• Journal of the Korean Electrochemical Society
• /
• v.2 no.4
• /
• pp.183-189
• /
• 1999

A study on the destruction of organic cation and anion exchange resins by electro-generated Ag(II) as a mediator was carried out to develop the ambient-temperature aqueous process, known as Ag(II)-mediated electro-chemical oxidation (MEO) process, for the treatment of a large quantity of spent organic ion exchange resins as the low and Intermediated-level radioactive wastes arising from the operation, maintenance and repairs of nuclear facilities. The effects of controllable process parameters such as applied current density, temperature, and nitric acid concentration on the MEO of organic ion exchange resins were investigated. The cation exchange resin was completely decomposed to $CO_2$. The current efficiency increased with a decrease in applied current density while nitric acid concentration and temperature on the MEO of cation exchange resin did not affect the MEO. On the other hand, anion exchange resins were decomposed to CO and $CO_2$. The ultimate conversion to CO was about $10\%$ regardless of temperature. The destruction efficiencies to $CO_2$ were dependent upon temperature and the effective destruction of anion exchange resin could be obtained above $60^{\circ}C$.

• Nuclear Engineering and Technology
• /
• v.23 no.4
• /
• pp.387-400
• /
• 1991

An ocean compartment model simulating transport of nuclides by advection due to ocean circulation and intertaction with suspended sediments is developed, by which concentration breakthrough curves of nuclides can be calculated as a function of time. Dividing ocean into arbitrary number of characteristic compartments and performing a balance of mass of nuclides in each ocean compartment, the governing equation for the concentration in the ocean is obtained and a solution by the numerical integration is obtained. The integration method is specially useful for general stiff systems. For transfer coefficients describing advective transport between adjacent compartments by ocean circulation, the ocean turnover time is calculated by a two-dimensional numerical ocean model. To exemplify the compartment model, a reference case calculation for breakthrough curves of three nuclides in low-level radioactive wastes, Tc-99, Cs-137, and Pu-238 released from hypothetical repository under the seabed is carried out with five ocean compartments. Sensitivity analysis studies for some parameters to the concentration breakthrough curves are also made, which indicates that parameters such as ocean turnover time and ocean water volume of compartments have an important effect on the breakthrough curves.

• The Journal of Engineering Geology
• /
• v.29 no.1
• /
• pp.1-12
• /
• 2019

Earthquake can change underground stress condition around the hypocenter and affect the fracture systems of the rocks. In Korea, the M5.8 Gyeongju earthquake on September 12, 2016 and M5.4 Pohang earthquake on November 15, 2017 occurred inside the Yangsan fault zone and possibly affected the fracture systems in the Yangsan fault zone and nearby rock masses. In this study, the characteristics of the fracture system (fracture orientation, number of the fractures, fracture spacing and aperture, dip angle, fracture density along depth, and relative rock strength) of the rocks in the low/intermediate level radioactive waste repository site located in the coastal area of the East Sea are analyzed by the impact of the Gyeongju and Pohang earthquakes using acoustic televiewer data taken from the boreholes at the radioactive waste repository site in 2005 and 2018. As a result of acoustic televiewer logging analysis, the fracture numbers, fracture aperture, and fracture density along depth overall increased in 2018 comparing to those in 2005. This increase tendency may be due to changes in the fracture system due to the impact of the earthquakes, or due to weathering of the wall of the boreholes for a long period longer than 10 years after the installation of the boreholes in 2005. In the borehole KB-14, on the whole, the orientation of the fractures and the average fracture spacing are slightly different between 2005 and 2018, while dip angle and relative rock strength in 2005 and 2018 are similar each other.

• Economic and Environmental Geology
• /
• v.49 no.4
• /
• pp.301-314
• /
• 2016

Disused Sealed Radioactive Sources (DSRSs) are stored temporally in the centralized storage facility of Korea Radioactive Waste Agency (KORAD) and planned to be disposed in the low- and intermediate-level radioactive waste (LILW) disposal facility in Gyeongju city. In this study, preliminary post-closure safety assessment was performed for DSRSs in order to draw up an optimum disposal plan. Two types of disposal options were considered, i.e. engineered vault type disposal and rock cavern type disposal which were planned to be constructed and operated respectively in LILW disposal facility in Gyeongju city. Assessment end-point was individual effective dose of critical group and calculated by using GoldSim code. In normal scenario, the maximum dose was estimated to be approximately $1{\times}10^{-7}mSv/yr$ for both disposal options. It meant that both options had sufficient safety margin when compared with regulatory limit (0.1 mSv/yr). Otherwise, in well scenario, the maximum dose exceeded regulatory limit of 1 mSv/yr in engineered vault type disposal and the exposure dose was mainly contributed by $^{226}Ra$, $^{210}Pb$ (daughter nuclide of $^{226}Ra$) and $^{237}Np$ (daughter nuclide of $^{241}Am$). For rock cavern type disposal, even though the peak dose satisfied regulatory limit, the exposure doses by $^{14}C$ and $^{237}Np$ were relatively high above 10% of regulatory limit. Therefore, it is necessary to exclude $^{14}C$, $^{226}Ra$ and $^{241}Am$ for two type of disposal options and additional management such as long-term storage and development of disposal container for those radionuclides should be performed before permanent disposal for conservative safety and security.