}$-amylase was performed and compared according to nine different rice cultivars domestically cultivated in Korea using gas chromatography-mass spectrometry combined by solid phase microextraction and gas chromatography-time of flight-mass spectrometry after a derivatization, respectively. In total, 46 volatile compounds identified included 6 alcohols, 6 aldehydes, 4 esters, 4 furan derivatives, 4 ketones, 1 acid, 1 sulfur-containing compound, 7 hydrocarbons, 5 aromatics and 8 terpenes. The non-volatile flavor components found were composed of 12 amino acids, 6 sugars and 4 sugar alcohols. In principal component analysis, rice paste samples could be discriminated according to cultivars on the score plots of volatile and non-volatile flavor compounds. In particular, some volatile compounds such as pentanal and 4,7-dimethylundecane could contribute to distinguish Senong 17 white and Senong 17 brown, whereas ethanol, 6-methylhep-5-en-2-one, and tridecane could be highly related to the discrimination of Iipum from other cultivars. Among non-volatile compounds, some amino acids such as glycine, serine and ${\gamma}$-aminobutyric acid and some sugars such as sucrose and fructose were mainly responsible for the discrimination of Danmi from the other cultivars. On the other hand, galactose, arabitol and mannose were more closely related to Senong 17 white than Senong 17 brown.

Analysis and Experiment on The Performance of an Autocascade Refrigeration System Using Carbon Dioxide As a Refrigerant (이산화탄소를 냉매로 사용하는 오토캐스케이드 냉동기의 성능에 관한 해석 및 실험)

  • 김성구;김민수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.5
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    • pp.411-421
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    • 2001
  • The purpose of this study is to investigate the performance of an autocascade refrigeration system by simulation and experiment using refrigerant mixtures of R744/134a and R744/290 as working fluid. Variations of mass flow rate of refrigerant, compressor work refrigeration capacity and COP with respect to mass fraction of R744/134a and R744/290 mixture were presented under different operating conditions. Performance test has been executed by ASRAE standard. Experimental results show as the composition of R744 in the refrigerant mixture increases, heating and coling capacity are enhanced, but COP trends to decrease. Experimental results are compared with those from the simulation.

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