• Title/Summary/Keyword: 지화학적 자료

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Characteristics of Metal Distribution in the Sediment in Kyeonggi Bay, Korea (경기만 퇴적물의 중금속 분포 특성)

  • Lee, Jong-Hyeon;Yi, Jung-Suk;Kim, Bum-Su;Lee, Chang-Bok;Koh, Chul-Hwan
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.3 no.3
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    • pp.103-111
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    • 1998
  • This paper reports the sediment geochemistry and its relation to the grain size distribution in Kyeonggi Bay, Korea. Sediment samples were collected from 90 stations during the cruise crossing the bay in December 1995. Variables investigated were the sediment grain size, organic carbon content, and concentrations of AI, Fe, Mn, V, Co, Ni, Cr, Zn and Cu in the sediment. We followed the change in these variables by comparing the data obtained from this region in 1981. Distribution pattern of sediment grain size was modified from that in 1981 in some places. Near the Shihwa Dike which was completed in 1994, sediment had got finer grained. Sediment facies changed from fine to mixed facies near Youngjong Island where the tidal flat has been reclaimed for airport construction. Contents of organic matter and metals in the sediment were mostly dependent upon the sediment grain size, but an exception was found in the harbor area. The sediment in the Incheon North Harbor showed higher accumulation of organic matter and metals such as Ni, Cr, Zn and Cu.

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Geochemical Comparison Study on the Amphibolite in the Central Gyeonggi massif and Southeastern Okcheon metamorphic belt (중부 경기육괴와 동남부 옥천변성대의 각섬암에 대한 지화학적 비교 연구)

  • Na Ki Chang;Cheong Won Seok
    • The Journal of the Petrological Society of Korea
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    • v.13 no.4
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    • pp.201-213
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    • 2004
  • The Precambrian amphibolites in the central Gyeonggi massif, Yangsuri, Gyeonggido and southeastern Okcheon metamophic belt, Mungyeonggun, Gyeongsangbukdo, Korea, were studied on the geochemical characteristics of major and trace elements, and discussed petrogenetically and geotectonically. The characteristics of major elements of the amphibolites in these study areas are igeous origin such as tholeiitic-, subalkaline and alkaline basalt. Geotectonic distinction diagrams of trace elements such as Ti-Zr-Y and Zr-Nb-Y show basaltic igneous activity of island arc and mid ocean ridge environment at central Gyunggi massif, and within plate environment at southeastern Okcheon metamorphic belt. This result shows that genetic environments of study areas are different. Especially, origin of amphibolites in central Gyeonggi massif is similar with that of western Gyeonggi massif but different with the amphibolites of Chuncheon area. Genetic environment estimated of fractional crystallization of plagioclase has no particular effect on the origin of magma because value of LREE is higher than that of HREE and Eu anomaly definitely don't be exposed.

Rb-Sr Isotopic Ages of Biotite in the Weathering Profile of Granodiorite, Yecheon (예천지역 화강섬록암 풍화대내 흑운모의 Rb-Sr 동위원소연대 변화)

  • Jeong Gi Young;Cheong Chang-Sik;Lee Bong Ho
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.1
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    • pp.53-59
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    • 2005
  • Rb-Sr isotopic ages of oxidized biotite in the weathering profile of granodiorite, Yecheon area, were measured by thermal ionization mass spectrometry, and compared with their K-Ar ages. A decrease of Rb-Sr isotopic age is well correlated with iron oxidation, and consistent with K-Ar age. Octahedral and interlayer cations including Rb and Sr were partly released from the oxidizing biotite by excess positive charge from iron oxidation. Divalent /sup 87/Sr decayed from monovalent /sup 87/Rb was more easily released from biotite, resulting in the reduction of Rb-Sr isotopic age. Weathered biotite is not suitable for the age dating of parent rocks, but behaviour of radiogenic isotopes provides useful information on the geochemical and structural changes of biotite during weathering.

Stratigraphic Implication of the Daljeon Basalt in the Miocene Pohang Basin, SE Korea (한반도 동남부 마이오세 포항분지 내 달전현무암의 층서적 의미)

  • Song, Cheol Woo;Kim, Hyeonjeong;Kim, Jong-Sun;Kim, Min-Cheol;Son, Moon
    • The Journal of the Petrological Society of Korea
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    • v.24 no.4
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    • pp.323-335
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    • 2015
  • Although the Daljeon Basalt in the Pohang Basin is important for interpreting the basin evolution, its relative chronology, stratigraphic position, and isotopic age still remain controversial. In order to clear up the controversies, this study carried out detailed field investigation to determine its distribution and occurrence together with reanalysis of its previous geochemical data and $^{40}Ar/^{39}Ar$ age dating. Based upon the field investigation, the basalt occurring in the central part of the Pohang basin is composed of three main bodies and a dozen of minor dikes and sills that intruded into the Yeonil Group. Their mineral assemblages consist of phenocrysts such as olivine and clinopyroxene and fine groundmasses of clinopyroxene, plagioclase, olivine, and opaque oxide, impling the porphyritic texture of alkaline basalt. All their geochemical data also show the similar geochemical characteristics in TAS, Zr-Ti, and REE/trace elements distribution diagrams. The samples are plotted on alkalic field in the total alkali-versus-silica diagram and show similar patterns to enrichment oceanic basalt or within plate basalt in trace elements. In addition, $^{40}Ar/^{39}Ar$ isochron age of 13.82Ma is obtained. These results indicate that the Daljeon Basalt is an alkaline intrusive rock belonging to the middle Miocene Yeonil Group.

Petrology and Amphibolites(Meta-Dolerite sill) in the Mungyong Areal Korea (문경지역에 분포하는 각섬암(변성조립현무암)에 대한 암석학적연구)

  • Ahn, Kun-Sang;Shin, In-Hyun;Kim, Hee-Nam
    • Journal of the Korean earth science society
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    • v.18 no.6
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    • pp.500-514
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    • 1997
  • With respect to the amphibolites in the Mungyong area of the central part of the Ogcheon Fold Belt, detail field occurrence, texture and geochemical properties within each sills and petrogenetic environment are presented. We confirmed that the amphibolites in the Sangnaeri Formation (Ogcheon Supergroup) and limestone(Cambro-Ordovician Chosun Supergroup) sequences are metamorphosed dolerite sills which are roughly concordant to bedding of country rocks. Geologic distribution of the rocks is distinctly improved compared with those of previous investigations. There are four main sills so far observed in the study area. One is emplaced in limestone(Ls Sill, about 3 m thick) and the others are emplaced in Sangnaeri Formation, which are named First Sill(about 40 m thick), Second Sill(about 100 m thick) and Third Sill(about 40 m thick) from lower to upper horizons of the meta-pelitic sequences. The thick sills are intruded by minor sills and the Third Sill is a composite sill consisting of two main and two minor sills. Each sill has fine grained chilled marginal zones and grain size increases inwards from both contacts. The Second Sill has various vein and white patch in central part and the rock compositions vary systematically from margin to central part. $SiO_2,\;Na_2O,\;K_2O\;and\;P_2O_5$ increase, whereas $TiO_2,\;FeO,\;Al_2O_3\;and\;CaO$ decrease toward the contort. We investigate the major and trace element variations of ten selected rock compositions as intruding initial magma take occurrence and chemical properties into consideration. The compositional variations of them can not be explained by fractionation crystallization of single magma. Geologic distribution, geochemical properties and previous data suggest that amphibolite precursors(basaltic magma) of the study area were intrusive as sill-like in an intracontinental rift environment.

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Theoretical Background for Data-driven Integration of Raster-based Geological Information (격자형 지질정보의 자료유도 통합을 위한 이론적 배경)

  • Lee, Ki-Won;Chi, Kwang-Hoon
    • Journal of Korean Society for Geospatial Information Science
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    • v.3 no.1 s.5
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    • pp.115-121
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    • 1995
  • Recently, spatial integration for mineral exploration is regarded as an important task of various geological applications of GIS. Therefore, theoretical bases of data representation and reasoning concerned with Dempster-Shafer theory and Fuzzy theory were systematically as the data-driven integration methodologies for raster-based geoinformation; they are distinguished from target-driven methodology based on statistical background. According to previous actual applications of these methods to mineral exploration, they have been proven to provide useful information related to hidden target mineral deposits, and it is thought that some suggestions in this study are helpful to further real applications including representation, reasoning, and interpretation stages in order to obtain a decision-supporting layer.

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Variations of Clay Mineral Assemblage, Colour, and Microfossil Abundance in the Tertiary Sediments from the Pohang Area During Chemical Weathering (포항지역(浦項地域) 제(第)3기층(紀層) 퇴적암(堆積岩)중 화학적풍화작용(化學的風化作用)이 결토광물조성(結土鑛物組成), 화학조성(化學組成), 암색(岩色) 및 미화석(微化石) 산출빈도(産出頻度)에 미치는 영향)

  • Moon, Hi-Soo;Yun, Hyesu;Min, Kyung Duck;Lee, Hyun Koo;Lee, Jong Chun
    • Economic and Environmental Geology
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    • v.23 no.2
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    • pp.201-213
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    • 1990
  • Mineralogy, chemistry, physical property, and fossil abundance have been studied for the samples collected from three weathering profiles, two from the Duho Formation and one from the Hagjeon Formation in the Tertiary sediments in the Pohang area. The mineralogy of the samples from the Duho Formation shows somewhat different from that of the Hagjeon Formation. Kaolinite is more abundant and shows higher crystallinity in samples from the Duho Formation than those in the Hagjeon Formation, but clay mineral assemblage in each weathering profile remain fairly constant with depth. This difference in mineral distribution seems to be inherited from original source materials. It indicates that little or not severe leaching has been taking place in these three weathering profiles. Weathering indicies indicate different degrees of susceptibility to chemical weathering in these two formations. The Duho Formation has a higher degree of susceptibility to weathering than that of the Hagjeon Formation which is mainly due to differences in clay mineral assemblages in both formations. A noticeble colour difference between oxidized and unoxidized zones in each profile can be easily recognized which is definetely due to different decomposition rate organic carbon by various oxidation state from surface to bottom of the profile. Weathering process have also intensively influenced microfossil preservation about up to 7-10 m in depth in the Duho Formation. Consequently, characteristics observed at weathering surface should be used as a subsidiary tool in setting geologic boundary or establishing formation. Great care must be taken to choose sampling site for microfossil study.

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Hydrothermal Gold mineralization of the trabong district, vietnam : Mineralogical and geochemical study (베트남 짜봉(Trabong) 지역의 열수 금 광화작용 : 광물 및 지화학적 연구)

  • 한진경
    • Economic and Environmental Geology
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    • v.32 no.2
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    • pp.129-139
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    • 1999
  • Hydrothermal gold deposits of the Trabong district in Vietnam occur as single-stage quartz $\pm$ calcite veins (0.3-1.2 m thick) which fill fault fractures in graphite-bearing gneiss and schist of the Chulai Complex and Kham Duc Formation of the Proterozoic age. Ore grades are 1.3 to 92.4 g/ton Au. Ore mineralogy is very simple, consisting mainly of pyrite with minor amounts of base-metal sulfides and electrum. Gold grains occur in two assemblages as follows: (1) early, Fe-rich (7.2-10.4 mole % FeS) sphalerite + electrum (50.4-64.3 atom % Au) assemblage occurring as inclusions in pyrite; (2) late, Fe-poor «4.7 mole % FeS) sphalerite + galena + electrum (47.6-81.7 atom % Au) assemblage occurring along fractures of pyrites. Based on fluid inclusion data and thermochemical considerations of ore mineral assemblages, ore minerals were formed at high temperatures (about $230^{\circ}C$ to $420^{\circ}C$) from $H_{2}O-CO_{2}(-CH_{4})$-NaCI fluids with the sulfur fugacity of about $10^{-6}$ to $10^{-10}$ atm. Fluid inclusion data also indicate that ore mineralization occurred mainly as a result of fluid unmixing accompanying $CO_2$ effervescence. Calculated oxygen and measured hydrogen isotope compositions of mineralizing waters (${\delta}^{18}O_{V-SMOW}$ values = 5.3 to 8.6$\textperthousand$, ${\delta}D_{V-SMOW}$ values = - 60 to - 52$\textperthousand$), along with the sulfur isotope compositions of vein sulfides (${\delta}^{34}S_{CDR}$ values = - 1.2 to 2.8$\textperthousand$) and carbon isotope compositions of inclusion $CO_2$ (${\delta}^{13}C_{PDB}$ values = - 4.7 to - 2.0$\textperthousand$) indicate that the high temperature (mesohypothermal) gold mineralization formed from a magmatic fluid.

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Geochemical Characteristics of Geothermal Water and Groundwater in the Dongrae Hot-Spring Area (동래온천지역의 지열수와 지하수의 지화학적 특성)

  • Suck Jong Han;Se-Yeong Hamm;Ig Hwan Sung;Byeong Dae Lee;Byong Wook Cho;Myong Hee Cho
    • The Journal of Engineering Geology
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    • v.9 no.3
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    • pp.207-225
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    • 1999
  • Twenty water samples (eleven groundwater and nine geothermal water samples) were collected to elucidate hydrogeochemical characteristics of the groundwater and geothermal water in the Dongrae hot-spring area and its vicinity. Major and minor elements were analyzed for ground and geothermal water samples. Physicochemical properties of the groundwater and the geothermal water were examined and chemical composition of the two waters were compared. Factor and correlation analyses were carried out to simplify the physicochemical data into grouping some factors and to find interaction between them. The groundwaters belong to $Ca-HCO_3$ type, while the geothermal waters belong to Na-Cl type. The Na and Cl concentrations in the Dongrae hot-spring area are higher than those of other granite areas in South Korea. The Na/Cl weight ratio ranges from 0.7 to 1.3 for the geothermal waters. On the phase stability diagram groundwaters fall effectively in the field of stability of kaolinite, while geothermal waters fall in the stability field of microcline or kolinite depending on the chemical composition system. Based on the Na-K, Na-K-Ca and Na-K-Ca-Mg geothermometers, the geothermal reservoir is estimated to have equilibrium temperature between 115 and $145^{\circ}C$.

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Investigation on Natural Radioactivity of Environmental Samples Near the Bauxite Processing Facility (보오크사이트 사용업체 주변 환경시료의 자연방사능 조사)

  • Moon, Dong-Hyeok;Koh, Sang-Mo;Chang, Byung-Uck;Kim, Tong-Kwon;Kim, Yong-Ug
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.347-356
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    • 2010
  • Bauxite is a main raw material for the production of alumina and aluminum hydroxide in the processing plant of KC company. It is a NORM (Naturally Occurring Radioactive Materials), and its waste, red mud, is a TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials). The purpose of the geochemical and mineralogical investigations of the bedrock and soils in and around the plant, a large NORM source, was to provide basic data for measuring the radiation dose and protecting from radioactive hazards. Soils were mixtures of minerals derived from the country rock (quartz, feldspar, mica, kaolin, gibbsite, and sepiolite) and bauxite (hematite, boehmite, and calcite) of open-air storage. Average U and Th contents of the soil samples were 4.7 ppm and 23 ppm, respectively, indicating somewhat Th anomaly. The average concentrations of radionuclides are $^{40}K$ 100~1,433 Bq/kg, $^{226}Ra$ anomaly in the red mud open-air storage. Soil external hazard indices range from 0.10 to 1.66 with an average of 0.63. Although most of the indices are below 1.0 that is a regulation value, those of 4 samples of total 41 soil samples exceed 1.0, requiring further detailed investigation.