• Journal of Soil and Groundwater Environment
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• v.11 no.2
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• pp.1-12
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• 2006

A model describing the distributions of surfactants and HOCs (hydrophobic organic chemicals) in surfactant/HOC/activated carbon systems for surfactant reuse in soil washing process was developed. The model simulation was conducted for the evaluation of the effect of concentrations of surfactant, HOC, or activated carbons. Phenanthrene as a target HOC, Triton X-100 as surfactant and three granular activated carbons with different particle sizes (4-12, 12-20, and 20-40 mesh) were used in the model simulation. The distributions of HOC were significantly affected by surfactant dosages, especially at around the CMC(s). The results of selectivities for phenanthrene were much larger than 1 at various concentrations of surfactants, phenanthrene and activated carbons, which mean that the selective adsorption of phenanthrene by activated carbons is a proper separation method from surfactant solution. The model can be applied for the design of the surfactant reuse process using activated carbons without extra experimental efforts.

• Journal of Soil and Groundwater Environment
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• v.13 no.1
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• pp.32-42
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• 2008

A surfactant recovery and reuse process by selective adsorption with activated carbon was proposed to reduce surfactant cost in a soil washing process. Mathematical model simulation was performed for the whole process, which consists of soil washing, soil recovery, and soil re-washing. The optimal range of surfactant dosage was $6{\sim}10$-fold critical micelle concentration in soil. The efficiency of surfactant reuse process was decreased with increasing the dosage of activated carbon. Effectiveness factor for activated carbon significantly altered the efficiency of the reuse process unlike effectiveness factor for soil. Total requirement of surfactant was reduced to 20-30% with the reuse process compared to the conventional soil washing process. The contamination of wastewater after soil washing was reduced with the reuse process. This mathematical model can be used to estimate performance of the whole process of soil washing including surfactant recovery and to obtain optimal ranges of operating conditions without extra labor-intensive experimental works.

• Journal of Soil and Groundwater Environment
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• v.11 no.5
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• pp.1-8
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• 2006

The objective of this study is to assess impacts of sorption heterogeneity on the transport of leachate leaked from unlined landfill sites and is accomplished by examining the results from a series of Monte-Carlo simulations. For random distribution coefficient ($K_{d}$) fields with four different levels of heterogeneity ranging from homogeneous to highly heterogeneous, the transport of leachate was investigated by linking a saturated flow model with a contaminant transport model. Impacts of a chemical heterogeneity were evaluated using point statistics values such as mean, standard deviation, and coefficient of variation of the concentration obtained at monitoring wells from 100 Monte-Carlo trials. Inspection of point statistics shows that the distribution of distribution coefficient in the landfill site proves to be an important parameter in controlling leachate concentrations. In comparison to homogeneous sorption, heterogeneous $K_{d^-}$ fields produce the variability in the leachate concentration for different realizations. The variability increases significantly as the variance in the $K_{d^-}$ field and the travel time between source and monitoring well increase. These outcomes indicate that use of a constant homogeneous $K_{d}$ value for predicting the transport of leachate can result in significant error, especially when variability in $K_{d}$ is high.

• Journal of Soil and Groundwater Environment
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• v.16 no.1
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• pp.42-50
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• 2011

Potential risk of heavy metals to various receptors including humans depends on the bioavailability of the heavy metals in soil. In this study, the heavy metal extraction methods using 0.1N HCl and aqua regia were compared with the Tessier's sequential extraction method to assess whether these two methods can be used to determine the plant-available heavy metal concentrations. The contamination characteristics of copper (Cu), cadmium (Cd), lead (Pb), and arsenic (As) found in soils collected from 75 sites around the closed Janghang smelter were analyzed by extracting heavy metals using 0.1 N HCl, aqua regia, and the Tessier's sequential extraction method. The portion of metals bioavailable to plants is considered as the sum of the fraction 1 (exchangeable) and the fraction 2 (carbonates binding) of the Tessier's 5-step sequential extraction method, which were determined to be 3.1 ${\pm}$ 3.82, 0.6 ${\pm}$ 0.15, 20.6 ${\pm}$ 18.78, and 7.0 ${\pm}$ 6.48 mg/kg for Cu, Cd, Pb, and As, respectively, in this study. When the extraction using aqua regia and the Tessier's extraction method were compared, the extracted Cu and Pb concentrations did not show significant differences, whereas the extracted Cd and As concentrations showed significant differences. These results indicate that the portion of Cd and As in the fraction 5 of the Tessier's sequential extraction can not be extracted using aqua regia. Using aqua regia, which is the official test method, higher concentrations of Cu, Cd, Pb and As were extracted than the sum of the fraction 1 and 2. The results show that only 9, 40, 39 and 10% of Cu, Cd, Pb and As using aqua regia can be uptaken by plants (i.e., plant-available). Using 0.1N HCl, the portion of Cd equivalent to about 66% the fraction 1 could be extracted, while, with Pb, the portion of the fraction 1 and about 90% of the fraction 2 could be extracted. With As, the portion equivalent to the fraction 1, 2 and 79% of the fraction 3 was extracted, while with Cu, the portion equivalent to the fraction 1, 2, 3 and 20% of the fraction 4 was extracted using 0.1N HCl.

• Economic and Environmental Geology
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• v.45 no.3
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• pp.255-264
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• 2012

The stabilization using limestone ($CaCO_3$) and steel making slag as the immobilization amendments for Cu and Pb contaminated farmland soils was investigated by batch tests, continuous column experiments and the pilot scale feasibility study with 4 testing grounds at the contaminated site. From the results of batch experiment, the amendment with the mixture of 3% of limestone and 2% of steel making slag reduced more than 85% of Cu and Pb compared with the soil without amendment. The acryl column (1 m in length and 15 cm in diameter) equipped with valves, tubes and a sprinkler was used for the continuous column experiments. Without the amendment, the Pb concentration of the leachate from the column maintained higher than 0.1 mg/L (groundwater tolerance limit). However, the amendment with 3% limestone and 2% steel making slag reduced more than 60% of Pb leaching concentration within 1 year and the Pb concentration of leachate maintained below 0.04 mg/L. For the testing ground without the amendment, the Pb and Cu concentrations of soil water after 60 days incubation were 0.38 mg/L and 0.69 mg/l, respectively, suggesting that the continuous leaching of Cu and Pb may occur from the site. For the testing ground amended with mixture of 3% of limestone + 2% of steel making slag, no water soluble Pb and Cu were detected after 20 days incubation. For all testing grounds, the ratio of Pb and Cu transfer to plant showed as following: root > leaves(including stem) > rice grain. The amendment with limestone and steel making slag reduced more than 75% Pb and Cu transfer to plant comparing with no amendment. The results of this study showed that the amendment with mixture of limestone and steel making slag decreases not only the leaching of heavy metals but also the plant transfer from the soil.

• Economic and Environmental Geology
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• v.43 no.4
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• pp.305-314
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• 2010

The stabilization process using limestone ($CaCO_3$) and steel making slag as the immobilization amendments was investigated for As contaminated farmland soils around Chonam abandoned mine, Korea. Batch and continuous column experiments were performed to quantify As-immobilization efficiency in soil and the analyses using XRD and SEM/EDS for secondary minerals precipitated in soil were also conducted to understand the mechanism of Asimmobilization by the amendments. For the batch experiment, with 3% of limestone and steel making slag, leaching concentration of As from the contaminated soil decreased by 62% and 52% respectively, compared to that without the amendment. When the mixed amendment (2% of limestone and 1% of steel making slag) was used, As concentration in the effluent solution decreased by 72%, showing that the mixed of limestone and steel making slag has a great capability to immobilize As in the soil. For the continuous column experiments without the amendment, As concentration from the effluent of the column ranged from 50 to $80\;{\mu}g/L$. However, with 2% limestone and 1% steel making slag, more than 80% diminution of As leaching concentration occurred within 1 year and maintained mostly below $10\;{\mu}g/L$. Results from XRD and SEM/EDS analysis for the secondary minerals created from the reaction of the amendments with $As^{+3}$ (arsenite) investigated that portlandite ($Ca(OH)_2$), calcium-arsenite (Ca-As-O) and calcite ($CaCO_3$) were main secondary minerals and the distinct As peaks in the EDS spectra of the secondary minerals can be observed. These findings suggest that the co-precipitation might be the major mechanisms to immobilize As in the soil medium with limestone and steel making slag.

• Journal of Korea Water Resources Association
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• v.57 no.4
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• pp.263-276
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• 2024

Since the first introduction of one-dimensional transient storage modeling in the field of solute transport analysis in rivers, its application has notably expanded for various purposes, including for hydrology and geobiology over the past few decades. Despite strides in refining transient storage models, there remain unresolved challenges in simplifying complex river transport dynamics into concise formulas and a limited set of parameters. This review paper is dedicated to cataloging and assessing existing transient storage models, outlining the difficulties associated with model structures, parameters, and data, and suggesting directions for future research. We seek to enhance understanding of transient storage by highlighting the importance of continuously evaluating residence time distribution modeling, integrating hydrodynamic models, and using data with minimal assumptions. This paper would contribute to advance our comprehension of the transient storage process, offering insights into sophisticated modeling techniques, pinpointing uncertainty in parameters, and suggesting the necessary avenues for further study.

• Economic and Environmental Geology
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• v.55 no.1
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• pp.97-109
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• 2022

This study focused on the physicochemical effects of bottom ash dissolved precipitation on the soil and groundwater environment. The iced column and percolation experiments showed that most of the bottom ash particles were drained as the ash-dissolved solution, while the charcoal powder was filtered through the soil. Ion species of Al, As, Cu, Cd, Cr, Pb, Fe, Mn, Ca, K, Si, F, NO₃, SO₄ were analyzed from the eluates collected during the 24 h column test. In the charcoal powder eluates, a high concentration of K was detected at the beginning of the reaction, but it decreased with time. The concentrations of Al and Ca were observed to increase with time, although they existed in trace amount. In the bottom ash eluates, the concentrations of Ca and SO₄ decreased by 30 mg·L^-1 and 67 mg·L^-1, respectively, over 24 h. It is regarded that the infiltration patterns of the bottom ash and biochar in the unsaturated zone were different owing to their particle sizes and solvent properties. It is expected that a significant amount of the bottom ash will mix with the precipitation and percolate below the water table, especially in the case of thin and highly permeable unsaturated zone. The biochar was filtered through the unsaturated zone. The biochar did not dissolve in the groundwater, although it reached the saturation zone. For these reasons, it is considered that the direct contamination by the bottom ash and biochar are unlikely to occur.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.76-76
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• 2015

토양수분은 생태수문학에서 식생과의 상호작용의 중요한 인자이자, 대기와의 상호작용으로 인한 총체적인 물 순환에 밀접한 관련이 있다. 수문학적으로는 증발, 침투, 지하수 함량, 토양 침식, 식생 분포 등을 지배하는 중요한 요소이고, 특히 시 공간적 분포특성은 강수 사상 후 토양으로의 침투 및 토양수분의 재분포, 증발산과 불포화대에서의 오염물의 이송을 예측하는데 매우 중요하다. 또한, '07년 하천법 개정으로 증발산량 및 토양수분량이 신규 수문조사 항목으로 추가되어, 토양수분 측정에 대한 필요성이 높아졌다. 따라서, 2008년 5월, K-water연구원에서는 현재 시험유역으로 운영하고 있는 용담시험유역에 토양수분관측망(6개 관측소)을 구축하였다. 토양수분계는 토양수분을 결정하는 가장 중요한 인자인 강우자료의 획득이 이루어지는 지점에 설치하여 정확도와 신뢰도를 높일 수 있도록 용담시험 유역 내 6개 우량관측소에 설치하였다. 하지만 장비의 노후화에 따른 자료 취득의 어려움으로 인하여 2013년 4월, 토양수분계를 전면 교체하였다. 토양수분계는 기존의 FDR 방식에서 EC 농도에 대한 영향이 가장 적고, 플럭스 타워에 위치한 토양수분계 센서와 동일한 TDR 방식의 센서로 장비를 전면 교체하였다. 센서 설치 장소 변경에 따른 TDR 센서의 검증과 그리고 흙의 종류, 입도, 다짐도, 온도 등에 의한 오차가 발생 여부를 판단하기 위하여 이에 대한 보정을 실시하였다. 원지반 시료채취를 통하여 토양수분량을 측정하였고, TDR 센서에 의해 측정된 토양수분량과 채취된 시료에서 측정된 토양수분량의 결과를 비교하였고, 각 지점별 토양구성비와 전기전도도 조건을 고려하여 각 토층별 계수적용을 달리하여 센서 보정을 실시하였다. 그 결과 기존 센서 제조사에서 제안한 방정식을 그대로 사용하는 것 보다는 센서 검증을 통하여 얻은 계수보정에 의한 토양수분 변환식을 사용하는 것이 정확한 현장 자료를 확보할 수 있고, 신뢰도 높은 자료를 얻을 수 있다고 판단된다.

• Economic and Environmental Geology
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• v.39 no.4 s.179
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• pp.403-416
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• 2006

Magnetic method is rapid, cheap and simple geophysical exploration technique, and has wide range of applications such as resources prospecting, geological structure investigation and even geotechnical and environmental problems. Especially, aeromagnetics gives fundamental and useful geoscientific data fnr not only assessment of potential resources, but also national land planning. Magnetic method, perhaps the oldest geophysical technique, was relatively early introduced into Korea. Documents during Japanese occupation says that magnetic method was used for exploring metallic ore deposits and hot spring, and that a geomagnetic observatory was operated. From mid 1950's, after Korean War, magnetic explorations for natural resources such as metallic ore, uranium, coal, and groundwater were intensively executed for industrialization. Apache aeromagnetic survey project during $1958{\sim}1959$ and its ground follow-up surveys are typical and important cases in those days. Magnetic survey techniques were rapidly advanced during 1970's and 1980's with improvements of instruments, growth of geophysical manpower, and availability of computers. The national aeromagnetic mapping project by KIGAM in 1981 showed the improved technical capability of those days. Decline of mining industry since mid 1980's moved the exploration objects from traditional resources to new ones such as groundwater and geothermal resources, and applications to investigation of geological structure were revived. Recently appeared applications such as natural hazard assessment, and engineering and environmental studies increased the magnetic method's utility in the realm of exploration.