• Title/Summary/Keyword: 질량감소량

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Evaluation of Mechanical Properties of Early-age Concrete Containing Electric Arc Furnace Oxidizing Slag (전기로 산화슬래그를 혼입한 초기재령 콘크리트의 역학적 특성 평가)

  • Kwon, Seung-Jun;Hwang, Sang-Hyeon;Lim, Hee-Seob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.93-100
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    • 2019
  • In this study, the mechanical properties of early-age concrete were evaluated by mixing the electric arc furnace oxidizing slag fine aggregate with 30% and 50% replacement ratio. Slump test, air content test and unit volume weight test were performed for fresh concrete, and compressive strength test and chloride penetration experiments were carried out in hardened concrete. The compressive strength increased up to 7 days of curing age with increasing replacement ratio of the electric furnace oxidizing slag, but the strength decreased to 90% level of OPC concrete at 28 days of age. Regarding the result of chloride penetration test, no significant differences from OPC concrete were evaluated, which shows a feasibility of application to concrete aggregate.

Thermal Decomposition Behavior of Boron-Potassium Nitrate (BKNO3) by TGA (열중량분석법에 의한 Boron-Potassium Nitrate(BKNO3)의 열분해 특성 연구)

  • Go, Cheongah;Kim, Junhyung;Park, Youngchul;Moon, Youngtaek;Seo, Taeseok;Ryu, Byungtae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.104-110
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    • 2019
  • The thermal decomposition characteristics of boron-potassium nitrate ($BKNO_3$) were investigated by non-isothermal thermal gravimetric analysis (TGA). Two steps of mass loss were observed in the temperature range between room temperature and $600^{\circ}C$. Kinetic parameters of the thermal decompositions were evaluated from the measured TGA curves using the AKTS Thermokinetics Software. For the first step of mass loss ($220-360^{\circ}C$) corresponding to the thermal decomposition process of the binder (Laminac/Lupersol), the activation energy is in the range of approximately 120-270 kJ/mol when evaluated by Friedman's iso-conversional method, while the value of activation energy varies in the range of approximately 150-400 kJ/mol during the second step process ($360-550^{\circ}C$).

Correlation between Charged Silicon Nanoparticles in the Gas Phase and the Low Temperature Deposition of Crystalline Silicon Films during Hot Wire Chemical Vapor Deposition

  • Yu, Seung-Wan;Hong, Ju-Seop;Kim, Jeong-Hyeong;Yu, Sin-Jae;Hwang, Nong-Mun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.283.2-283.2
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    • 2014
  • 열필라멘트 화학증착공정(Hot Wire Chemical Vapor Deposition)에서 기상 에서 생성되는 하전된 실리콘 나노입자와 저온결정성 실리콘박막 증착의 연관성을 압력의 변화에 따른 상호비교를 통해 조사하였다. 필라멘트 온도는 $1800^{\circ}C$로 고정시키고 0.3~2 torr의 범위에서 공정 압력을 변화시키면서 증착하였다. 압력이 증가함에 따라 증착된 실리콘 박막의 결정화도는 증가하였으며, 증착속도는 감소하였다. 반응기 압력에 따른 기상에서 생성되는 나노입자의 크기분포의 변화를 조사하기 위하여 탄소막이 코팅된 투과전자현미경(Transmission Electron Microscopy) 그리드 위에 실리콘 나노입자를 포획하고 관찰하였다. 포획된 실리콘 나노입자의 크기분포와 개수농도는 압력이 증가함에 따라 감소하였다. 투과전자현미경을 이용하여 분석한 결과, 나노입자는 결정성 구조를 보였다. 압력이 증가함에 따라 나노입자의 크기가 감소하고 개수농도가 감소하는 것은 증착속도의 감소와 관련됨을 알 수 있다. 한편, 공정압력 증가에 따른 나노입자의 크기분포 및 개수농도 감소와 증착속도의 감소는 일반적으로 알려진 기상에서 석출하는 고상의 평형석출량(equilibrium amount of precipitation)이 압력의 증가함에 따라 증가한다는 사실과 일치하지 않는다. 이러한 압력경향성은 Si-H 시스템이 0.3~2 torr의 압력 영역에서 retrograde solubility를 갖는 것을 의미한다. 나노입자의 하전여부, 크기분포 및 개수농도를 측정하기 위하여 입자빔질량분석장비(Particle Beam Mass Spectroscopy)를 이용하였다. 그 결과, 실리콘 나노입자는 양 또는 음의 극성을 가진 하전된 상태임을 확인하였고, 투과전자현미경(TEM) grid에 포획한 실리콘 나노입자의 크기와 경향성이 일치하였다. 이는 나노입자가 저온의 기판에서 핵생성되어 성장하여 생성된 것이 아니라 열필라멘트 주위의 고온영역에서 생성된 것을 의미한다.

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Effect of Bambusae Caulis in Liquamen on Lipid Metabolism in Rats Fed High Fat Diet (죽력(Bambusae Caulis in Liquamen)이 고지방식이를 급여한 흰쥐의 체내 지질대사에 미치는 영향)

  • Choi Hyun-Sook;Ha Jin-Ok;Choo Myung-Hi;Na Myung-Soon;Lee Myung-Yul
    • Food Science and Preservation
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    • v.11 no.3
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    • pp.373-382
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    • 2004
  • The purposes of this study were to investigate effects of Bambusae Caulis in Liquamen(BCL) on antioxidant activities and inhibitory activities of HMG-CoA reductase of in vitro, and lipid metabolism in rats fed the high cholesterol diet in vivo. Sprague-Dawley male rats weighing l00$\pm$10 g were devided into five groups ; normal group(NOR), the high cholesterol diet administered group(1 $\%$ cholesterol and 0.25$\%$ sodium cholate)(CON), 5$\%$ BCL administered group (5BL), the high cholesterol diet and 5$\%$ BCL administered group (5BCB) and the high cholesterol diet and 10\$\%$ BCL administered group (10BCB), respectively. In antioxidative activities of BCL using Rancimat in vitro, 1.25 diulent and original solution were more excellent activities than the control group, and in inhibiting activities of HMG-CoA reductase, BCL was shown inhibitory effects compared with the control, in dose dependent manners, especially 57.9$\%$ in original solution and 36.0$\%$ in 1.25 diulent. The growth rate of the control group was higher than the normal group, wheras the group given 5$\%$ BCL and 10$\%$ BCL were gradually decreased, especially the most excellent effect in 10$\%$ BCL. Serum levels of total cholesterol, LDL-cholesterol, triglyceride and free cholesterol were significantly decreased, whereas levels of HDL-cholesterol and phospholipid were increased, but not significantly. BCL administered group was increased in HDL-cholesterol/total cholesterol ratio and lowered antherogenic index. The activities of AST in serum were rather lowered in the BCL administration group than the cholesterol diet group, but not in ALT and ALP. The hepatic contents of total cholesterol were lowered significantly than control group, but not in triglyceride. Therefore, it might be expected that BCL is believed to be a possible protective or curative effects for fatty livers and hyperlipidemia-induced by a hi~h cholesterol diet.

An Experimental Study on the Property of the Concrete with Glass Hollow Micro Sphere (유리질중공미소구체를 사용한 콘크리트의 특성에 관한 실험적 연구)

  • Kim, Sang-Heon;Kim, Se-Hwan;Park, Young-Shin;Jeon, Hyun-Gyu;Seo, Chee-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.160-166
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    • 2014
  • In this research, as a measure of reducing energy lost through external wall, we used Glass Hollow Micro Sphere (HMS) to improve insulation performance to structural concrete. The following is a result of experimenting concrete using HMS. As usage of HMS, decrease in slump arose and it is judged as a need of using superplasticizer. Replacement ratio increasing more and more, amount of air showed tendency to decrease and compressive strength decreased for interfacial adhesion had not been formed. as replacement ratio and unit volume decreased. It appears that thermal conductivity decreased about 30.0~46.5 percent as compared with normal weight concrete.

PWR 사용후핵연료 건식 저장 시설의 연소도 크레디트에 관한 연구

  • Gang, Gyeong-Min;Je, Mu-Seong;Jeong, Jae-Hak
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2006.11a
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    • pp.87-88
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    • 2006
  • 사용후 핵연료용 수송용기의 설계 안전평가에서는 이제까지 용기에 수납되는 연료는 미조사, 즉 신연료라 가정해서 보수적으로 임계안전설계를 수행하여 왔다. 이것은 연소에 따른 연료내의 핵연료 물질의 감손 및 생성의 의한 반응도의 변동을 계산 평가하는 것이나 또는 연소로 인해 생성되는 중성자 흡수 핵종의 조성 및 함유량 등을 정확히 계산 평가하는 것이 복잡해서 곤란했던 것으로 그 요인을 들 수 있다. 사용 후 핵연료를 신 연료로 가정하는 등의 불합리성을 해소하고, 안전성을 잃지 않고 사용 후 핵연료 운반용기 들의 경제성을 추구하는 기운이 높아지고, 관련 연구가 적극적으로 진척되게 되었다. 그 결과 연소에 따른 연료내의 핵연료 물질의 감손 생성과 핵분열 생성물 등에 의한 반응도의 저하, 즉 중성자 실효 증배율의 저하를 고려한 것을 사용 후 핵연료용 캐스크 설계 안전평가에 취할 수 있게 되었다. 연소도 크레디트를 채용함으로서 사용후 핵연료내의 핵연료물질량은 실제로 존재하는 양을 사용하는 것이 되므로 초기 농축도가 높은 고연소도 연료에서 그 효과가 보다 크게 될 것이다. 이것은 연소도 크레디트 채용에 따라 연료 바스켓의 중성자흡수제 사용량 감소가 가능해져 사용 캐스크의 수를 줄일 수 있어 경제성 향상이 기대되고 아울러 그이 취급 횟수 및 수송횟수가 감소됨에 따라 안전성의 향상도 기대된다.

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Combustion Characteristics of Pool Fire by Height of Fire Source (화점높이 변화에 따른 Pool Fire의 연소특성)

  • Park, Hyung-Ju;Cha, Jong-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4671-4676
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    • 2010
  • This study is intended to understand flame behavior of the pool fire by height of fire source. Liquid fuels were methanol and n-Heptane which are used in many studies of pool fire. Size of vessel was $100mm{\times}100mm{\times}50mm$ and the vessel was made by stainless steel. Combustion time, mass loss rate, flame temperature, flame height and air entrainment rate from the outside to flame were measured, and flame behavior was visualized with video camera. Based on the experiment, it was found that combustion characteristics of pool fire was decreased according to increase of height of fire source because entrainment volume of relative cold air was increased from the outside to flame.

Influence of Alkali Activator Type and Amount of Addition on CO2 Uptake of GGBFS Geopolymer Pastes Containing Zeolite (알칼리계 활성화제의 종류 및 첨가량이 고로슬래그-제올라이트 지오폴리머 페이스트의 탄소포집에 미치는 영향에 관한 연구)

  • Jang-Hyun Park;Hyo-Min Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.112-119
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    • 2023
  • In this study, the variations in CO2 uptake according to the type and amount of alkali-based activator (Ca(OH)2, CSA) of geopolymer paste were evaluated. As the amount of activator added to the geopolymer paste increased, the fluidity of the paste is decreased and the compressive strength increased. According to the type of activator, it was confirmed that the addition of Ca(OH)2 had a greater effect on improving the compressive strength than CSA. As a result of changes in chemical properties according to carbonation curing, the amount of C-S-H and C-A-S-H gels produced before carbonation increased as the amount of activator increased, and amount of CaCO3 produced after carbonation increased. The reactivity of the blast furnace slag and zeolite increased due to the addition of the activator, and the reactivity tended to increase as the amount of addition increased. As a result of CO2 uptake, 10.3 wt% when Ca(OH)2 10 % was added and 8.77 wt% when CSA 10 % was added was confirmed. It increased by 421 % and 388 % respectively, compared to the case where no activator was added.

Analysis of the Long-Range Transport Contribution to PM10 in Korea Based on the Variations of Anthropogenic Emissions in East Asia using WRF-Chem (WRF-Chem 모델을 활용한 동아시아의 인위적 배출량 변동에 따른 한국 미세 먼지 장거리 수송 기여도 분석)

  • Lee, Hyae-Jin;Cho, Jae-Hee
    • Journal of the Korean earth science society
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    • v.43 no.2
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    • pp.283-302
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    • 2022
  • Despite the nationwide COVID-19 lockdown in China since January 23, 2020, haze days with high PM10 levels of 88-98 ㎍ m-3 occurred on February 1 and 2, 2020. During these haze days, the East Asian region was affected by a warm and stagnant air mass with positive air temperature anomalies and negative zonal wind anomalies at 850 hPa. The Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) was used to analyze the variation of regional PM10 aerosol transport in Korea due to decreased anthropogenic emissions in East Asia. The base experiment (BASE), which applies the basic anthropogenic emissions in the WRF-Chem model, and the control experiment (CTL) applied by reducing the anthropogenic emission to 50%, were used to assess uncertainty with ground-based PM10 measurements in Korea. The index of agreement (IOA) for the CTL simulation was 0.71, which was higher than that of BASE (0.67). A statistical analysis of the results suggests that anthropogenic emissions were reduced during the COVID-19 lockdown period in China. Furthermore, BASE and CTL applied to zero-out anthropogenic emissions outside Korea (BASE_ZEOK and CTL_ZEOK) were used to analyze the variations of regional PM10 aerosol transport in Korea. Regional PM10 transport in CTL was reduced by only 10-20% compared to BASE. Synthetic weather variables may be another reason for the non-linear response to changes in the contribution of regional transport to PM10 in Korea with the reduction of anthropogenic emissions in East Asia. Although the regional transport contribution of other inorganic aerosols was high in CTL (80-90%), sulfate-nitrate-ammonium (SNA) aerosols showed lower contributions of 0-20%, 30-60%, and 30-60%, respectively. The SNA secondary aerosols, particularly nitrates, presumably declined as the Chinese lockdown induced traffic.

Properties of Ternary or Quaternary High Strength Concrete Using Silica Fume & Meta Kaolin (실리카퓸과 메타카올린을 사용한 다성분계 고강도콘크리트의 특성)

  • Park, Cho-Bum;Kim, Ho-Su;Jeon, Jun-Young;Kim, Eun-Kyum;Ryu, Deug-Hyun
    • Journal of the Korea Concrete Institute
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    • v.20 no.3
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    • pp.307-315
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    • 2008
  • In this study, it is investigated the properties of high strength concrete using mineral admixture, on the purpose of use of meta kaolin for the substitutive materials to silica fume which is so expensive. The plain mixtures are 3 degrees which are ordinary portland cement, blast furnace slag cement and OPC included fly ash 20%, and silica fume and meta kaolin are substituted for the each plain mixtures in the range of 20%. The results of experiment showed as follows. In case of silica fume was only used, the viscosity and slump flow of fresh concrete were much decreased, on the contrary air content increased. But as usage of meta kaolin increased, to being increase the viscosity of fresh concrete, slump flow increased and air content and usage of super-plasticizer were decreased. Accordingly the workabilities of concrete were against tendency between silica fume and meta kaolin. The compressive strength, velocity of ultrasonic pulse and unit weight were increased according to usage of meta kaolin, the properties of hardened concrete were judged that they are affected with air content of fresh concrete, so it is very important to control air content of high strength concrete. Therefore, the use of meta kaolin is prospected to the substitutive material of silica fume, in case of using silica fume and meta kaolin, it is judged that the optimum usage of silica fume and meta kaolin is about 10% respectively, considering workability and strength of concrete.