• Journal of the Korean Applied Science and Technology
• /
• v.26 no.1
• /
• pp.80-86
• /
• 2009

This research was performed to evaluate heavy metal leaching characteristics of the sludge from paper mill process with sintering temperature. Heavy metal leaching of the sludge was characterized with Korean Leaching Test and Toxicity Characteristic Leaching Procedure. The test sludge was composed of 70.72% of moisture, 9.5% of volatile solids and 9.76% of fixed solids. As a result of XRF analysis, Fe was the highest inorganic element in approximately 83%, which implies the recycling possibility of the sludge in reuse of Fenton chemicals and artificial lightweight aggregate. Leaching of heavy metals from sintered sludge was lower than the dry ones. However, there was no significant difference in leaching characteristics between the sludges sintered at $350^{\circ}C$ and $650^{\circ}C$. Zn and Fe were leached more greatly in TCLP and KLT methods respectively.

• Resources Recycling
• /
• v.19 no.2
• /
• pp.10-18
• /
• 2010

This research investigates the feasibility of ceramic specimens made from Primary clay and Red Hwangto with MSWI fly ash. Specimens preduced by mix-design maximum 20 wt% MSWI fly ash were analysed by SEM, UTM, ICP, etc. As a result of measurement,$P_{10}$ specimen was improved on bending strength and $R_5$ specimen was improved on compressive and bending strength. Also amount of extracted heavy metal was suitable for regulatory limits. This indicates that MSWI fly ash is indeed suitable for the partial replacement of ceramic materials in bricks.

• Journal of Environmental Impact Assessment
• /
• v.16 no.1
• /
• pp.35-43
• /
• 2007

Vitrified aggregates obtained by using mine tailings were evaluated using various leaching methods to assess their environmental safety. The leaching tests in this study include continuous batch leaching, Dutch availability leaching, pH-stat and tank diffusion test as well as TCLP (Toxicity Characteristic Leaching Procedure), which is commonly adopted. Vitrification technique has successfully been applied treating some solid wastes containing high level of heavy metals, such as EAF (Electric Arc Furnace) dust and mine tailings. The potentially most leachable element among trace metals was As and theoretically about 7% of total concentrations in the aggregate can be released under extreme condition. Zinc was leached about 4% and the other trace metals including Cd, Cr and Pb were hardly released from the vitrified mine tailing aggregate.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.5 no.2
• /
• pp.57-64
• /
• 1997

This study was performed to investigate the characteristics of compost produced from the composting facility at Nanjido. The capacity of the facility is 10 ton/day. Feed material was food waste generated in Seoul. Moisture content of the compost product was 31% and conductivity was 2.6 mmhos/cm. The compost product met Korean quality standards and EC quality standards for VS and C/N ratio. In case of TOC and TKN, they were met with Japan quality standards. The water soluble-C/N ratio finally reached about 5 based on dry compost. The color of compost product was dark brown. The product had earthy smell. Heavy metal contents of the compost were below Korean quality standards by wet basis.

• Journal of Environmental Impact Assessment
• /
• v.22 no.5
• /
• pp.427-437
• /
• 2013

Generation rate of construction wastes in Korea has occupied preponderantly in recent years. To understand chemical properties of recycled concrete aggregate (RCA), RCA samples were tested for their leaching characteristics. Leaching tests were conducted according to Korean Standard Leaching Test (KLT) and Toxicity Characteristics Leaching Procedure (TCLP) respectively. The RCA samples were characterized using X-ray fluorescence (XRF). Alkalinity of the leachate was determined using a pH meter titration method. The XRF analysis result shows that the calcium oxide (CaO) content in the RCA sample is 25.3~50.4 %. When the RCA sample was mixed with water in a batch reactor, pH in the solution was rapidly increased, and 70% of the total pH change was found in 1 hour. The TCLP showed slightly higher efficiency for leaching heavy metals than the KLT. The leaching efficiency was also higher as the particle size of RCA sample was smaller. The leaching test results suggest that RCA can be generally classified as nonhazardous waste.

• Journal of the Korean Applied Science and Technology
• /
• v.27 no.4
• /
• pp.475-481
• /
• 2010

Elution effect was studied by the reactions between Electric arc furnace(EAF)dust and conc. or dil. sulfuric acid for the purpose of recoverying of the useful metals afterwards. The methods of mixing with acids and EAF dust for the elutions were depend on the ratios of acid/EAF dust. Experimental results showed that increased the ratios of sulfuric acids, decreased the elution effects are on the Zn, Fe and Mn, and conc. sulfuric acid showed higher elution effects than dil. sulfuric acids for the all metals. But in case of Pb, dil. sulfuric acid showed higher elution effects than conc. sulfuric acids conversely. Furthermore, the reason of the extreamly low quantities of eluted Pb is caused by the low solubilities by sulfuric acids compared to the other metals, as the results of the insoluble Pb is removed by the process of filtering.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2012.05a
• /
• pp.588-592
• /
• 2012

저수지에서 퇴사가 저수지에 미치는 영향으로는 저수용량의 감소로 인한 용수공급량 저하, 상류하천 수위 상승에 따른 홍수소통능력 감소로 인한 배수위 상승, 퇴적토의 용출에 의한 부영양화 촉진 및 중금속 퇴적 등의 수질변화, 퇴사로 인한 어류서식처 환경의 변화 등이 있다. 또한, 저수지로 유입되는 유사에 대한 정확한 예측은 댐의 계획 및 운영과 관련된 저수지 퇴사관계를 이해하는데 필수 요소이다. 즉, 저수지 퇴사에 관한 예측 자료는 댐 설계시에 장래 50년 및 100년 후의 저수위-저수용량 관계곡선을 결정하고, 댐의 사수위를 결정하는데 중요한 기본자료이며, 또한 댐 건설후의 저수지내로 유입되는 유사의 공간적 퇴적분포를 예측하고, 기능별 저수지 용량배분, 본체 및 취수구 등 각종 수리구조물의 안정, 저수지 상류 퇴사로 인한 홍수위의 상승 등 저수지 제 기능의 적정 관리를 계획하는데 필요한 기본자료이기 때문이다. 본 연구에서는 저수지 내에서의 2차원적 하상변동을 해석하기 위한 퇴사 모델링 방법으로 2차원 정상 및 동수역학적인 유사이송과 하상변동을 모의할 수 있으며, 침식과 포착 및 이송 그리고 퇴적의 각 단계에 따라 세부모의가 가능할 뿐만 아니라 RMA2와 SMS 프로그램과 상호 연계가 자유로운 SED-2D 모형을 이용하여 댐 축조로 인한 저수지내의 퇴사거동을 모의한 후 하상변동을 분석하였다.

• Analytical Science and Technology
• /
• v.21 no.4
• /
• pp.279-283
• /
• 2008

Blood soil and the mixture of blood soil, elvan soil and, silica soil materials were molded, then they were sintered in $1100^{\circ}C$ and were used for the emission of the far infrared ray boll. The emission from the manufactured bolls was relatively high in the range of $8{\sim}12{\mu}m$ wavelength each. The elution of minerals from mixture bolls was very low, but the elimination of heavy metal cadmium ion in activated water and energy water treated with mixture bolls was very high. Activated water and energy water had a high to the UV protected ability in comparison to drinking water.

• Economic and Environmental Geology
• /
• v.28 no.3
• /
• pp.251-257
• /
• 1995

Three PEA (Pulverised Fuel Ash) samples, which were fresh, 17 and some 40 years weathered, were collected from two major British power plants. Batch leaching tests with these samples using distilled water and simulated industrial leachate showed higher amounts of element liberation from fresh ash, including Ca, Na, K, S (as $SO^{2-}_4$, $Cr_{total}$, Cu, Li Ni, Mo and CI and this seems to indicate their surface association and easier dissolution when contact with water. On the contrary Mg, Al, Ba, Si, V, As and Se do not show such readily leachable concentrations and these elements might be more associated with glass fraction in PFA particle rather than surface. Although element concentrations in the weathered ash are much lower than those in the initial leachate from the fresh ash, elements are still detected as resonable concentrations, with rather constant levels and this seems to demonstrate the element release from unstable glass phase of PFA particle. Fe, Ca, $Cr_{total}$, Cu, Ni, Zn and Hg were removed from the synthetic leachate by PFA and this is also confirmed by gain in solid PFA. The order of element retention is Meaford weathered ash > Drax weathered ash > Drax fresh ash in decreasing order and this conforms with the degree of weathering. Namely, the more wethered, the more wethered, the more effective in metal retention from the synthetic leachate.

• Analytical Science and Technology
• /
• v.24 no.5
• /
• pp.387-394
• /
• 2011

This study was performed to investigate the contents and leaching characteristics of hazardous wastes from the paint industry. In order to establish a hazardous waste list, samples from industrial discharge have been analyzed for 8 non-regulated inorganic hazardous substances (i.e., Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples from a total of 64 workplaces, e.g. manufacture, formulation, supply and use (MFSU) of coatings, adhesives, sealants and printing inks processing, have been chosen and analyzed. Contents and leaching tests for inorganic metal species in samples show that the non-regulated hazardous substances satisfy all the criteria, while quantitative analyses reveal that some samples of the discharged wastes exceeded the criteria proposed by NIER (National Instituted of Environmental Research). In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.