• Title/Summary/Keyword: 증기폭발

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The Prediction of Lower Explosion Limit of n-Hexadecane (n-Hexadecane의 폭발하한계 예측)

  • Ha, Dong-Myeong;Park, Sang-Hun
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.04a
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    • pp.163-163
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    • 2013
  • 최근의 수많은 산업 현장에서 취급하고 있는 각종 화학물질은 잠재적 위험성이 크므로 보관, 수송 및 취급할 때 특별한 주의가 필요하다. 공정 설계 시 정확하지 않은 폭발한계를 사용함으로서 사고가 유발되는 경우가 많다. 따라서 사업장에서 사용되고 있는 화학물질의 화재 및 폭발 특성치인 인화점, 폭발한계 등을 정확히 파악하는 것은 중요하다. 인화점은 하부인화점과 상부인화점으로 나누고 있고 있으며, 인화점은 가연성 액체의 화재 위험성을 나타내는 지표로써, 가연성액체의 액면 가까이서 인화할 때 필요한 증기를 발산하는 액체의 최저온도 또는 점화원 존재시 인화가 일어날 수 있는 최저온도, 그리고 가연성증기의 포화증기압이 공기와 혼합기체의 폭발한계 하한농도와 같게 되는 온도로 정의한다. 폭발한계는 발화원이 존재할 때 가연성가스와 공기가 혼합하여 일정 농도범위 내에서만 연소가 이루어지는 혼합범위를 말한다. 본 연구에서는 실제 공정에서 사용되고 있는 n-Hexadecane의 인화점을 측정하여 이를 기존 문헌값과 비교 하였고, 측정된 인화점을 이용하여 폭발한계를 예측하였다. 예측된 폭발한계를 여러 문헌에 제시된 자료과 비교하여 공정안전에 타당한 자료를 제시하였다. 본 연구는 n-Hexadecane을 취급하는 공정에서 안전 확보의 중요한 지침 마련과 MSDS D/B의 최신화에 유용한 정보를 제공하는데 목적이 있다.

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The TROI Steam Explosion Experiments Using Metal-added Corium (금속이 함유된 코륨을 이용한 TROI 증기폭발 실험)

  • Kim, Jong-Hwan;Min, Beong-Tae;Hong, Seong-Wan;Hong, Seong-Ho;Park, Ik-Kyu;Song, Jin-Ho;Kim, Hee-Dong
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3479-3484
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    • 2007
  • Two steam explosion experiments were performed in the TROI facility by using metal-added molten corium (core material) which is produced during a postulated severe accident in the nuclear reactor. A triggered steam explosion occurred in a case, but no triggered steam explosion did in the other case. The dynamic pressure and the dynamic load measured in the former experiment show a stronger explosion that those performed previously with oxidic corium. A steam explosion is prohibited when the melt temperature is low, because the melt is easily solidified to prevent a liquid-liquid interaction.

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Development of axial tomography technique for the study of steam explosion (증기폭발 적용 축방향 토모그라피 기술 개발)

  • Seo, Si-Won;Ha, Kwang-Soon;Hong, Seong-Wan;Song, Jin-Ho;Lee, Jae-Young
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3027-3032
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    • 2007
  • To understand the complex phenomena performed in steam explosion, the fast and global measurement of the steam distribution is imperative for this extremely rapid transient stimulation of the bubble breakup and coalescence due to turbulent eddies and shock waves. TROI, the experimental facility requests more robust sensor system to meet this requirement. In Europe, researchers are prefer a X-ray method but this method is very expensive and has limited measurement range. There is an alternative technology such as ECT. Because of TROI's geometry, however, we need axial tomography method. This paper reviews image reconstruction algorethms for axial tomography, including Tikhonov regularization and iterative Tikhonov regularization. Axial tomography method is examined by simulation and experiment for typical permittivity distributions. Future works in axial tomography technology is discussed.

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Minimum Film Boiling Temperatures for Spheres in Dilute Aqueous Polymer Solutions and Implications for the Suppression of Vapor Explosions (폴리머 수용액에서 구형체의 최소막비등온도와 증기폭발 억제 효과)

  • Bang, Kwang-Hyun;Jeun, Gyoo-Dong
    • Nuclear Engineering and Technology
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    • v.27 no.4
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    • pp.544-554
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    • 1995
  • Pool boiling of dilute aqueous solutions of polyethylene oxide polymer has been experimentally investigated for the purpose of understanding the physical mechanisms of the suppression of vapor explosions in this polymer solution. Tn solid spheres of 22.2mm and 9.5mm-diameter ore heat-ed and quenched in the polymer solutions of various concentrations at 3$0^{\circ}C$. The results showed that minimum film boiling temperature($\Delta$ $T_{MFB}$) in this highly-subcooled liquid rapidly decreased from over $700^{\circ}C$ for pure water to about 15$0^{\circ}C$ as the polymer concentration was increased up to 300ppm for 22.2mm sphere, and it decreased to 35$0^{\circ}C$ for 9.5mm sphere. This large decrease of minimum film boiling temperature in this aqueous polymer solution may explain its ability to suppress spontaneous vapor explosions. Also, tests with applying a pressure wave showed that the vapor film behaved more stable against an external disturbance at higher polymer concentrations. These observations together with the experimental evidences of vapor explosion suppression in dilute polymer solutions suggest that the application of polymeric additives such as polyethylene oxide as low as 300ppm to reactor emergency coolant be considered to prevent or mitigate energetic fuel-coolant interactions during severe reactor accidents.s.

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Assessment of the Applicability of Vapor Cloud Explosion Prediction Models (증기운 폭발 예측 모델의 적용성 평가)

  • Yoon, Yong-Kyun
    • Explosives and Blasting
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    • v.40 no.3
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    • pp.44-53
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    • 2022
  • This study evaluates the applicability of the TNT Equivalency Method, Multi-Energy Method, and Baker-Strehlow-Tang (BST) Method, which are blast prediction models used to determine the overpressure of blast wave generated from vapor cloud explosion. It is assumed that the propane leaked from a propane storage container with a capacity of 2000 kg installed in an area where studio houses and shopping centers are concentrated causes a vapor cloud explosion. The equivalent mass of TNT calculated by applying the TNT Equivalency Method is found to be 4061 kg. Change of overpressure with the distance obtained by the TNT Equivalency Method, Multi-Energy Method, and BST Method is rapid and the magnitude of overpressure obtained by the TNT Equivalency Method and BST method is generally similar within 100 m from explosion center. As a result of comparing the overpressure observed in the actual vapor cloud explosion case with the overpressure obtained by applying the TNT Equivalent Method, Multi-Energy Method, and BST Method, the BST Method is found to be the best fit. As a result of comparing the overpressure with the distance obtained by each explosion prediction model with the damage criteria for structure, it is estimated that the structure located within 90 m from explosion center would suffer a damage more than partial destruction, and glass panes of the structure separated by 600 m would be fractured.