• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.597-600
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• 2003

용인시 백암취수장 주변 지역의 지하수에 대해 기초적인 지화학적 조사를 수행하였다. 현장측정자료에서는 취수정의 pH와 EC값이 주변지하수보다 지표수와 유사한 값을 보이며, 취수정의 용존산소(DO) 함량이 천층지하수보다 높은 값을 보인다. 더구나 취수정의 경우 NO$_3$함량이 10.5-12.1 mg/L이며 주변 지하수는 7.2-25.3 mg/L, 지표수는 13.1-14.9 mg/L로서 취수정의 설치심도가 70-180m로서 상대적으로 깊은 암반층에 설치되어 있다 하더라도 주변지하수 및 인접 지표수의 혼입에 의해 영향을 받아 오염이 진행되고 있음을 알 수 있다. 이와 같이 연구 지역은 현재 취수정이 모두 청미천변에 위치하고 있어서, 현재 암반 지하수로 개발하고 있는 취수정 지하수가 주변 천부지하수 및 지표수에 의한 혼입 및 오염가능성이 높기 때문에, 앞으로 장기적인 모니터링 및 지화학적 연구가 지속적으로 이루어 져야 할 것으로 사료된다.

• Journal of the Korean Geographical Society
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• v.45 no.5
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• pp.541-552
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• 2010

Geochemical and physical investigations such as ${\delta}^{13}C$ isotope ratio, carbon/nitrogen (C/N) ratio, magnetic susceptibility (MS), and particle size analyses were carried out on the estuarine tidal flat sediments from the west coast of Korea in order to reconstruct the East Asian summer monsoon variability during the late Pleistocene and Holocene Our results indicated that the summer monsoon probably peaked around 7,700-7,800 yr BP and then started to decline about 7,400 yr BP in the Korean peninsular, and that the monsoon was relatively weak between 24,000-24,500 yr BP but relatively strong between 18,500-19,500 yr BP during the Last Glacial Maximum. Our estuarine geochemical data have proven to be valuable as a new proxy for detecting the shifts in monsoon strength. This new evidence will be helpful, especially for Korean paleoenvironmental studies with few proxy data archives.

• The Journal of the Petrological Society of Korea
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• v.11 no.3_4
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• pp.182-199
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• 2002

We attempted to show the evolution of the magma and the geochemical characteristics of dikes and dike swarms by using the petrographic and geochemical data from 287 dikes, SE Korea. The dikes can be divided into mafic, intermediate, and felsic dikes in the field. And each of them is subdivided into three groups, two groups, and two groups, respectively. The group (I) among the mafic dikes most pervasively occurs and are distributed in both sides of the Yeonil Tectonic Line (YIL), which petrographic and geochemical characteristics are the same. These facts thus, strongly support the results of the previous studies which showed that they were intruded contemporaneously and that YTL was a main tectonic line which restricted the crustal clockwise rotation during the Early Miocene. The geochemical characteristics are discriminated according to the seven groups divided petrographically. The mafic, intermediate and felsic dikes belong to basalt and basaltic andesite, andesite and facile, and rhyolite, respectively, and the magmas mostly belong to calc-alkaline series. The geochemical data indicate that there were the fractional crystallizations of olivine, clinopyroxene, and plagioclase in the mafic dikes. And the content of characteristic elements and tectonic discrimination diagrams show that the dikes were formed from the magma related to the subduction of plate and that the tectonic setting was related to orogenic volcanic arc.

• Economic and Environmental Geology
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• v.34 no.3
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• pp.255-269
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• 2001

The geochemical studies on groundwater in the borehole, which is straddled by multi-packer (MP) system, were carried out from a volcanic terrain in the Yeosu area. The pH of groundwater collected from selected sections in the MP-installed borehole is much higher (up to 9.6) than that of the borehole groundwater (7.0-7.9) collected using conventional pumping technique. Hydrochemistry shows that the groundwater has a typical chemical change with increasing sampling depth, suggesting that the groundwater is evolved through water-rock interaction along the fracture-controlled flow paths. The groundwater from the deeper part (138-175 m below the surface) in borehole KI is characterized by the Ca-C11 type with high Ca (up to 160 mg/L) and Cl (up to 293 mg/L) contents, probably reflecting seawater intrusion. The groundwater also has high sodium and sulfate contents compared to the waters from other boreholes. These observed groundwater chemistry is explained by the cation exchange, sulfide oxidation, and mixing process with seawater along the flow path.

• The Journal of the Petrological Society of Korea
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• v.13 no.1
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• pp.16-33
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• 2004

By relating mineralogy, petrology and geochemistry to observed magnetic properties, an understanding of the geological factors that control magnetic signatures is obtained. Magnetic susceptibility measurements and geochemical analyses were carried out for 160 samples in the Jurassic to Cretaceous granitoids, which is distributed to Pocheon, Jipori, Geumsan, Namwon, Songnisan, Yongdam, Masan, Jindong, and Taebaeksan areas. The magnetic properties of igneous infusion in these granites reflect bulk rock composition, reduction-oxidation state, hydrothermal alteration which are controlled by tectonic setting, composition and history of the source region, depth of emplacement and nature of wall rocks.

• Journal of the Korean earth science society
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• v.31 no.4
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• pp.301-312
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• 2010

Geochemical data have been regarded as one of the important environmental variables in the environmental management. Since they are often sampled at sparse locations, it is important not only to predict attribute values at unsampled locations, but also to assess the uncertainty attached to the prediction for further analysis. The main objective of this paper is to exemplify how indicator geostatistics can be effectively applied to geochemical data processing for providing decision-supporting information as well as spatial distribution of the geochemical data. A whole geostatistical analysis framework, which includes probabilistic uncertainty modeling, classification and risk analysis, was illustrated through a case study of cadmium mapping. A conditional cumulative distribution function (ccdf) was first modeled by indicator kriging, and then e-type estimates and conditional variance were computed for spatial distribution of cadmium and quantitative uncertainty measures, respectively. Two different classification criteria such as a probability thresholding and an attribute thresholding were applied to delineate contaminated and safe areas. Finally, additional sampling locations were extracted from the coefficient of variation that accounts for both the conditional variance and the difference between attribute values and thresholding values. It is suggested that the indicator geostatistical framework illustrated in this study be a useful tool for analyzing any environmental variables including geochemical data for decision-making in the presence of uncertainty.

• Economic and Environmental Geology
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• v.34 no.4
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• pp.329-343
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• 2001

The deep environment and geochemical evolution of the Bugok geothennal waters, located in the Kyeongnam Province, was re-interpreted based on the hydrochemical and isotopic data published by Yun et al. (1998). The geothermal waters of the Bugok area is geochemically divided into three groups; Geothennal water I, II and III groups. Groups I and II are geochemically similar; high temperature (55.2-77.2$^{\circ}$C) and chemically belonging to Na-S04 types. However, pH and Eh values are a little different each other and Group II water is highly enriched in S04 compared to Group I water. Group III water, occurring from peripheral sites of the central part of the geothennal waters, shows temperature range of 29.3 to 47.0$^{\circ}$C and belongs to $Na-HCO_3-S0_4$ types. The deep environment and geochemical evolution of the Bugok geothennal waters, showing the diversity of geochemistry, can be interpreted as follows; I) Descending to great depth of meteoric waters that originated at high elevation and reacting with sediments and/or granites in depth. The $S0_4$ concentration of the waters has been increased by the dissolution of sulfate minerals in sediments. 2) During the continuous descending, the waters has met with the reduction environment, producing the $H_2S$ gas due to sulfate reduction. The waters has been heated up to 130$^{\circ}$C and the extent of water-rock reaction was increased. At this point, pH of waters are increased, S04 concentration decreased and calcite precipitated, therefore, the waters show the $Na-S0_4$ type. 3) Ascending of the geothennal waters along the flow path of fluids and mixing with less-deeply circulated waters. The $S0_4$ concentration is re-increased due to the oxidation of $H_2S$ gas and/or sulfide minerals in sediments. During continuous ascending, these geothennal waters are mixed with shallow groundwater.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.69-76
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• 2021

This study is to identify the mineralogical properties of caprock samples from drilling cores of the Pohang basin, which is the research area for the demonstration-scale CO2 storage project in Korea. The interaction of water-rock-gas that can occur due to CO2 injection was identified using geochemical modeling. Results of mineralogical studies, together with petrographic data of caprock and data on the physicochemical parameters of pore water were used for geochemical modeling. Modelling was carried out using the The Geochemist's Workbench 14.0.1 geochemical simulator. Two steps of modeling enabled prediction of immediate changes in the caprocks impacted by the first stage of CO2 injection and the assessment of long-term effects of sequestration. Results of minerlaogical analysis showed that the caprock samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, kaolinite and montmollonite. After the injection of carbon dioxide, the porosity of the caprock increased due to the dissolution of calcite, and dawsonite and chalcedony were precipitated as a result of the dissolution of albite and k-feldspar. In the second step after the injection was completed, the precipitation of dawsonite and chalcedony occurred as a result of dissolution of calcite and albite, and the pH was increased due to this reaction. Results of these studies are expected to be used as data to quantitatively evaluate the efficiency of mineral trapping capture in long-term storage of carbon dioxide.

• Journal of the Korean Geographical Society
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• v.49 no.2
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• pp.221-244
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• 2014

We suggested several implications by examining geochemical properties of sediments in Simjeok, Jangdo, and Hwaeomneup mountain wetlands which are natural preservation areas. Geochemical properties of wetland sediments show that all wetlands were included in the type of fens, but their distribution patterns were different from one another. We classified three sub-groups of sediments using the two step cluster analysis on the ratio of exchangeable cations. Wetland sediments can be grouped into Ca-dominated, Mg-dominated, and K-dominated types. Simjeok wetland have Ca-dominated sediments, while the sediments of Jangdo wetland indicate the Mg-dominated and Ca-dominated characteristics. Hwaeomneup wetland is composed of K-dominated sediment mainly. Different properties in the ratio are affected by various environmental factors such as geological, pedological, and vegetational settings. Because these geochemical properties will be affected by climate change and human impacts, these will be environmental indicator in mountain wetlands and be used in wetland management. This scheme can be used for classification of mountain wetlands. Therefore, we should work on geochemical properties of wetland sediments and classification schemes based on geochemical properties not only to widen understanding in geomorphic system or ecosystem of mountain wetlands but to conserve mountain wetlands properly.

• 한국지구과학회:학술대회논문집
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• 2006.02a
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• pp.213-218
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• 2006

이 논문에서는 지구통계학적 시뮬레이션을 이용하여 자료 표현에서의 불확실성이 최종적인 공간통합에 미치는 영향을 정량적으로 분석하고자 하였다. 광물자원 탐사를 위한 공간통합 사례연구를 통해 시뮬레이션 결과에 따라 예측 능력의 차이가 나타남을 확인 할 수 있었으며, 결론적으로 지구통계학적 시뮬레이션이 공간 자료의 불확실성 모델링에 효율적으로 이용될 수 있을 것으로 판단된다.