• Title/Summary/Keyword: 중화반응

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Studies for Neutralization Teratment of Acid Mine Drainage from Abandoned Mine (폐광산으로부터 유출되는 산성광산배수 중화처리를 위한 반응조 실험 연구)

  • Kang, Han;Park, Seong-Min;Jang, Yun-Deug;Kim, Jeong-Jin
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.33-45
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    • 2008
  • Two types of reactor were designed to neutralize acid mine drainage flow from closed mine. Limestone used as a neutralizer, which composed mainly of calcite with small amount of dolomite. In general, the effect of neutralization depended upon both the position of reaction and the amount of supply of neutralizer. It was observed that the neutralization was enhanced as the reaction with acid mine drainage occurred at the upper part of reactor with sufficient supply of neutralizer. When the reaction was sustained in upper part of the reactor, the neutralizer was not affected by precipitates and the reaction could last until all of neutralizer was consumed.

Characteristics of Ammonia Removal by Natural Neutralizer (천연중화제를 이용한 암모니아 제거특성)

  • Kim, Tak-Hyun;Park, Hyung-Yong;Kim, Sangyong
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.651-659
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    • 2000
  • The characteristics of ammonia removal by natural neutralizer were studied by using a scrubber type equipment. As operation parameters, neutralizer dilution ratio, neutralizer inlet flowrate, air flowrate and initial ammonia concentration were selected and their effects on ammonia removal efficiency were investigated. The optimal removal effect was achieved at neutralizer dilution ratio of 1.0% and neutralizer inlet flowrate of $60m{\ell}/min$. On the other hand, with respect to air flowrate and initial ammonia concentration, there was no significant effect on removal efficiency, when loading rate was considered. In addition, ammonia removal reaction was investigated by analyzing the ammonia oxides, such as nitrites and nitrates, after reacting ammonium solution with natural neutralizer. The result shows a partial oxidation by natural neutralizer besides dominant absorption of ammonia.

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An Analysis and Improvement of the Experiment of the Acid-Base Neutralization Reaction (산-염기 중화반응 실험의 문제점 분석 및 개선 방안)

  • Jeon, Yeong-Hwa;Hong, Lan-Sun;Kang, Young-Jin;Kang, Seong-Joo
    • Journal of the Korean Chemical Society
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    • v.48 no.2
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    • pp.189-194
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    • 2004
  • The aim of this study is to analyze and improve the experiment of the acid-base neutralization reaction described in science textbooks. The problems in the neutralization reaction of NaOH-HCl solution were following; 1) the decoloration of phenolphthalein solution, 2) the color change of the titrated solution during condensation for the confirmation of the salt crystals, 3) the difficulty for the confirmation of the salt crystals. These problems are explained by the structure change of phenolphthalein and the improved experiment is proposed.

Role of Plant Extracts to Remove Hydrogen Sulfide in the Air-Lifter Reactor (Air-lift 반응기내 황화수소제거시 식물정유추출물의 역할)

  • Park, Jong-Woo;Park, Young-G.;Kim, Jeong-In
    • KSBB Journal
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    • v.25 no.5
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    • pp.421-428
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    • 2010
  • This paper reports on the experimental investigation carried out to evaluate the physical optimal conditions in the absorption column to remove odorous hydrogen sulfide gas. Hydrogen sulfide gas, as a highly undesirable contaminant, is most widely emitted from environmental treatment facilities. The absorbent mixed with natural second metabolites extracted from conifer trees and chemical absorbent of 2-aminoethanol was applied to remove it via chemical neutralization. The absorbent of natural second metabolites was achieved by a removal efficiency of 20-40% by itself depending on the treatment conditions, but the complex absorbent mixed with 0.1% amine chemical provides the removal efficiency of 98%. The optimal removal efficiencies have been examined against the two major parameters of temperature and pH. This study shows that the aqueous solution by natural second metabolites can be used as an appropriate absorbent in the column absorbed for the removal of hydrogen sulfide gas.

Study of Toxic Gas Removal Characteristics by Chemical Analysis of Essential Oil using SPME Method (SPME법을 이용한 식물정유 성분분석을 통한 유해가스 제거 특성연구)

  • 박영규
    • KSBB Journal
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    • v.19 no.3
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    • pp.231-235
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    • 2004
  • This paper was investigated to clarify the possibility of ammonia gas removal by essential oil. First of all, the chemical analysis was peformed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil react with ammonia by neutralization and their reaction mechanism was elucidated. Based on their chemical neutralized reaction, the removal efficiencies of ammonia gas were studied to derive the optimal conditions in the scrubber tower such as optimal temperature and pH. The experimental result shows that the removal efficiency of ammonia gas was achieved over 98 % by the misty aerosol dispersion of scrubber tower.

Performance Evaluation of Quality-Improved Recycled Aggregate Using Ultrasonic Wave and Chemical Neutralization Reaction (초음파 세척 및 화학적 중화반응을 이용한 품질 개선된 순환골재의 성능 평가)

  • Jay Jang-Ho Kim;Young-Jun You
    • Journal of Korean Society of Disaster and Security
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    • v.17 no.1
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    • pp.27-35
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    • 2024
  • This paper presents experimental research results to evaluate the applicability of chemical neutralization reaction and ultrasonic wave to remove cement paste and mortar attached to the surface of recycled aggregate. In order to derive optimal ultrasonic cleaning efficiency and chemical neutralization reaction, experiments were conducted using variables such as ultrasonic frequency and type of chemical solution. As a result, the optimal frequency was found to be 24 kHz, and immersion in a 15% hydrochloric acid solution for 30 minutes of stimulation showed the highest efficiency. In addition, the specific gravity, absorption rate, and wear rate of the quality-improved recycled coarse aggregate were similar to those of general aggregate and were found to satisfy all KS F 2527 standards. Therefore, it is believed that the recycled aggregate whose quality has been improved through the method proposed in this study can be used for concrete.

College Students' Misconception about the Volume Change of Solution during Acid/Base Titration: Partial Molar Volume of Salt (산·염기 적정에서 용액의 부피 변화에 대한 대학생들의 오개념 연구)

  • Jang, Nak Han
    • Journal of Science Education
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    • v.33 no.2
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    • pp.317-320
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    • 2009
  • I investigated Korean college students' conception about the volume change of solution when they detected the equivalence point during acid/base titration experiment using method of volume measurement. According to this study, most college students had a misconception that the volume increment was due to the formation of water by neutralization during acid/base titration. However, this is not enough to explain the volume change, neglecting contribution of a salt in solution. I calculated the partial molar volume of NaCl formed to explain the volume increment of solution during HCl/NaOH neutralization. Comparing the result of experiment with the calculation of partial molar volume, I elucidated that the main effect of volume increment was due to the partial molar volume of NaCl formed during HCl/NaOH neutralization. Here I propose to introduce college students to the concept of partial molar volume of the salt formed to reduce misconception about the volume change of solution during acid/base neutralization.

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Chemistry Experiment Program Using 3D - Neutralization Reaction - (3D를 이용한 화학실험 프로그램 - 중화반응 -)

  • Yoon, Kyung-Seob;Kang, Min-Uk;Kim, Hyun-Woo
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2012.07a
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    • pp.285-286
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    • 2012
  • 실험의 주된 목적은 가설의 검증에 있다. 그 중에서도 화학 실험은 다른 실험보다 위험도가 높을뿐더러 소모성 약품이 많고 실험을 할 장소도 마련되어야 하며 실험할 기구 또한 준비가 제대로 되어 있어야 한다. 또 미세한 실수라든지 실험하는 과정이나 방법을 약간만 다르게 해도 결과가 얼마든지 다르게 나올 수 있는 실험이 바로 화학실험이다. 그렇기 때문에 화학 실험에 있어서 충분히 과정과 방법을 숙지해 실험에 임해야 한다. 본 논문에서는 화학 실험 중에서 중화 반응 실험의 과정과 방법을 미리 시뮬레이션을 통해 숙지할 수 있는 프로그램을 제안한다.

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Characteristic Study for Methyl-mercaptain Removal by an Essential Oil (식물추출물을 이용한 메틸멀캡탄 제거 특성 연구)

  • Park, Young-Gyu
    • KSBB Journal
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    • v.22 no.3
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    • pp.151-156
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    • 2007
  • Increasing public concerns over odors and air regulations necessitates the remediation of a wide range of odorous compounds for industrial purpose. Currently, wet scrubbing technique by neutralization using essential oils is utilized to treat methyl mercaptan odor. The chemical analysis is performed to analyze the composition of an essential oil by GC-MS. The objective of this study is to clarify the possibility of the neutralization of odors sprayed in the fixed bed and determine the removal efficiencies in the misty aerosol by different input odor concentration. It is found that methyl mercaptan is significantly removed in the wet scrubber, and their removal efficiency of methyl mercaptan is obtained by 98%.

The study on the formation of titanic acid by dehydration of TiCl₄ (TiCl₄가수분해에 의한 titanic acid의 생성에 관한 연구)

  • Kim, Heon;Kim, Dae Ung;Lee, Gyeong Hui;Baek, Un Pil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.342-342
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    • 1998
  • The effect of pH on the dehydration reaction of TiCl₄solution. KOH and HCl were used as a accelerater and retarder in dehydration. Results are follow. Neutralization point is pH 7.4 in the system of $TiCl_4-KOH$ and the production which is produced at acidic side is Ti-gel of poly metatitanic acid. The production which is produced at alkalic side is aligomer and crystalline potasium titanate is not detected.